NickelMaghrebV1, PascalFrancis, Corpus, bibRecord, 000466

Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II ) monohydrate

Identifieur interne : 000466 ( PascalFrancis/Corpus ); précédent : 000465; suivant : 000467

Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II ) monohydrate

Auteurs : S. Namouchi-Cherni ; A. Driss ; T. Jouini

Source :

Acta crystallographica. Section C, Crystal structure communications [ 0108-2701 ] ; 1999.

RBID : Pascal:99-0194411

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Diffraction RX, Structure cristalline, Structure moléculaire, Nickel II Complexe, Coordinat organique, Hétérocycle azote, Macrocycle, Composé crown azote, Hydrate, Liaison hydrogène, 6166F, Complexe dihydrogénophosphato, Tétraaza-14-crown-4.

English descriptors

KwdEn :
- Crystal structure, Experimental study, Hydrates, Hydrogen bonds, Macrocycle, Molecular structure, Nickel II Complexes, Nitrogen crown compound, Nitrogen heterocycle, Organic ligand, XRD.

Abstract

The Ni^II ion in the title compound, [Ni(H₂PO₄)₂(C₁₀H₂₄N₄)].H₂O, is six-coordinate in a distorted square-bipyramidal environment. Four N atoms from the tetraaza-macrocycle are in a square-planar arrangement [average Ni-N distance = 2.071 (2) Å] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.144 (2) Å]. The structure of the title complex forms a three-dimensional framework, which delimits intersecting b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H...O and N-H...O, ensure the cohesion and stability of the molecular packing.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0108-2701`
A02	`01`			`@0 ACSCEE`
A03		`1`		`@0 Acta crystallogr., Sect. C Cryst. struct. commun.`
A05				`@2 55`
A06				`@3 p.3`
A08	`01`	`1`	`ENG`	`@1 Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ⁴N]nickel(II ) monohydrate`
A11	`01`	`1`		`@1 NAMOUCHI-CHERNI (S.)`
A11	`02`	`1`		`@1 DRISS (A.)`
A11	`03`	`1`		`@1 JOUINI (T.)`
A14	`01`			`@1 Département de Chimie, Faculté des Sciences, Campus Universitaire @2 1060 Tunis @3 TUN @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A20				`@1 345-347`
A21				`@1 1999`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 5160C @5 354000075008050340`
A44				`@0 0000 @1 © 1999 INIST-CNRS. All rights reserved.`
A45				`@0 12 ref.`
A47	`01`	`1`		`@0 99-0194411`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Acta crystallographica. Section C, Crystal structure communications`
A66	`01`			`@0 DNK`
C01	`01`		`ENG`	@0 The Ni^II ion in the title compound, [Ni(H₂PO₄)₂(C₁₀H₂₄N₄)].H₂O, is six-coordinate in a distorted square-bipyramidal environment. Four N atoms from the tetraaza-macrocycle are in a square-planar arrangement [average Ni-N distance = 2.071 (2) Å] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.144 (2) Å]. The structure of the title complex forms a three-dimensional framework, which delimits intersecting b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H...O and N-H...O, ensure the cohesion and stability of the molecular packing.
C02	`01`	`3`		`@0 001B60A66F5`
C03	`01`	`3`	`FRE`	`@0 Etude expérimentale @5 01`
C03	`01`	`3`	`ENG`	`@0 Experimental study @5 01`
C03	`02`	`3`	`FRE`	`@0 Diffraction RX @5 02`
C03	`02`	`3`	`ENG`	`@0 XRD @5 02`
C03	`03`	`3`	`FRE`	`@0 Structure cristalline @5 03`
C03	`03`	`3`	`ENG`	`@0 Crystal structure @5 03`
C03	`04`	`3`	`FRE`	`@0 Structure moléculaire @5 04`
C03	`04`	`3`	`ENG`	`@0 Molecular structure @5 04`
C03	`05`	`X`	`FRE`	`@0 Nickel II Complexe @2 NC @2 NA @5 05 @6 Nickel «II» Complexe`
C03	`05`	`X`	`ENG`	`@0 Nickel II Complexes @2 NC @2 NA @5 05 @6 Nickel «II» Complexes`
C03	`05`	`X`	`SPA`	`@0 Niquel II Complejo @2 NC @2 NA @5 05 @6 Niquel «II» Complejo`
C03	`06`	`X`	`FRE`	`@0 Coordinat organique @5 06`
C03	`06`	`X`	`ENG`	`@0 Organic ligand @5 06`
C03	`06`	`X`	`SPA`	`@0 Ligando orgánico @5 06`
C03	`07`	`X`	`FRE`	`@0 Hétérocycle azote @5 07`
C03	`07`	`X`	`ENG`	`@0 Nitrogen heterocycle @5 07`
C03	`07`	`X`	`SPA`	`@0 Heterociclo nitrógeno @5 07`
C03	`08`	`X`	`FRE`	`@0 Macrocycle @5 08`
C03	`08`	`X`	`ENG`	`@0 Macrocycle @5 08`
C03	`08`	`X`	`SPA`	`@0 Macrociclo @5 08`
C03	`09`	`X`	`FRE`	`@0 Composé crown azote @5 09`
C03	`09`	`X`	`ENG`	`@0 Nitrogen crown compound @5 09`
C03	`09`	`X`	`SPA`	`@0 Compuesto crown nitrógeno @5 09`
C03	`10`	`3`	`FRE`	`@0 Hydrate @2 NA @5 12`
C03	`10`	`3`	`ENG`	`@0 Hydrates @2 NA @5 12`
C03	`11`	`3`	`FRE`	`@0 Liaison hydrogène @5 13`
C03	`11`	`3`	`ENG`	`@0 Hydrogen bonds @5 13`
C03	`12`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 56`
C03	`13`	`3`	`FRE`	`@0 Complexe dihydrogénophosphato @4 INC @5 92`
C03	`14`	`3`	`FRE`	`@0 Tétraaza-14-crown-4 @2 FC @4 INC @5 93`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 16`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 16`
C07	`02`	`3`	`FRE`	`@0 Métal transition complexe @5 17`
C07	`02`	`3`	`ENG`	`@0 Transition element complexes @5 17`
N21				`@1 123`

