Extraction of n-Alcohols from n-Heptane Using Ionic Liquids
Identifieur interne : 000503 ( Hal/Corpus ); précédent : 000502; suivant : 000504Extraction of n-Alcohols from n-Heptane Using Ionic Liquids
Auteurs : Anne-Laure Revelli ; Fabrice Mutelet ; Jean-Noël JaubertSource :
- Journal of Chemical and Engineering Data [ 0021-9568 ] ; 2011.
English descriptors
- mix :
Abstract
In this work, the efficiency of three ionic liquids: 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium thiocyanate, and 1,3-dimethylimidazolium methylphosphonate to extract n-alcohols from an aliphatic compound was studied. Liquid-liquid equilibria (LLE) measurements of ternary mixtures containing 1-propanol, 1-butanol, or 1-pentanol with n-heptane and these ILs were carried out at 298.15 K in order to check the ability of these ILs to act as extractive solvents. Experimental data were successfully represented using the NRTL and UNIQUAC correlations.
Url:
DOI: 10.1021/je200481u
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Hal:hal-00776933Le document en format XML
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<front><div type="abstract" xml:lang="en">In this work, the efficiency of three ionic liquids: 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium thiocyanate, and 1,3-dimethylimidazolium methylphosphonate to extract n-alcohols from an aliphatic compound was studied. Liquid-liquid equilibria (LLE) measurements of ternary mixtures containing 1-propanol, 1-butanol, or 1-pentanol with n-heptane and these ILs were carried out at 298.15 K in order to check the ability of these ILs to act as extractive solvents. Experimental data were successfully represented using the NRTL and UNIQUAC correlations.</div>
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<abstract xml:lang="en">In this work, the efficiency of three ionic liquids: 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium thiocyanate, and 1,3-dimethylimidazolium methylphosphonate to extract n-alcohols from an aliphatic compound was studied. Liquid-liquid equilibria (LLE) measurements of ternary mixtures containing 1-propanol, 1-butanol, or 1-pentanol with n-heptane and these ILs were carried out at 298.15 K in order to check the ability of these ILs to act as extractive solvents. Experimental data were successfully represented using the NRTL and UNIQUAC correlations.</abstract>
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