NickelMaghrebV1, Main, Exploration, bibRecord, 000C71

Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II ) monohydrate

Identifieur interne : 000C71 ( Main/Exploration ); précédent : 000C70; suivant : 000C72

Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II ) monohydrate

Auteurs : S. Namouchi-Cherni [Tunisie] ; A. Driss [Tunisie] ; Tahar Jouini [Tunisie]

Source :

Acta crystallographica. Section C, Crystal structure communications [ 0108-2701 ] ; 1999.

RBID : Pascal:99-0194411

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Diffraction RX, Structure cristalline, Structure moléculaire, Nickel II Complexe, Coordinat organique, Hétérocycle azote, Macrocycle, Composé crown azote, Hydrate, Liaison hydrogène, 6166F, Complexe dihydrogénophosphato, Tétraaza-14-crown-4.

English descriptors

KwdEn :
- Crystal structure, Experimental study, Hydrates, Hydrogen bonds, Macrocycle, Molecular structure, Nickel II Complexes, Nitrogen crown compound, Nitrogen heterocycle, Organic ligand, XRD.

Abstract

The Ni^II ion in the title compound, [Ni(H₂PO₄)₂(C₁₀H₂₄N₄)].H₂O, is six-coordinate in a distorted square-bipyramidal environment. Four N atoms from the tetraaza-macrocycle are in a square-planar arrangement [average Ni-N distance = 2.071 (2) Å] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.144 (2) Å]. The structure of the title complex forms a three-dimensional framework, which delimits intersecting b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H...O and N-H...O, ensure the cohesion and stability of the molecular packing.

Affiliations:

Links toward previous steps (curation, corpus...)

to stream PascalFrancis, to step Corpus: 000466
to stream PascalFrancis, to step Curation: 000601
to stream PascalFrancis, to step Checkpoint: 000462
to stream Main, to step Merge: 000D11
to stream Main, to step Curation: 000C71

Le document en format XML

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N]nickel(II ) monohydrate</title>
<author><name sortKey="Namouchi Cherni, S" sort="Namouchi Cherni, S" uniqKey="Namouchi Cherni S" first="S." last="Namouchi-Cherni">S. Namouchi-Cherni</name>
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</author>
<author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">Tahar Jouini</name>
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<placeName><settlement type="city">Tunis</settlement>
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<orgName type="university" n="3">Université de Tunis - El Manar</orgName>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ<sup>4</sup>
N]nickel(II ) monohydrate</title>
<author><name sortKey="Namouchi Cherni, S" sort="Namouchi Cherni, S" uniqKey="Namouchi Cherni S" first="S." last="Namouchi-Cherni">S. Namouchi-Cherni</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, Campus Universitaire</s1>
<s2>1060 Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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</inist:fA14>
<country>Tunisie</country>
<placeName><settlement type="city">Tunis</settlement>
<region nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A." last="Driss">A. Driss</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, Campus Universitaire</s1>
<s2>1060 Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Tunisie</country>
<placeName><settlement type="city">Tunis</settlement>
<region nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">Tahar Jouini</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, Campus Universitaire</s1>
<s2>1060 Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Tunisie</country>
<placeName><settlement type="city">Tunis</settlement>
<region nuts="2">Gouvernorat de Tunis</region>
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<placeName><settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
<orgName type="university" n="3">Université de Tunis - El Manar</orgName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
<imprint><date when="1999">1999</date>
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<seriesStmt><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Crystal structure</term>
<term>Experimental study</term>
<term>Hydrates</term>
<term>Hydrogen bonds</term>
<term>Macrocycle</term>
<term>Molecular structure</term>
<term>Nickel II Complexes</term>
<term>Nitrogen crown compound</term>
<term>Nitrogen heterocycle</term>
<term>Organic ligand</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Structure moléculaire</term>
<term>Nickel II Complexe</term>
<term>Coordinat organique</term>
<term>Hétérocycle azote</term>
<term>Macrocycle</term>
<term>Composé crown azote</term>
<term>Hydrate</term>
<term>Liaison hydrogène</term>
<term>6166F</term>
<term>Complexe dihydrogénophosphato</term>
<term>Tétraaza-14-crown-4</term>
</keywords>
</textClass>
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</teiHeader>
<front><div type="abstract" xml:lang="en">The Ni<sup>II</sup>
 ion in the title compound, [Ni(H<sub>2</sub>
PO<sub>4</sub>
)<sub>2</sub>
(C<sub>10</sub>
H<sub>24</sub>
N<sub>4</sub>
)].H<sub>2</sub>
O, is six-coordinate in a distorted square-bipyramidal environment. Four N atoms from the tetraaza-macrocycle are in a square-planar arrangement [average Ni-N distance = 2.071 (2) Å] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.144 (2) Å]. The structure of the title complex forms a three-dimensional framework, which delimits intersecting b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H...O and N-H...O, ensure the cohesion and stability of the molecular packing.</div>
</front>
</TEI>
<affiliations><list><country><li>Tunisie</li>
</country>
<region><li>Gouvernorat de Tunis</li>
</region>
<settlement><li>Tunis</li>
</settlement>
<orgName><li>Université de Tunis - El Manar</li>
</orgName>
</list>
<tree><country name="Tunisie"><region name="Gouvernorat de Tunis"><name sortKey="Namouchi Cherni, S" sort="Namouchi Cherni, S" uniqKey="Namouchi Cherni S" first="S." last="Namouchi-Cherni">S. Namouchi-Cherni</name>
</region>
<name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A." last="Driss">A. Driss</name>
<name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">Tahar Jouini</name>
</country>
</tree>
</affiliations>
</record>

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Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II ) monohydrate

Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II ) monohydrate

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri