LrgpV1, Istex, Curation, bibRecord, 001579

Linear polarization Raman optical activity: a new form of natural optical activity

Identifieur interne : 001579 ( Istex/Curation ); précédent : 001578; suivant : 001580

Linear polarization Raman optical activity: a new form of natural optical activity

Auteurs : Lutz Hecht [États-Unis] ; Laurence A. Nafie [États-Unis]

Source :

Chemical Physics Letters [ 0009-2614 ] ; 1990.

RBID : ISTEX:73980A5010AE1DC8A37AC76ECC59BB330D9BBEBD

English descriptors

KwdEn :
- Alternative approach, Barron, Chem, Chemical physics letters, Chiral molecules, Circular dichroism, Circular polarization, Corresponding script, Dichroism, Differential intensity, Electronic absorption bands, Experimental configuration, Experimental configurations, General theory, Imaginary part, Incident laser radiation, Incident radiation, Laser frequency, November, Optical activity, Optical rotation, Optical rotatory dispersion, Phys, Polarization, Polarization ellipse, Polarization state, Polarization vectors, Propagation vectors, Raman, Raman effect, Raman spectroscopy, Real part, Real parts, Relative signs, Second polarizer, Stokes, Stokes vectors, Tensor, Tensor products, Theoretical description, Theoretical expressions, Total intensity, Total raman intensity, Transition tensors, Various types, Vector products.
Teeft :
- Alternative approach, Barron, Chem, Chemical physics letters, Chiral molecules, Circular dichroism, Circular polarization, Corresponding script, Dichroism, Differential intensity, Electronic absorption bands, Experimental configuration, Experimental configurations, General theory, Imaginary part, Incident laser radiation, Incident radiation, Laser frequency, November, Optical activity, Optical rotation, Optical rotatory dispersion, Phys, Polarization, Polarization ellipse, Polarization state, Polarization vectors, Propagation vectors, Raman, Raman effect, Raman spectroscopy, Real part, Real parts, Relative signs, Second polarizer, Stokes, Stokes vectors, Tensor, Tensor products, Theoretical description, Theoretical expressions, Total intensity, Total raman intensity, Transition tensors, Various types, Vector products.

Abstract

Abstract: A new form of natural optical activity is identified on the basis of a general theory of natural Raman optical activity (ROA). This novel ROA phenomenon is predicted to occur as the difference in Raman-scattered intensity for pairs of linearly polarized measurements and depends on the real part of the product of the transition-polarizability and optical-activity tensors. This is the first form of ROA to be identified that does not directly involve the use or measurement of circularly polarized radiation.

Url:

https://api.istex.fr/document/73980A5010AE1DC8A37AC76ECC59BB330D9BBEBD/fulltext/pdf

DOI: 10.1016/0009-2614(90)85489-Y

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Le document en format XML

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<term>Chemical physics letters</term>
<term>Chiral molecules</term>
<term>Circular dichroism</term>
<term>Circular polarization</term>
<term>Corresponding script</term>
<term>Dichroism</term>
<term>Differential intensity</term>
<term>Electronic absorption bands</term>
<term>Experimental configuration</term>
<term>Experimental configurations</term>
<term>General theory</term>
<term>Imaginary part</term>
<term>Incident laser radiation</term>
<term>Incident radiation</term>
<term>Laser frequency</term>
<term>November</term>
<term>Optical activity</term>
<term>Optical rotation</term>
<term>Optical rotatory dispersion</term>
<term>Phys</term>
<term>Polarization</term>
<term>Polarization ellipse</term>
<term>Polarization state</term>
<term>Polarization vectors</term>
<term>Propagation vectors</term>
<term>Raman</term>
<term>Raman effect</term>
<term>Raman spectroscopy</term>
<term>Real part</term>
<term>Real parts</term>
<term>Relative signs</term>
<term>Second polarizer</term>
<term>Stokes</term>
<term>Stokes vectors</term>
<term>Tensor</term>
<term>Tensor products</term>
<term>Theoretical description</term>
<term>Theoretical expressions</term>
<term>Total intensity</term>
<term>Total raman intensity</term>
<term>Transition tensors</term>
<term>Various types</term>
<term>Vector products</term>
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<term>Barron</term>
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<term>Chemical physics letters</term>
<term>Chiral molecules</term>
<term>Circular dichroism</term>
<term>Circular polarization</term>
<term>Corresponding script</term>
<term>Dichroism</term>
<term>Differential intensity</term>
<term>Electronic absorption bands</term>
<term>Experimental configuration</term>
<term>Experimental configurations</term>
<term>General theory</term>
<term>Imaginary part</term>
<term>Incident laser radiation</term>
<term>Incident radiation</term>
<term>Laser frequency</term>
<term>November</term>
<term>Optical activity</term>
<term>Optical rotation</term>
<term>Optical rotatory dispersion</term>
<term>Phys</term>
<term>Polarization</term>
<term>Polarization ellipse</term>
<term>Polarization state</term>
<term>Polarization vectors</term>
<term>Propagation vectors</term>
<term>Raman</term>
<term>Raman effect</term>
<term>Raman spectroscopy</term>
<term>Real part</term>
<term>Real parts</term>
<term>Relative signs</term>
<term>Second polarizer</term>
<term>Stokes</term>
<term>Stokes vectors</term>
<term>Tensor</term>
<term>Tensor products</term>
<term>Theoretical description</term>
<term>Theoretical expressions</term>
<term>Total intensity</term>
<term>Total raman intensity</term>
<term>Transition tensors</term>
<term>Various types</term>
<term>Vector products</term>
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<front><div type="abstract" xml:lang="en">Abstract: A new form of natural optical activity is identified on the basis of a general theory of natural Raman optical activity (ROA). This novel ROA phenomenon is predicted to occur as the difference in Raman-scattered intensity for pairs of linearly polarized measurements and depends on the real part of the product of the transition-polarizability and optical-activity tensors. This is the first form of ROA to be identified that does not directly involve the use or measurement of circularly polarized radiation.</div>
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Linear polarization Raman optical activity: a new form of natural optical activity

Linear polarization Raman optical activity: a new form of natural optical activity

Source :

English descriptors

Abstract

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