NickelMaghrebV1, PascalFrancis, Corpus, bibRecord, 000288

Structural, solid-gas and electrochemical characterization of Mg2Ni-rich and MgxNi100-x amorphous-rich nanomaterials obtained by mechanical alloying

Identifieur interne : 000288 ( PascalFrancis/Corpus ); précédent : 000287; suivant : 000289

Structural, solid-gas and electrochemical characterization of Mg2Ni-rich and MgxNi100-x amorphous-rich nanomaterials obtained by mechanical alloying

Auteurs : M. Abdellaoui ; S. Mokbli ; F. Cuevas ; M. Latroche ; A. Percheron Guegan ; H. Zarrouk

Source :

International journal of hydrogen energy [ 0360-3199 ] ; 2006.

RBID : Pascal:06-0233034

Descripteurs français

Pascal (Inist)
- Accumulateur électrochimique, Alliage mécanique, Broyeur satellite, Broyeur boulet, Magnésium Nickel Alliage, Nanocomposite, Nanomatériau, Hydrogène, Alliage amorphe, Caractéristique électrochimique.

English descriptors

KwdEn :
- Amorphous alloy, Ball mill, Electrochemical characteristic, Hydrogen, Magnesium Nickel Alloys, Mechanical alloying, Nanocomposite, Nanostructured materials, Planetary mill, Secondary cell.

Abstract

Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg₂Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol^-1 (3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg₂Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg₄₀Ni₆₀ and Mg₆₀Ni₄₀ samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg₅₀Ni₅₀ sample obtained at milling duration 10 times shorter than that reported in the literature.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0360-3199`
A02	`01`			`@0 IJHEDX`
A03		`1`		`@0 Int. j. hydrogen energy`
A05				`@2 31`
A06				`@2 2`
A08	`01`	`1`	`ENG`	`@1 Structural, solid-gas and electrochemical characterization of Mg₂Ni-rich and Mg_xNi_100-x amorphous-rich nanomaterials obtained by mechanical alloying`
A09	`01`	`1`	`ENG`	`@1 HTM 2004 Hydrogen treatment of materials`
A11	`01`	`1`		`@1 ABDELLAOUI (M.)`
A11	`02`	`1`		`@1 MOKBLI (S.)`
A11	`03`	`1`		`@1 CUEVAS (F.)`
A11	`04`	`1`		`@1 LATROCHE (M.)`
A11	`05`	`1`		`@1 PERCHERON GUEGAN (A.)`
A11	`06`	`1`		`@1 ZARROUK (H.)`
A12	`01`	`1`		`@1 GOLTSOV (V. A.) @9 ed.`
A14	`01`			`@1 INRAP, Pôle technologique de Sidi Thabet 2020 @2 Sidi Thabet @3 TUN @Z 1 aut. @Z 2 aut. @Z 6 aut.`
A14	`02`			`@1 LCMTR, CNRS, 2-8, rue Henri Dunant @2 94320 Thiais @3 FRA @Z 3 aut. @Z 4 aut. @Z 5 aut.`
A20				`@1 247-250`
A21				`@1 2006`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 17522 @5 354000132990040140`
A44				`@0 0000 @1 © 2006 INIST-CNRS. All rights reserved.`
A45				`@0 7 ref.`
A47	`01`	`1`		`@0 06-0233034`
A60				`@1 P @2 C`
A61				`@0 A`
A64	`01`	`1`		`@0 International journal of hydrogen energy`
A66	`01`			`@0 GBR`
C01	`01`		`ENG`	@0 Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg₂Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol^-1 (3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg₂Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg₄₀Ni₆₀ and Mg₆₀Ni₄₀ samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg₅₀Ni₅₀ sample obtained at milling duration 10 times shorter than that reported in the literature.
C02	`01`	`X`		`@0 001D05I03E`
C03	`01`	`X`	`FRE`	`@0 Accumulateur électrochimique @5 05`
C03	`01`	`X`	`ENG`	`@0 Secondary cell @5 05`
C03	`01`	`X`	`SPA`	`@0 Acumulador electroquímico @5 05`
C03	`02`	`X`	`FRE`	`@0 Alliage mécanique @5 06`
C03	`02`	`X`	`ENG`	`@0 Mechanical alloying @5 06`
C03	`02`	`X`	`SPA`	`@0 Aleación mecánico @5 06`
C03	`03`	`X`	`FRE`	`@0 Broyeur satellite @5 07`
C03	`03`	`X`	`ENG`	`@0 Planetary mill @5 07`
C03	`03`	`X`	`SPA`	`@0 Molino rodillos satelite @5 07`
C03	`04`	`X`	`FRE`	`@0 Broyeur boulet @5 08`
C03	`04`	`X`	`ENG`	`@0 Ball mill @5 08`
C03	`04`	`X`	`SPA`	`@0 Molino bolas @5 08`
C03	`05`	`X`	`FRE`	`@0 Magnésium Nickel Alliage @2 NC @2 FR @2 FX @2 NA @5 09`
C03	`05`	`X`	`ENG`	`@0 Magnesium Nickel Alloys @2 NC @2 FR @2 FX @2 NA @5 09`
C03	`05`	`X`	`SPA`	`@0 Magnesio Niquel Aleación @2 NC @2 FR @2 FX @2 NA @5 09`
C03	`06`	`X`	`FRE`	`@0 Nanocomposite @5 10`
C03	`06`	`X`	`ENG`	`@0 Nanocomposite @5 10`
C03	`06`	`X`	`SPA`	`@0 Nanocompuesto @5 10`
C03	`07`	`3`	`FRE`	`@0 Nanomatériau @5 11`
C03	`07`	`3`	`ENG`	`@0 Nanostructured materials @5 11`
C03	`08`	`X`	`FRE`	`@0 Hydrogène @2 NC @5 12`
C03	`08`	`X`	`ENG`	`@0 Hydrogen @2 NC @5 12`
C03	`08`	`X`	`SPA`	`@0 Hidrógeno @2 NC @5 12`
C03	`09`	`X`	`FRE`	`@0 Alliage amorphe @5 13`
C03	`09`	`X`	`ENG`	`@0 Amorphous alloy @5 13`
C03	`09`	`X`	`SPA`	`@0 Aleación amorfa @5 13`
C03	`10`	`X`	`FRE`	`@0 Caractéristique électrochimique @5 14`
C03	`10`	`X`	`ENG`	`@0 Electrochemical characteristic @5 14`
C03	`10`	`X`	`SPA`	`@0 Característica electroquímica @5 14`
N21				`@1 149`