Format Inist (serveur)

NO :	PASCAL 99-0194411 INIST
ET :	Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ⁴N]nickel( II ) monohydrate
AU :	NAMOUCHI-CHERNI (S.); DRISS (A.); JOUINI (T.)
AF :	Département de Chimie, Faculté des Sciences, Campus Universitaire/1060 Tunis/Tunisie (1 aut., 2 aut., 3 aut.)
DT :	Publication en série; Niveau analytique
SO :	Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Danemark; Da. 1999; Vol. 55; No. p.3; Pp. 345-347; Bibl. 12 ref.
LA :	Anglais
EA :	The Ni^II ion in the title compound, [Ni(H₂PO₄)₂(C₁₀H_{2 4}N₄)].H₂O, is six-coordinate in a distorted square-bipyramidal environment. Four N atoms from the tetraaza-macrocycle are in a square-planar arrangement [average Ni-N distance = 2.071 (2) Å] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.144 (2) Å]. The structure of the title complex forms a three-dimensional framework, which delimits intersecting b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H...O and N-H...O, ensure the cohesion and stability of the molecular packing.
CC :	001B60A66F5
FD :	Etude expérimentale; Diffraction RX; Structure cristalline; Structure moléculaire; Nickel II Complexe; Coordinat organique; Hétérocycle azote; Macrocycle; Composé crown azote; Hydrate; Liaison hydrogène; 6166F; Complexe dihydrogénophosphato; Tétraaza-14-crown-4
FG :	Composé minéral; Métal transition complexe
ED :	Experimental study; XRD; Crystal structure; Molecular structure; Nickel II Complexes; Organic ligand; Nitrogen heterocycle; Macrocycle; Nitrogen crown compound; Hydrates; Hydrogen bonds
EG :	Inorganic compounds; Transition element complexes
SD :	Niquel II Complejo; Ligando orgánico; Heterociclo nitrógeno; Macrociclo; Compuesto crown nitrógeno
LO :	INIST-5160C.354000075008050340
ID :	99-0194411

