Determination of Scandium, Yttrium and Rare Earth Elements in Rocks by High Resolution Inductively Coupled Plasma‐Mass Spectrometry
Identifieur interne : 000C44 ( Istex/Checkpoint ); précédent : 000C43; suivant : 000C45Determination of Scandium, Yttrium and Rare Earth Elements in Rocks by High Resolution Inductively Coupled Plasma‐Mass Spectrometry
Auteurs : Philip Robinson [Australie] ; Ashley T. Townsend [Australie] ; Zongshou Yu [Australie] ; Carsten Münker [Australie]Source :
- Geostandards Newsletter [ 0150-5505 ] ; 1999-06.
Descripteurs français
- Wicri :
- topic : Chimie analytique, Sciences de la terre, Oxyde, Spectrométrie.
English descriptors
- KwdEn :
- Abundance samples, Analysis time, Analytical chemistry, Analytical sciences, Analytical sequence, Average precision, Bacl, Baoh, Basalt, Calibration, Calibration solutions, Calibration standards, Central science laboratory, Chemical geology, Chondrite, Critical evaluation, Detection limits, Digestion, Earth sciences, Eggins, Elements element, Exchange separation, Final dilution, Final rinse, Geoanalysis, Geoanalysis table, Geological materials, Geological samples, Geostandards, Geostandards newsletter, Good agreement, Good detection limits, High resolution, High resolution inductively, Higher resolution, Incipient dryness, Indium, Inductively, Internal standards, Ionov, Isotope, Isotope dilution mass spectrometry, Jarvis, Jenner, Joannon, Level analysis, Literature values, Lithium borate fusion, Little difference, Mafic rocks, Mass spectrum, Matrix, Matrix effects, Maximum signal intensity, Medium resolution, Memory effects, Ndoh, Newsletter, Other laboratories, Other studies, Other workers, Oxide, Oxide formation, Perkin elmer, Plasmamass spectrometry, Polyatomic interferences, Powder pellets, Precise determination, Pure quartz, Pure water, Quadrupole, Quadrupole instruments, Quartz, Rare earth elements, Reference material, Reference materials, Resolution mode, Rinsing solution, Rock reference materials, Rock samples, Sample blanks, Sample solution, Sampling depth, Scandium, Silicate, Smoh, Sodium peroxide sinter, Special issue, Spectral interferences, Spectrometry, Spray chamber, Standard deviation, Standard solutions, Tafahi, Tasmania, Terres rares, Trace element analysis, Trace element concentrations, Trace elements, Uptake time, Yttrium.
- Teeft :
- Abundance samples, Analysis time, Analytical chemistry, Analytical sciences, Analytical sequence, Average precision, Bacl, Baoh, Basalt, Calibration, Calibration solutions, Calibration standards, Central science laboratory, Chemical geology, Chondrite, Critical evaluation, Detection limits, Digestion, Earth sciences, Eggins, Elements element, Exchange separation, Final dilution, Final rinse, Geoanalysis, Geoanalysis table, Geological materials, Geological samples, Geostandards, Geostandards newsletter, Good agreement, Good detection limits, High resolution, High resolution inductively, Higher resolution, Incipient dryness, Indium, Inductively, Internal standards, Ionov, Isotope, Isotope dilution mass spectrometry, Jarvis, Jenner, Joannon, Level analysis, Literature values, Lithium borate fusion, Little difference, Mafic rocks, Mass spectrum, Matrix, Matrix effects, Maximum signal intensity, Medium resolution, Memory effects, Ndoh, Newsletter, Other laboratories, Other studies, Other workers, Oxide, Oxide formation, Perkin elmer, Plasmamass spectrometry, Polyatomic interferences, Powder pellets, Precise determination, Pure quartz, Pure water, Quadrupole, Quadrupole instruments, Quartz, Rare earth elements, Reference material, Reference materials, Resolution mode, Rinsing solution, Rock reference materials, Rock samples, Sample blanks, Sample solution, Sampling depth, Scandium, Silicate, Smoh, Sodium peroxide sinter, Special issue, Spectral interferences, Spectrometry, Spray chamber, Standard deviation, Standard solutions, Tafahi, Tasmania, Terres rares, Trace element analysis, Trace element concentrations, Trace elements, Uptake time, Yttrium.
