Linear polarization Raman optical activity: a new form of natural optical activity
Identifieur interne : 001579 ( Istex/Corpus ); précédent : 001578; suivant : 001580Linear polarization Raman optical activity: a new form of natural optical activity
Auteurs : Lutz Hecht ; Laurence A. NafieSource :
- Chemical Physics Letters [ 0009-2614 ] ; 1990.
English descriptors
- KwdEn :
- Alternative approach, Barron, Chem, Chemical physics letters, Chiral molecules, Circular dichroism, Circular polarization, Corresponding script, Dichroism, Differential intensity, Electronic absorption bands, Experimental configuration, Experimental configurations, General theory, Imaginary part, Incident laser radiation, Incident radiation, Laser frequency, November, Optical activity, Optical rotation, Optical rotatory dispersion, Phys, Polarization, Polarization ellipse, Polarization state, Polarization vectors, Propagation vectors, Raman, Raman effect, Raman spectroscopy, Real part, Real parts, Relative signs, Second polarizer, Stokes, Stokes vectors, Tensor, Tensor products, Theoretical description, Theoretical expressions, Total intensity, Total raman intensity, Transition tensors, Various types, Vector products.
- Teeft :
- Alternative approach, Barron, Chem, Chemical physics letters, Chiral molecules, Circular dichroism, Circular polarization, Corresponding script, Dichroism, Differential intensity, Electronic absorption bands, Experimental configuration, Experimental configurations, General theory, Imaginary part, Incident laser radiation, Incident radiation, Laser frequency, November, Optical activity, Optical rotation, Optical rotatory dispersion, Phys, Polarization, Polarization ellipse, Polarization state, Polarization vectors, Propagation vectors, Raman, Raman effect, Raman spectroscopy, Real part, Real parts, Relative signs, Second polarizer, Stokes, Stokes vectors, Tensor, Tensor products, Theoretical description, Theoretical expressions, Total intensity, Total raman intensity, Transition tensors, Various types, Vector products.
Abstract
Abstract: A new form of natural optical activity is identified on the basis of a general theory of natural Raman optical activity (ROA). This novel ROA phenomenon is predicted to occur as the difference in Raman-scattered intensity for pairs of linearly polarized measurements and depends on the real part of the product of the transition-polarizability and optical-activity tensors. This is the first form of ROA to be identified that does not directly involve the use or measurement of circularly polarized radiation.
Url:
DOI: 10.1016/0009-2614(90)85489-Y
Links to Exploration step
ISTEX:73980A5010AE1DC8A37AC76ECC59BB330D9BBEBDLe document en format XML
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Nafie</name><affiliation><mods:affiliation>Department of Chemistry, Syracuse University, Syracuse, NY 13244-4100, USA</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:73980A5010AE1DC8A37AC76ECC59BB330D9BBEBD</idno><date when="1990" year="1990">1990</date><idno type="doi">10.1016/0009-2614(90)85489-Y</idno><idno type="url">https://api.istex.fr/document/73980A5010AE1DC8A37AC76ECC59BB330D9BBEBD/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001579</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001579</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Linear polarization Raman optical activity: a new form of natural optical activity</title><author><name sortKey="Hecht, Lutz" sort="Hecht, Lutz" uniqKey="Hecht L" first="Lutz" last="Hecht">Lutz Hecht</name><affiliation><mods:affiliation>Department of Chemistry, Syracuse University, Syracuse, NY 13244-4100, USA</mods:affiliation></affiliation></author><author><name sortKey="Nafie, Laurence A" sort="Nafie, Laurence A" uniqKey="Nafie L" first="Laurence A." last="Nafie">Laurence A. Nafie</name><affiliation><mods:affiliation>Department of Chemistry, Syracuse University, Syracuse, NY 13244-4100, USA</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Chemical Physics Letters</title><title level="j" type="abbrev">CPLETT</title><idno type="ISSN">0009-2614</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1990">1990</date><biblScope unit="volume">174</biblScope><biblScope unit="issue">6</biblScope><biblScope unit="page" from="575">575</biblScope><biblScope unit="page" to="582">582</biblScope></imprint><idno type="ISSN">0009-2614</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0009-2614</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Alternative approach</term><term>Barron</term><term>Chem</term><term>Chemical physics letters</term><term>Chiral molecules</term><term>Circular dichroism</term><term>Circular polarization</term><term>Corresponding script</term><term>Dichroism</term><term>Differential intensity</term><term>Electronic absorption bands</term><term>Experimental configuration</term><term>Experimental configurations</term><term>General theory</term><term>Imaginary part</term><term>Incident laser radiation</term><term>Incident radiation</term><term>Laser frequency</term><term>November</term><term>Optical activity</term><term>Optical rotation</term><term>Optical rotatory dispersion</term><term>Phys</term><term>Polarization</term><term>Polarization ellipse</term><term>Polarization state</term><term>Polarization vectors</term><term>Propagation vectors</term><term>Raman</term><term>Raman effect</term><term>Raman spectroscopy</term><term>Real part</term><term>Real parts</term><term>Relative signs</term><term>Second