A30	`01`	`1`	`ENG`	`@1 Hydrogen Treatment of Materials International Conference @2 4 @3 Donetsk UKR @4 2004-05-17`

Format Inist (serveur)

NO :	PASCAL 06-0233034 INIST
ET :	Structural, solid-gas and electrochemical characterization of Mg₂Ni-rich and Mg_xNi_100-x amorphous-rich nanomaterials obtained by mechanical alloying
AU :	ABDELLAOUI (M.); MOKBLI (S.); CUEVAS (F.); LATROCHE (M.); PERCHERON GUEGAN (A.); ZARROUK (H.); GOLTSOV (V. A.)
AF :	INRAP, Pôle technologique de Sidi Thabet 2020/Sidi Thabet/Tunisie (1 aut., 2 aut., 6 aut.); LCMTR, CNRS, 2-8, rue Henri Dunant/94320 Thiais/France (3 aut., 4 aut., 5 aut.)
DT :	Publication en série; Congrès; Niveau analytique
SO :	International journal of hydrogen energy; ISSN 0360-3199; Coden IJHEDX; Royaume-Uni; Da. 2006; Vol. 31; No. 2; Pp. 247-250; Bibl. 7 ref.
LA :	Anglais
EA :	Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg₂Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol^-1 (3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg₂Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg₄₀Ni₆₀ and Mg₆₀Ni₄₀ samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg₅₀Ni₅₀ sample obtained at milling duration 10 times shorter than that reported in the literature.
CC :	001D05I03E
FD :	Accumulateur électrochimique; Alliage mécanique; Broyeur satellite; Broyeur boulet; Magnésium Nickel Alliage; Nanocomposite; Nanomatériau; Hydrogène; Alliage amorphe; Caractéristique électrochimique
ED :	Secondary cell; Mechanical alloying; Planetary mill; Ball mill; Magnesium Nickel Alloys; Nanocomposite; Nanostructured materials; Hydrogen; Amorphous alloy; Electrochemical characteristic
SD :	Acumulador electroquímico; Aleación mecánico; Molino rodillos satelite; Molino bolas; Magnesio Niquel Aleación; Nanocompuesto; Hidrógeno; Aleación amorfa; Característica electroquímica
LO :	INIST-17522.354000132990040140
ID :	06-0233034

