ThuliumV1, Istex, Corpus, bibRecord, 000F23

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

Identifieur interne : 000F23 ( Istex/Corpus ); précédent : 000F22; suivant : 000F24

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

Auteurs : Mercouri G. Kanatzidis ; Rainer Pöttgen ; Wolfgang Jeitschko

Source :

Angewandte Chemie International Edition [ 1433-7851 ] ; 2005-11-04.

RBID : ISTEX:45263569ADD19A59188F53B9C6EF8E67F854E504

English descriptors

KwdEn :
- Acetic acid, Acta, Acta chem, Acta crystallogr, Albering, Allg, Alloy, Alloys compd, Alumina, Aluminides, Ampoule, Angew, Angewandte, Angewandte chemie synthesis, Annealing, Anorg, Appl, Atomic ratio, Bilc, Binary, Binary compounds, Binary phosphides, Boride, Borides, Braun, Brazis, Canfield, Chem, Chemie, Compd, Compound, Cosn, Crucible, Crucible material, Cryst, Crystal growth, Crystal structures, Crystallogr, Cubic phase, Direct reaction, Disalvo, Elemental components, Eutectic, Gmbh, Higashi, High content, High pressure, High temperatures, Hydrochloric, Hydrochloric acid, Indium, Indium flux, Inorg, Intermetallic, Intermetallic compounds, Intermetallic phases, Intermetallics, Isotypic, Jeitschko, Kanatzidis, Kannewurf, Kgaa, Kristallogr, Kudou, Lanthanoid, Large crystals, Large number, Liquid aluminum, Liquid gallium, Liquid metals, Lithium, Lower temperatures, Mahanti, Mater, Matrix, Metal flux, Metallic flux, Metallic fluxes, Molten, Molten aluminum, Molten metals, Naturforsch, Niemann, Nitride, Okada, Peritectic, Peritectic reactions, Phase diagram, Phosphides, Phosphorus, Phys, Physical properties, Polyphosphides, Quaternary, Quaternary compounds, Rare earths, Reactant, Reaction product, Reactive, Reactive flux, Recent examples, Reehuis, Room temperature, Scanning electron micrograph, Shishido, Silica tubes, Silicide, Silicon, Single crystal, Single crystals, Slow cooling, Small amounts, Solid state chem, Stannides, Structure type, Such reactions, Ternary, Ternary compounds, Ternary phosphides, Thiede, Transition metal, Transition metals, Unpublished results, Verlag, Verlag gmbh, Weinheim, Weinheim angew, Yamane, Zhuravleva.
Teeft :
- Acetic acid, Acta, Acta chem, Acta crystallogr, Albering, Allg, Alloy, Alloys compd, Alumina, Aluminides, Ampoule, Angew, Angewandte, Angewandte chemie synthesis, Annealing, Anorg, Appl, Atomic ratio, Bilc, Binary, Binary compounds, Binary phosphides, Boride, Borides, Braun, Brazis, Canfield, Chem, Chemie, Compd, Compound, Cosn, Crucible, Crucible material, Cryst, Crystal growth, Crystal structures, Crystallogr, Cubic phase, Direct reaction, Disalvo, Elemental components, Eutectic, Gmbh, Higashi, High content, High pressure, High temperatures, Hydrochloric, Hydrochloric acid, Indium, Indium flux, Inorg, Intermetallic, Intermetallic compounds, Intermetallic phases, Intermetallics, Isotypic, Jeitschko, Kanatzidis, Kannewurf, Kgaa, Kristallogr, Kudou, Lanthanoid, Large crystals, Large number, Liquid aluminum, Liquid gallium, Liquid metals, Lithium, Lower temperatures, Mahanti, Mater, Matrix, Metal flux, Metallic flux, Metallic fluxes, Molten, Molten aluminum, Molten metals, Naturforsch, Niemann, Nitride, Okada, Peritectic, Peritectic reactions, Phase diagram, Phosphides, Phosphorus, Phys, Physical properties, Polyphosphides, Quaternary, Quaternary compounds, Rare earths, Reactant, Reaction product, Reactive, Reactive flux, Recent examples, Reehuis, Room temperature, Scanning electron micrograph, Shishido, Silica tubes, Silicide, Silicon, Single crystal, Single crystals, Slow cooling, Small amounts, Solid state chem, Stannides, Structure type, Such reactions, Ternary, Ternary compounds, Ternary phosphides, Thiede, Transition metal, Transition metals, Unpublished results, Verlag, Verlag gmbh, Weinheim, Weinheim angew, Yamane, Zhuravleva.