Abstract
The high sensitivity, minimal oxide formation and single internal standard capability of high resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) is demonstrated in the direct determination of Sc, Y and REE in the international reference materials: basalts (BCR‐1, BHVO‐1, BIR‐1, DNC‐1), andesite (AGV‐1) andultramafics (UB‐N, PCC‐1 and DTS‐1). Time consuming ion exchange separation or preconcentration were found to be unnecessary. Smooth chondrite normalized plots of the REE in PCC‐1 and DTS‐1 were obtained in the range 0.8‐50 ng g‐1 (0.01‐0.1x chondrite). Method precision was found to be digestion dependent with an average external repeatability of 2‐4% for the basalts, AGV‐1 and UB‐N, and 10% for PCC‐1 and DTS‐1. The mass peak due to 45Sc was completely resolved from 29Si16O and 28Si16O1H spectral interferences using medium resolution, which casts doubt on the accuracy of Sc determinations using quadrupole ICP‐MS. Literature values for Y in rock reference materials were found to be approximately 9% high after HR‐ICP‐MS and XRF analysis.
Url:
DOI: 10.1111/j.1751-908X.1999.tb00557.x
Affiliations:
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ISTEX:BCF698766F4B7A3E37395CC62EA6D71F1EF7B4EFLe document en format XML
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<term>Analysis time</term>
<term>Analytical chemistry</term>
<term>Analytical sciences</term>
<term>Analytical sequence</term>
<term>Average precision</term>
<term>Bacl</term>
<term>Baoh</term>
<term>Basalt</term>
<term>Calibration</term>
<term>Calibration solutions</term>
<term>Calibration standards</term>
<term>Central science laboratory</term>
<term>Chemical geology</term>
<term>Chondrite</term>
<term>Critical evaluation</term>
<term>Detection limits</term>
<term>Digestion</term>
<term>Earth sciences</term>
<term>Eggins</term>
<term>Elements element</term>
<term>Exchange separation</term>
<term>Final dilution</term>
<term>Final rinse</term>
<term>Geoanalysis</term>
<term>Geoanalysis table</term>
<term>Geological materials</term>
<term>Geological samples</term>
<term>Geostandards</term>
<term>Geostandards newsletter</term>
<term>Good agreement</term>
<term>Good detection limits</term>
<term>High resolution</term>
<term>High resolution inductively</term>
<term>Higher resolution</term>
<term>Incipient dryness</term>
<term>Indium</term>
<term>Inductively</term>
<term>Internal standards</term>
<term>Ionov</term>
<term>Isotope</term>
<term>Isotope dilution mass spectrometry</term>
<term>Jarvis</term>
<term>Jenner</term>
<term>Joannon</term>
<term>Level analysis</term>
<term>Literature values</term>
<term>Lithium borate fusion</term>
<term>Little difference</term>
<term>Mafic rocks</term>
<term>Mass spectrum</term>
<term>Matrix</term>
<term>Matrix effects</term>
<term>Maximum signal intensity</term>
<term>Medium resolution</term>
<term>Memory effects</term>
<term>Ndoh</term>
<term>Newsletter</term>
<term>Other laboratories</term>
<term>Other studies</term>
<term>Other workers</term>
<term>Oxide</term>
<term>Oxide formation</term>
<term>Perkin elmer</term>
<term>Plasmamass spectrometry</term>
<term>Polyatomic interferences</term>
<term>Powder pellets</term>
<term>Precise determination</term>
<term>Pure quartz</term>
<term>Pure water</term>
<term>Quadrupole</term>
<term>Quadrupole instruments</term>
<term>Quartz</term>
<term>Rare earth elements</term>
<term>Reference material</term>
<term>Reference materials</term>
<term>Resolution mode</term>
<term>Rinsing solution</term>
<term>Rock reference materials</term>
<term>Rock samples</term>
<term>Sample blanks</term>
<term>Sample solution</term>
<term>Sampling depth</term>
<term>Scandium</term>
<term>Silicate</term>
<term>Smoh</term>
<term>Sodium peroxide sinter</term>
<term>Special issue</term>
<term>Spectral interferences</term>
<term>Spectrometry</term>
<term>Spray chamber</term>
<term>Standard deviation</term>
<term>Standard solutions</term>
<term>Tafahi</term>
<term>Tasmania</term>
<term>Terres rares</term>
<term>Trace element analysis</term>
<term>Trace element concentrations</term>
<term>Trace elements</term>
<term>Uptake time</term>
<term>Yttrium</term>
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<term>Analysis time</term>
<term>Analytical chemistry</term>
<term>Analytical sciences</term>
<term>Analytical sequence</term>
<term>Average precision</term>
<term>Bacl</term>
<term>Baoh</term>
<term>Basalt</term>
<term>Calibration</term>
<term>Calibration solutions</term>