Links to Exploration step

Pascal:99-0194411

Le document en format XML

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N]nickel(II ) monohydrate</title>
<author><name sortKey="Namouchi Cherni, S" sort="Namouchi Cherni, S" uniqKey="Namouchi Cherni S" first="S." last="Namouchi-Cherni">S. Namouchi-Cherni</name>
<affiliation><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, Campus Universitaire</s1>
<s2>1060 Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<author><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A." last="Driss">A. Driss</name>
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<s2>1060 Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">T. Jouini</name>
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<s3>TUN</s3>
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<publicationStmt><idno type="wicri:source">INIST</idno>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ<sup>4</sup>
N]nickel(II ) monohydrate</title>
<author><name sortKey="Namouchi Cherni, S" sort="Namouchi Cherni, S" uniqKey="Namouchi Cherni S" first="S." last="Namouchi-Cherni">S. Namouchi-Cherni</name>
<affiliation><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, Campus Universitaire</s1>
<s2>1060 Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A." last="Driss">A. Driss</name>
<affiliation><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, Campus Universitaire</s1>
<s2>1060 Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">T. Jouini</name>
<affiliation><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, Campus Universitaire</s1>
<s2>1060 Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
<imprint><date when="1999">1999</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Crystal structure</term>
<term>Experimental study</term>
<term>Hydrates</term>
<term>Hydrogen bonds</term>
<term>Macrocycle</term>
<term>Molecular structure</term>
<term>Nickel II Complexes</term>
<term>Nitrogen crown compound</term>
<term>Nitrogen heterocycle</term>
<term>Organic ligand</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Structure moléculaire</term>
<term>Nickel II Complexe</term>
<term>Coordinat organique</term>
<term>Hétérocycle azote</term>
<term>Macrocycle</term>
<term>Composé crown azote</term>
<term>Hydrate</term>
<term>Liaison hydrogène</term>
<term>6166F</term>
<term>Complexe dihydrogénophosphato</term>
<term>Tétraaza-14-crown-4</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The Ni<sup>II</sup>
 ion in the title compound, [Ni(H<sub>2</sub>
PO<sub>4</sub>
)<sub>2</sub>
(C<sub>10</sub>
H<sub>24</sub>
N<sub>4</sub>
)].H<sub>2</sub>
O, is six-coordinate in a distorted square-bipyramidal environment. Four N atoms from the tetraaza-macrocycle are in a square-planar arrangement [average Ni-N distance = 2.071 (2) Å] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.144 (2) Å]. The structure of the title complex forms a three-dimensional framework, which delimits intersecting b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H...O and N-H...O, ensure the cohesion and stability of the molecular packing.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0108-2701</s0>
</fA01>
<fA02 i1="01"><s0>ACSCEE</s0>
</fA02>
<fA03 i2="1"><s0>Acta crystallogr., Sect. C Cryst. struct. commun.</s0>
</fA03>
<fA05><s2>55</s2>
</fA05>
<fA06><s3>p.3</s3>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ<sup>4</sup>
N]nickel(II ) monohydrate</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>NAMOUCHI-CHERNI (S.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>DRISS (A.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>JOUINI (T.)</s1>
</fA11>
<fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, Campus Universitaire</s1>
<s2>1060 Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA20><s1>345-347</s1>
</fA20>
<fA21><s1>1999</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>5160C</s2>
<s5>354000075008050340</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 1999 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>12 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>99-0194411</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Acta crystallographica. Section C, Crystal structure communications</s0>
</fA64>
<fA66 i1="01"><s0>DNK</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>The Ni<sup>II</sup>
 ion in the title compound, [Ni(H<sub>2</sub>
PO<sub>4</sub>
)<sub>2</sub>
(C<sub>10</sub>
H<sub>24</sub>
N<sub>4</sub>
)].H<sub>2</sub>
O, is six-coordinate in a distorted square-bipyramidal environment. Four N atoms from the tetraaza-macrocycle are in a square-planar arrangement [average Ni-N distance = 2.071 (2) Å] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.144 (2) Å]. The structure of the title complex forms a three-dimensional framework, which delimits intersecting b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H...O and N-H...O, ensure the cohesion and stability of the molecular packing.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F5</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Structure moléculaire</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Molecular structure</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Nickel II Complexe</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
<s6>Nickel «II» Complexe</s6>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Nickel II Complexes</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
<s6>Nickel «II» Complexes</s6>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Niquel II Complejo</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
<s6>Niquel «II» Complejo</s6>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Coordinat organique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Organic ligand</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Ligando orgánico</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Hétérocycle azote</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Nitrogen heterocycle</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Heterociclo nitrógeno</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Macrocycle</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Macrocycle</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Macrociclo</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Composé crown azote</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Nitrogen crown compound</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Compuesto crown nitrógeno</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Hydrate</s0>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Hydrates</s0>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Liaison hydrogène</s0>
<s5>13</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Hydrogen bonds</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Complexe dihydrogénophosphato</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Tétraaza-14-crown-4</s0>
<s2>FC</s2>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition complexe</s0>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element complexes</s0>
<s5>17</s5>
</fC07>
<fN21><s1>123</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 99-0194411 INIST</NO>
<ET>Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ<sup>4</sup>
N]nickel( II ) monohydrate</ET>
<AU>NAMOUCHI-CHERNI (S.); DRISS (A.); JOUINI (T.)</AU>
<AF>Département de Chimie, Faculté des Sciences, Campus Universitaire/1060 Tunis/Tunisie (1 aut., 2 aut., 3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Danemark; Da. 1999; Vol. 55; No. p.3; Pp. 345-347; Bibl. 12 ref.</SO>
<LA>Anglais</LA>
<EA>The Ni<sup>II</sup>
 ion in the title compound, [Ni(H<sub>2</sub>
PO<sub>4</sub>
)<sub>2</sub>
(C<sub>10</sub>
H<sub>2 4</sub>
N<sub>4</sub>
)].H<sub>2</sub>
O, is six-coordinate in a distorted square-bipyramidal environment. Four N atoms from the tetraaza-macrocycle are in a square-planar arrangement [average Ni-N distance = 2.071 (2) Å] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.144 (2) Å]. The structure of the title complex forms a three-dimensional framework, which delimits intersecting b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H...O and N-H...O, ensure the cohesion and stability of the molecular packing.</EA>
<CC>001B60A66F5</CC>
<FD>Etude expérimentale; Diffraction RX; Structure cristalline; Structure moléculaire; Nickel II Complexe; Coordinat organique; Hétérocycle azote; Macrocycle; Composé crown azote; Hydrate; Liaison hydrogène; 6166F; Complexe dihydrogénophosphato; Tétraaza-14-crown-4</FD>
<FG>Composé minéral; Métal transition complexe</FG>
<ED>Experimental study; XRD; Crystal structure; Molecular structure; Nickel II Complexes; Organic ligand; Nitrogen heterocycle; Macrocycle; Nitrogen crown compound; Hydrates; Hydrogen bonds</ED>
<EG>Inorganic compounds; Transition element complexes</EG>
<SD>Niquel II Complejo; Ligando orgánico; Heterociclo nitrógeno; Macrociclo; Compuesto crown nitrógeno</SD>
<LO>INIST-5160C.354000075008050340</LO>
<ID>99-0194411</ID>
</server>
</inist>
</record>

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Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II ) monohydrate

Bis(dihydrogen phosphato-O)[(1RS, 4RS, -8SR, 11SR)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II ) monohydrate

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