Links to Exploration step

Pascal:06-0233034

Le document en format XML

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 amorphous-rich nanomaterials obtained by mechanical alloying</title>
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 amorphous-rich nanomaterials obtained by mechanical alloying</title>
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<front><div type="abstract" xml:lang="en">Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg<sub>2</sub>
Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol<sup>-1</sup>
 (3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg<sub>2</sub>
Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg<sub>40</sub>
Ni<sub>60</sub>
 and Mg<sub>60</sub>
Ni<sub>40</sub>
 samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg<sub>50</sub>
Ni<sub>50</sub>
 sample obtained at milling duration 10 times shorter than that reported in the literature.</div>
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 amorphous-rich nanomaterials obtained by mechanical alloying</s1>
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<fC01 i1="01" l="ENG"><s0>Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg<sub>2</sub>
Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol<sup>-1</sup>
 (3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg<sub>2</sub>
Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg<sub>40</sub>
Ni<sub>60</sub>
 and Mg<sub>60</sub>
Ni<sub>40</sub>
 samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg<sub>50</sub>
Ni<sub>50</sub>
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</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Accumulateur électrochimique</s0>
<s5>05</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Secondary cell</s0>
<s5>05</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Acumulador electroquímico</s0>
<s5>05</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Alliage mécanique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Mechanical alloying</s0>
<s5>06</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Aleación mecánico</s0>
<s5>06</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Broyeur satellite</s0>
<s5>07</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Planetary mill</s0>
<s5>07</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Molino rodillos satelite</s0>
<s5>07</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Broyeur boulet</s0>
<s5>08</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Ball mill</s0>
<s5>08</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Molino bolas</s0>
<s5>08</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Magnésium Nickel Alliage</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Magnesium Nickel Alloys</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Magnesio Niquel Aleación</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Nanocomposite</s0>
<s5>10</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Nanocomposite</s0>
<s5>10</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Nanocompuesto</s0>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Nanomatériau</s0>
<s5>11</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Nanostructured materials</s0>
<s5>11</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Hydrogène</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Hydrogen</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Hidrógeno</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Alliage amorphe</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Amorphous alloy</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Aleación amorfa</s0>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Caractéristique électrochimique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Electrochemical characteristic</s0>
<s5>14</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Característica electroquímica</s0>
<s5>14</s5>
</fC03>
<fN21><s1>149</s1>
</fN21>
</pA>
<pR><fA30 i1="01" i2="1" l="ENG"><s1>Hydrogen Treatment of Materials International Conference</s1>
<s2>4</s2>
<s3>Donetsk UKR</s3>
<s4>2004-05-17</s4>
</fA30>
</pR>
</standard>
<server><NO>PASCAL 06-0233034 INIST</NO>
<ET>Structural, solid-gas and electrochemical characterization of Mg<sub>2</sub>
Ni-rich and Mg<sub>x</sub>
Ni<sub>100-x</sub>
 amorphous-rich nanomaterials obtained by mechanical alloying</ET>
<AU>ABDELLAOUI (M.); MOKBLI (S.); CUEVAS (F.); LATROCHE (M.); PERCHERON GUEGAN (A.); ZARROUK (H.); GOLTSOV (V. A.)</AU>
<AF>INRAP, Pôle technologique de Sidi Thabet 2020/Sidi Thabet/Tunisie (1 aut., 2 aut., 6 aut.); LCMTR, CNRS, 2-8, rue Henri Dunant/94320 Thiais/France (3 aut., 4 aut., 5 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>International journal of hydrogen energy; ISSN 0360-3199; Coden IJHEDX; Royaume-Uni; Da. 2006; Vol. 31; No. 2; Pp. 247-250; Bibl. 7 ref.</SO>
<LA>Anglais</LA>
<EA>Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we successfully elaborated a nanocomposite material formed by the Mg<sub>2</sub>
Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding to 3.5 and 10 W/g shock power, respectively, after 18 and 4h. The best hydrogen absorption capacity reported, 3.75 H mol<sup>-1</sup>
 (3.53 wt%) is for the composite synthesized for 24 h at 3.5 W/g shock power. Using the same planetary ball mill and starting from a mixture of Mg<sub>2</sub>
Ni and Ni with a Mg atomic content ranging from 40 to 60at%, we elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W/g shock power, for milling durations ranging from 8 to 101 h for Mg<sub>40</sub>
Ni<sub>60</sub>
 and Mg<sub>60</sub>
Ni<sub>40</sub>
 samples, respectively. The best electrochemical capacity (470mAh/g) was obtained for the Mg<sub>50</sub>
Ni<sub>50</sub>
 sample obtained at milling duration 10 times shorter than that reported in the literature.</EA>
<CC>001D05I03E</CC>
<FD>Accumulateur électrochimique; Alliage mécanique; Broyeur satellite; Broyeur boulet; Magnésium Nickel Alliage; Nanocomposite; Nanomatériau; Hydrogène; Alliage amorphe; Caractéristique électrochimique</FD>
<ED>Secondary cell; Mechanical alloying; Planetary mill; Ball mill; Magnesium Nickel Alloys; Nanocomposite; Nanostructured materials; Hydrogen; Amorphous alloy; Electrochemical characteristic</ED>
<SD>Acumulador electroquímico; Aleación mecánico; Molino rodillos satelite; Molino bolas; Magnesio Niquel Aleación; Nanocompuesto; Hidrógeno; Aleación amorfa; Característica electroquímica</SD>
<LO>INIST-17522.354000132990040140</LO>
<ID>06-0233034</ID>
</server>
</inist>
</record>

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Structural, solid-gas and electrochemical characterization of Mg2Ni-rich and MgxNi100-x amorphous-rich nanomaterials obtained by mechanical alloying

Structural, solid-gas and electrochemical characterization of Mg2Ni-rich and MgxNi100-x amorphous-rich nanomaterials obtained by mechanical alloying

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