polarizer</term><term>Stokes</term><term>Stokes vectors</term><term>Tensor</term><term>Tensor products</term><term>Theoretical description</term><term>Theoretical expressions</term><term>Total intensity</term><term>Total raman intensity</term><term>Transition tensors</term><term>Various types</term><term>Vector products</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Alternative approach</term><term>Barron</term><term>Chem</term><term>Chemical physics letters</term><term>Chiral molecules</term><term>Circular dichroism</term><term>Circular polarization</term><term>Corresponding script</term><term>Dichroism</term><term>Differential intensity</term><term>Electronic absorption bands</term><term>Experimental configuration</term><term>Experimental configurations</term><term>General theory</term><term>Imaginary part</term><term>Incident laser radiation</term><term>Incident radiation</term><term>Laser frequency</term><term>November</term><term>Optical activity</term><term>Optical rotation</term><term>Optical rotatory dispersion</term><term>Phys</term><term>Polarization</term><term>Polarization ellipse</term><term>Polarization state</term><term>Polarization vectors</term><term>Propagation vectors</term><term>Raman</term><term>Raman effect</term><term>Raman spectroscopy</term><term>Real part</term><term>Real parts</term><term>Relative signs</term><term>Second polarizer</term><term>Stokes</term><term>Stokes vectors</term><term>Tensor</term><term>Tensor products</term><term>Theoretical description</term><term>Theoretical expressions</term><term>Total intensity</term><term>Total raman intensity</term><term>Transition tensors</term><term>Various types</term><term>Vector products</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: A new form of natural optical activity is identified on the basis of a general theory of natural Raman optical activity (ROA). 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This novel ROA phenomenon is predicted to occur as the difference in Raman-scattered intensity for pairs of linearly polarized measurements and depends on the real part of the product of the transition-polarizability and optical-activity tensors. This is the first form of ROA to be identified that does not directly involve the use or measurement of circularly polarized radiation.</p></abstract></profileDesc><revisionDesc><change when="1990-09-12">Modified</change><change when="1990">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/73980A5010AE1DC8A37AC76ECC59BB330D9BBEBD/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="UTF-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla" xml:lang="en"><item-info><jid>CPLETT</jid><aid>9085489Y</aid><ce:pii>0009-2614(90)85489-Y</ce:pii><ce:doi>10.1016/0009-2614(90)85489-Y</ce:doi><ce:copyright type="unknown" year="1990"></ce:copyright></item-info><head><ce:title>Linear polarization Raman optical activity: a new form of natural optical activity</ce:title><ce:author-group><ce:author><ce:given-name>Lutz</ce:given-name><ce:surname>Hecht</ce:surname></ce:author><ce:author><ce:given-name>Laurence A.</ce:given-name><ce:surname>Nafie</ce:surname></ce:author><ce:affiliation><ce:textfn>Department of Chemistry, Syracuse University, Syracuse, NY 13244-4100, USA</ce:textfn></ce:affiliation></ce:author-group><ce:date-received day="22" month="5" year="1990"></ce:date-received><ce:date-revised day="12" month="9" year="1990"></ce:date-revised><ce:abstract class="author"><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para view="all" id="simple-para.0010">A new form of natural optical activity is identified on the basis of a general theory of natural Raman optical activity (ROA). This novel ROA phenomenon is predicted to occur as the difference in Raman-scattered intensity for pairs of linearly polarized measurements and depends on the real part of the product of the transition-polarizability and optical-activity tensors. This is the first form of ROA to be identified that does not directly involve the use or measurement of circularly polarized radiation.</ce:simple-para></ce:abstract-sec></ce:abstract></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Linear polarization Raman optical activity: a new form of natural optical activity</title></titleInfo><titleInfo type="alternative" lang="en" contentType="CDATA"><title>Linear polarization Raman optical activity: a new form of natural optical activity</title></titleInfo><name type="personal"><namePart type="given">Lutz</namePart><namePart type="family">Hecht</namePart><affiliation>Department of Chemistry, Syracuse University, Syracuse, NY 13244-4100, USA</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Laurence A.</namePart><namePart type="family">Nafie</namePart><affiliation>Department of Chemistry, Syracuse University, Syracuse, NY 13244-4100, USA</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1990</dateIssued><dateModified encoding="w3cdtf">1990-09-12</dateModified><copyrightDate encoding="w3cdtf">1990</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><abstract lang="en">Abstract: A new form of natural optical activity is identified on the basis of a general theory of natural Raman optical activity (ROA). This novel ROA phenomenon is predicted to occur as the difference in Raman-scattered intensity for pairs of linearly polarized measurements and depends on the real part of the product of the transition-polarizability and optical-activity tensors. 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