Structural, solid-gas and electrochemical characterization of Mg2Ni-rich and MgxNi100-x amorphous-rich nanomaterials obtained by mechanical alloying
Identifieur interne :
000153 ( PascalFrancis/Curation );
précédent :
000152;
suivant :
000154
Structural, solid-gas and electrochemical characterization of Mg2Ni-rich and MgxNi100-x amorphous-rich nanomaterials obtained by mechanical alloying
Auteurs : M. Abdellaoui [
Tunisie] ;
S. Mokbli [
Tunisie] ;
F. Cuevas [
France] ;
M. Latroche [
France] ;
A. Percheron Guegan [
France] ;
H. Zarrouk [
Tunisie]
Source :
-
International journal of hydrogen energy [ 0360-3199 ] ; 2006.
RBID : Pascal:06-0233034
Descripteurs français
English descriptors
Abstract
Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg2Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol-1 (3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg2Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg40Ni60 and Mg60Ni40 samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg50Ni50 sample obtained at milling duration 10 times shorter than that reported in the literature.
pA |
A01 | 01 | 1 | | @0 0360-3199 |
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A02 | 01 | | | @0 IJHEDX |
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A03 | | 1 | | @0 Int. j. hydrogen energy |
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A05 | | | | @2 31 |
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A06 | | | | @2 2 |
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A08 | 01 | 1 | ENG | @1 Structural, solid-gas and electrochemical characterization of Mg2Ni-rich and MgxNi100-x amorphous-rich nanomaterials obtained by mechanical alloying |
---|
A09 | 01 | 1 | ENG | @1 HTM 2004 Hydrogen treatment of materials |
---|
A11 | 01 | 1 | | @1 ABDELLAOUI (M.) |
---|
A11 | 02 | 1 | | @1 MOKBLI (S.) |
---|
A11 | 03 | 1 | | @1 CUEVAS (F.) |
---|
A11 | 04 | 1 | | @1 LATROCHE (M.) |
---|
A11 | 05 | 1 | | @1 PERCHERON GUEGAN (A.) |
---|
A11 | 06 | 1 | | @1 ZARROUK (H.) |
---|
A12 | 01 | 1 | | @1 GOLTSOV (V. A.) @9 ed. |
---|
A14 | 01 | | | @1 INRAP, Pôle technologique de Sidi Thabet 2020 @2 Sidi Thabet @3 TUN @Z 1 aut. @Z 2 aut. @Z 6 aut. |
---|
A14 | 02 | | | @1 LCMTR, CNRS, 2-8, rue Henri Dunant @2 94320 Thiais @3 FRA @Z 3 aut. @Z 4 aut. @Z 5 aut. |
---|
A20 | | | | @1 247-250 |
---|
A21 | | | | @1 2006 |
---|
A23 | 01 | | | @0 ENG |
---|
A43 | 01 | | | @1 INIST @2 17522 @5 354000132990040140 |
---|
A44 | | | | @0 0000 @1 © 2006 INIST-CNRS. All rights reserved. |
---|
A45 | | | | @0 7 ref. |
---|
A47 | 01 | 1 | | @0 06-0233034 |
---|
A60 | | | | @1 P @2 C |
---|
A61 | | | | @0 A |
---|
A64 | 01 | 1 | | @0 International journal of hydrogen energy |
---|
A66 | 01 | | | @0 GBR |
---|
C01 | 01 | | ENG | @0 Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg2Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol-1 (3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg2Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg40Ni60 and Mg60Ni40 samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg50Ni50 sample obtained at milling duration 10 times shorter than that reported in the literature. |
---|
C02 | 01 | X | | @0 001D05I03E |
---|
C03 | 01 | X | FRE | @0 Accumulateur électrochimique @5 05 |
---|
C03 | 01 | X | ENG | @0 Secondary cell @5 05 |
---|
C03 | 01 | X | SPA | @0 Acumulador electroquímico @5 05 |
---|
C03 | 02 | X | FRE | @0 Alliage mécanique @5 06 |
---|
C03 | 02 | X | ENG | @0 Mechanical alloying @5 06 |
---|
C03 | 02 | X | SPA | @0 Aleación mecánico @5 06 |
---|
C03 | 03 | X | FRE | @0 Broyeur satellite @5 07 |
---|
C03 | 03 | X | ENG | @0 Planetary mill @5 07 |
---|
C03 | 03 | X | SPA | @0 Molino rodillos satelite @5 07 |
---|
C03 | 04 | X | FRE | @0 Broyeur boulet @5 08 |
---|
C03 | 04 | X | ENG | @0 Ball mill @5 08 |
---|
C03 | 04 | X | SPA | @0 Molino bolas @5 08 |
---|
C03 | 05 | X | FRE | @0 Magnésium Nickel Alliage @2 NC @2 FR @2 FX @2 NA @5 09 |
---|
C03 | 05 | X | ENG | @0 Magnesium Nickel Alloys @2 NC @2 FR @2 FX @2 NA @5 09 |
---|
C03 | 05 | X | SPA | @0 Magnesio Niquel Aleación @2 NC @2 FR @2 FX @2 NA @5 09 |
---|
C03 | 06 | X | FRE | @0 Nanocomposite @5 10 |
---|
C03 | 06 | X | ENG | @0 Nanocomposite @5 10 |
---|
C03 | 06 | X | SPA | @0 Nanocompuesto @5 10 |
---|
C03 | 07 | 3 | FRE | @0 Nanomatériau @5 11 |
---|
C03 | 07 | 3 | ENG | @0 Nanostructured materials @5 11 |
---|
C03 | 08 | X | FRE | @0 Hydrogène @2 NC @5 12 |
---|
C03 | 08 | X | ENG | @0 Hydrogen @2 NC @5 12 |
---|
C03 | 08 | X | SPA | @0 Hidrógeno @2 NC @5 12 |
---|
C03 | 09 | X | FRE | @0 Alliage amorphe @5 13 |
---|
C03 | 09 | X | ENG | @0 Amorphous alloy @5 13 |
---|
C03 | 09 | X | SPA | @0 Aleación amorfa @5 13 |
---|
C03 | 10 | X | FRE | @0 Caractéristique électrochimique @5 14 |
---|
C03 | 10 | X | ENG | @0 Electrochemical characteristic @5 14 |
---|
C03 | 10 | X | SPA | @0 Característica electroquímica @5 14 |
---|
N21 | | | | @1 149 |
---|
|
pR |
A30 | 01 | 1 | ENG | @1 Hydrogen Treatment of Materials International Conference @2 4 @3 Donetsk UKR @4 2004-05-17 |
---|
|
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Ni-rich and Mg<sub>x</sub>
Ni<sub>100-x</sub>
amorphous-rich nanomaterials obtained by mechanical alloying</title>
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amorphous-rich nanomaterials obtained by mechanical alloying</title>
<author><name sortKey="Abdellaoui, M" sort="Abdellaoui, M" uniqKey="Abdellaoui M" first="M." last="Abdellaoui">M. Abdellaoui</name>
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<front><div type="abstract" xml:lang="en">Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg<sub>2</sub>
Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol<sup>-1</sup>
(3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg<sub>2</sub>
Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg<sub>40</sub>
Ni<sub>60</sub>
and Mg<sub>60</sub>
Ni<sub>40</sub>
samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg<sub>50</sub>
Ni<sub>50</sub>
sample obtained at milling duration 10 times shorter than that reported in the literature.</div>
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Ni-rich and Mg<sub>x</sub>
Ni<sub>100-x</sub>
amorphous-rich nanomaterials obtained by mechanical alloying</s1>
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<fA09 i1="01" i2="1" l="ENG"><s1>HTM 2004 Hydrogen treatment of materials</s1>
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<fC01 i1="01" l="ENG"><s0>Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg<sub>2</sub>
Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol<sup>-1</sup>
(3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg<sub>2</sub>
Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg<sub>40</sub>
Ni<sub>60</sub>
and Mg<sub>60</sub>
Ni<sub>40</sub>
samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg<sub>50</sub>
Ni<sub>50</sub>
sample obtained at milling duration 10 times shorter than that reported in the literature.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D05I03E</s0>
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<s5>05</s5>
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<fC03 i1="02" i2="X" l="SPA"><s0>Aleación mecánico</s0>
<s5>06</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Broyeur satellite</s0>
<s5>07</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Planetary mill</s0>
<s5>07</s5>
</fC03>
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<s5>07</s5>
</fC03>
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<s5>08</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Ball mill</s0>
<s5>08</s5>
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<fC03 i1="04" i2="X" l="SPA"><s0>Molino bolas</s0>
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<fC03 i1="05" i2="X" l="FRE"><s0>Magnésium Nickel Alliage</s0>
<s2>NC</s2>
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<s5>09</s5>
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<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Magnesio Niquel Aleación</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Nanocomposite</s0>
<s5>10</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Nanocomposite</s0>
<s5>10</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Nanocompuesto</s0>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Nanomatériau</s0>
<s5>11</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Nanostructured materials</s0>
<s5>11</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Hydrogène</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Hydrogen</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Hidrógeno</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Alliage amorphe</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Amorphous alloy</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Aleación amorfa</s0>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Caractéristique électrochimique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Electrochemical characteristic</s0>
<s5>14</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Característica electroquímica</s0>
<s5>14</s5>
</fC03>
<fN21><s1>149</s1>
</fN21>
</pA>
<pR><fA30 i1="01" i2="1" l="ENG"><s1>Hydrogen Treatment of Materials International Conference</s1>
<s2>4</s2>
<s3>Donetsk UKR</s3>
<s4>2004-05-17</s4>
</fA30>
</pR>
</standard>
</inist>
</record>
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