Abstract

This review highlights the use and great potential of liquid metals as exotic and powerful solvents (i.e. fluxes) for the synthesis of intermetallic phases. The results presented demonstrate that considerable advances in the discovery of novel and complex phases are achievable utilizing molten metals as solvents. A wide cross‐section of examples of flux‐grown intermetallic phases and related solids are discussed and a brief history of the origins of flux chemistry is given. The most commonly used metal fluxes are surveyed and where possible, the underlying principal reasons that make the flux reaction work are discussed.

Url:

https://api.istex.fr/document/45263569ADD19A59188F53B9C6EF8E67F854E504/fulltext/pdf

DOI: 10.1002/anie.200462170

Links to Exploration step

ISTEX:45263569ADD19A59188F53B9C6EF8E67F854E504

Le document en format XML

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<term>Allg</term>
<term>Alloy</term>
<term>Alloys compd</term>
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<term>Angew</term>
<term>Angewandte</term>
<term>Angewandte chemie synthesis</term>
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<term>Alloy</term>
<term>Alloys compd</term>
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<term>Aluminides</term>
<term>Ampoule</term>
<term>Angew</term>
<term>Angewandte</term>
<term>Angewandte chemie synthesis</term>
<term>Annealing</term>
<term>Anorg</term>
<term>Appl</term>
<term>Atomic ratio</term>
<term>Bilc</term>
<term>Binary</term>
<term>Binary compounds</term>
<term>Binary phosphides</term>
<term>Boride</term>
<term>Borides</term>
<term>Braun</term>
<term>Brazis</term>
<term>Canfield</term>
<term>Chem</term>
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<term>Compound</term>
<term>Cosn</term>
<term>Crucible</term>
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<term>Cryst</term>
<term>Crystal growth</term>
<term>Crystal structures</term>
<term>Crystallogr</term>
<term>Cubic phase</term>
<term>Direct reaction</term>
<term>Disalvo</term>
<term>Elemental components</term>
<term>Eutectic</term>
<term>Gmbh</term>
<term>Higashi</term>
<term>High content</term>
<term>High pressure</term>
<term>High temperatures</term>
<term>Hydrochloric</term>
<term>Hydrochloric acid</term>
<term>Indium</term>
<term>Indium flux</term>
<term>Inorg</term>
<term>Intermetallic</term>
<term>Intermetallic compounds</term>
<term>Intermetallic phases</term>
<term>Intermetallics</term>
<term>Isotypic</term>
<term>Jeitschko</term>
<term>Kanatzidis</term>
<term>Kannewurf</term>
<term>Kgaa</term>
<term>Kristallogr</term>
<term>Kudou</term>
<term>Lanthanoid</term>
<term>Large crystals</term>
<term>Large number</term>
<term>Liquid aluminum</term>
<term>Liquid gallium</term>
<term>Liquid metals</term>
<term>Lithium</term>
<term>Lower temperatures</term>
<term>Mahanti</term>
<term>Mater</term>
<term>Matrix</term>
<term>Metal flux</term>
<term>Metallic flux</term>
<term>Metallic fluxes</term>
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<term>Molten aluminum</term>
<term>Molten metals</term>
<term>Naturforsch</term>
<term>Niemann</term>
<term>Nitride</term>
<term>Okada</term>
<term>Peritectic</term>
<term>Peritectic reactions</term>
<term>Phase diagram</term>
<term>Phosphides</term>
<term>Phosphorus</term>
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<term>Physical properties</term>
<term>Polyphosphides</term>
<term>Quaternary</term>
<term>Quaternary compounds</term>
<term>Rare earths</term>
<term>Reactant</term>
<term>Reaction product</term>
<term>Reactive</term>
<term>Reactive flux</term>
<term>Recent examples</term>
<term>Reehuis</term>
<term>Room temperature</term>
<term>Scanning electron micrograph</term>
<term>Shishido</term>
<term>Silica tubes</term>
<term>Silicide</term>
<term>Silicon</term>
<term>Single crystal</term>
<term>Single crystals</term>
<term>Slow cooling</term>
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<term>Solid state chem</term>
<term>Stannides</term>
<term>Structure type</term>
<term>Such reactions</term>
<term>Ternary</term>
<term>Ternary compounds</term>
<term>Ternary phosphides</term>
<term>Thiede</term>
<term>Transition metal</term>
<term>Transition metals</term>
<term>Unpublished results</term>
<term>Verlag</term>
<term>Verlag gmbh</term>
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<front><div type="abstract" xml:lang="en">This review highlights the use and great potential of liquid metals as exotic and powerful solvents (i.e. fluxes) for the synthesis of intermetallic phases. The results presented demonstrate that considerable advances in the discovery of novel and complex phases are achievable utilizing molten metals as solvents. A wide cross‐section of examples of flux‐grown intermetallic phases and related solids are discussed and a brief history of the origins of flux chemistry is given. The most commonly used metal fluxes are surveyed and where possible, the underlying principal reasons that make the flux reaction work are discussed.</div>
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The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

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