<term>Calibration standards</term>
<term>Central science laboratory</term>
<term>Chemical geology</term>
<term>Chondrite</term>
<term>Critical evaluation</term>
<term>Detection limits</term>
<term>Digestion</term>
<term>Earth sciences</term>
<term>Eggins</term>
<term>Elements element</term>
<term>Exchange separation</term>
<term>Final dilution</term>
<term>Final rinse</term>
<term>Geoanalysis</term>
<term>Geoanalysis table</term>
<term>Geological materials</term>
<term>Geological samples</term>
<term>Geostandards</term>
<term>Geostandards newsletter</term>
<term>Good agreement</term>
<term>Good detection limits</term>
<term>High resolution</term>
<term>High resolution inductively</term>
<term>Higher resolution</term>
<term>Incipient dryness</term>
<term>Indium</term>
<term>Inductively</term>
<term>Internal standards</term>
<term>Ionov</term>
<term>Isotope</term>
<term>Isotope dilution mass spectrometry</term>
<term>Jarvis</term>
<term>Jenner</term>
<term>Joannon</term>
<term>Level analysis</term>
<term>Literature values</term>
<term>Lithium borate fusion</term>
<term>Little difference</term>
<term>Mafic rocks</term>
<term>Mass spectrum</term>
<term>Matrix</term>
<term>Matrix effects</term>
<term>Maximum signal intensity</term>
<term>Medium resolution</term>
<term>Memory effects</term>
<term>Ndoh</term>
<term>Newsletter</term>
<term>Other laboratories</term>
<term>Other studies</term>
<term>Other workers</term>
<term>Oxide</term>
<term>Oxide formation</term>
<term>Perkin elmer</term>
<term>Plasmamass spectrometry</term>
<term>Polyatomic interferences</term>
<term>Powder pellets</term>
<term>Precise determination</term>
<term>Pure quartz</term>
<term>Pure water</term>
<term>Quadrupole</term>
<term>Quadrupole instruments</term>
<term>Quartz</term>
<term>Rare earth elements</term>
<term>Reference material</term>
<term>Reference materials</term>
<term>Resolution mode</term>
<term>Rinsing solution</term>
<term>Rock reference materials</term>
<term>Rock samples</term>
<term>Sample blanks</term>
<term>Sample solution</term>
<term>Sampling depth</term>
<term>Scandium</term>
<term>Silicate</term>
<term>Smoh</term>
<term>Sodium peroxide sinter</term>
<term>Special issue</term>
<term>Spectral interferences</term>
<term>Spectrometry</term>
<term>Spray chamber</term>
<term>Standard deviation</term>
<term>Standard solutions</term>
<term>Tafahi</term>
<term>Tasmania</term>
<term>Terres rares</term>
<term>Trace element analysis</term>
<term>Trace element concentrations</term>
<term>Trace elements</term>
<term>Uptake time</term>
<term>Yttrium</term>
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<front><div type="abstract" xml:lang="en">The high sensitivity, minimal oxide formation and single internal standard capability of high resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) is demonstrated in the direct determination of Sc, Y and REE in the international reference materials: basalts (BCR‐1, BHVO‐1, BIR‐1, DNC‐1), andesite (AGV‐1) andultramafics (UB‐N, PCC‐1 and DTS‐1). Time consuming ion exchange separation or preconcentration were found to be unnecessary. Smooth chondrite normalized plots of the REE in PCC‐1 and DTS‐1 were obtained in the range 0.8‐50 ng g‐1 (0.01‐0.1x chondrite). Method precision was found to be digestion dependent with an average external repeatability of 2‐4% for the basalts, AGV‐1 and UB‐N, and 10% for PCC‐1 and DTS‐1. The mass peak due to 45Sc was completely resolved from 29Si16O and 28Si16O1H spectral interferences using medium resolution, which casts doubt on the accuracy of Sc determinations using quadrupole ICP‐MS. Literature values for Y in rock reference materials were found to be approximately 9% high after HR‐ICP‐MS and XRF analysis.</div>
</front>
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<tree><country name="Australie"><noRegion><name sortKey="Robinson, Philip" sort="Robinson, Philip" uniqKey="Robinson P" first="Philip" last="Robinson">Philip Robinson</name>
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<name sortKey="Munker, Carsten" sort="Munker, Carsten" uniqKey="Munker C" first="Carsten" last="Münker">Carsten Münker</name>
<name sortKey="Townsend, Ashley T" sort="Townsend, Ashley T" uniqKey="Townsend A" first="Ashley T." last="Townsend">Ashley T. Townsend</name>
<name sortKey="Yu, Zongshou" sort="Yu, Zongshou" uniqKey="Yu Z" first="Zongshou" last="Yu">Zongshou Yu</name>
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