Extraction of Thiophene or Pyridine from n-Heptane Using Ionic Liquids. Gasoline and Diesel Desulfurization
Identifieur interne : 000502 ( Hal/Corpus ); précédent : 000501; suivant : 000503Extraction of Thiophene or Pyridine from n-Heptane Using Ionic Liquids. Gasoline and Diesel Desulfurization
Auteurs : K. Kedra-Krolik ; F. Mutelet ; J. N. JaubertSource :
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Abstract
The aim of this study is to investigate the possible use of ILs as solvents for two separation problems frequently encountered in petroleum industry: {aromatic sulfur compound + aliphatic hydrocarbon} or {nitrogen compound + aliphatic hydrocarbon}. This work is focused on three ILs: 1-ethyl-3-methylimidazolium thiocyanate, 1,3-dimethylimidazolium methylphosphonate, and tris-(2-hydroxyethyl)-methylammonium-methylsulfate. In the first part of this article, a study of new three ternary systems is studied in view of defining the capacity of proposed ILs as solvents for extraction of sulfur and nitrogen containing organic compounds from aliphatic hydrocarbons. Therefore, LLE measurements of ternary mixtures for five systems were measured at 298.15 K and at atmospheric pressure: {thiophene + n-heptane +1-ethyl-3-methylimidazolium thiocyanate}, {thiophene -n-heptane + 1,3-dimethylimidazolium methylphosphonate}, {thiophene + n-heptane + tris-(2-hydroxyethyl)-methylammonium-methylsulfate}, {pyridine + n-heptane + 1-ethyl-3-methylimidazolium thiocyanate}, {pyridine + n-heptane + 1,3-dimethylimidazolium methylphosphonate}. The second section of this article presents results of extraction of synthetic fuels - model gasoline and model diesel by the use of selected ILs. The influence of extraction time or temperature as well as three stepped procedure using each time a fresh portion of ILs on the final fuel contamination was investigated.
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DOI: 10.1021/ie101834m
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This work is focused on three ILs: 1-ethyl-3-methylimidazolium thiocyanate, 1,3-dimethylimidazolium methylphosphonate, and tris-(2-hydroxyethyl)-methylammonium-methylsulfate. In the first part of this article, a study of new three ternary systems is studied in view of defining the capacity of proposed ILs as solvents for extraction of sulfur and nitrogen containing organic compounds from aliphatic hydrocarbons. Therefore, LLE measurements of ternary mixtures for five systems were measured at 298.15 K and at atmospheric pressure: {thiophene + n-heptane +1-ethyl-3-methylimidazolium thiocyanate}, {thiophene -n-heptane + 1,3-dimethylimidazolium methylphosphonate}, {thiophene + n-heptane + tris-(2-hydroxyethyl)-methylammonium-methylsulfate}, {pyridine + n-heptane + 1-ethyl-3-methylimidazolium thiocyanate}, {pyridine + n-heptane + 1,3-dimethylimidazolium methylphosphonate}. The second section of this article presents results of extraction of synthetic fuels - model gasoline and model diesel by the use of selected ILs. The influence of extraction time or temperature as well as three stepped procedure using each time a fresh portion of ILs on the final fuel contamination was investigated.</div></front></TEI><hal api="V3"><titleStmt><title xml:lang="en">Extraction of Thiophene or Pyridine from n-Heptane Using Ionic Liquids. Gasoline and Diesel Desulfurization</title><author role="aut"><persName><forename type="first">K.</forename><surname>Kedra-Krolik</surname></persName><email></email><idno type="halauthor">622265</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">F.</forename><surname>Mutelet</surname></persName><email></email><idno type="halauthor">497853</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">J.N.</forename><surname>Jaubert</surname></persName><email></email><idno type="halauthor">401246</idno><affiliation ref="#struct-211875"></affiliation></author><editor role="depositor"><persName><forename>Josiane</forename><surname>Moras</surname></persName><email>josiane.moras@ensic.inpl-nancy.fr</email></editor></titleStmt><editionStmt><edition n="v1" type="current"><date type="whenSubmitted">2011-06-30 11:30:29</date><date type="whenModified">2016-05-17 10:12:13</date><date type="whenReleased">2011-06-30 11:30:29</date><date type="whenProduced">2011</date></edition><respStmt><resp>contributor</resp><name key="109516"><persName><forename>Josiane</forename><surname>Moras</surname></persName><email>josiane.moras@ensic.inpl-nancy.fr</email></name></respStmt></editionStmt><publicationStmt><distributor>CCSD</distributor><idno type="halId">hal-00604986</idno><idno type="halUri">https://hal.archives-ouvertes.fr/hal-00604986</idno><idno type="halBibtex">kedrakrolik:hal-00604986</idno><idno type="halRefHtml">Industrial & Engineering Chemistry Research, ACS, 2011, 50 ((4)), pp. 2296-2306. <10.1021/ie101834m></idno><idno type="halRef">Industrial & Engineering Chemistry Research, ACS, 2011, 50 ((4)), pp. 2296-2306. <10.1021/ie101834m></idno></publicationStmt><seriesStmt><idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno><idno type="stamp" n="LRGP-UL">LRGP</idno><idno type="stamp" n="UNIV-LORRAINE">Université de Lorraine</idno></seriesStmt><notesStmt><note type="audience" n="2">International</note><note type="popular" n="0">No</note><note type="peer" n="1">Yes</note></notesStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Extraction of Thiophene or Pyridine from n-Heptane Using Ionic Liquids. Gasoline and Diesel Desulfurization</title><author role="aut"><persName><forename type="first">K.</forename><surname>Kedra-Krolik</surname></persName><idno type="halAuthorId">622265</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">F.</forename><surname>Mutelet</surname></persName><idno type="halAuthorId">497853</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">J.N.</forename><surname>Jaubert</surname></persName><idno type="halAuthorId">401246</idno><affiliation ref="#struct-211875"></affiliation></author></analytic><monogr><idno type="halJournalId" status="INCOMING">37718</idno><title level="j">Industrial & Engineering Chemistry Research</title><imprint><publisher>ACS</publisher><biblScope unit="volume">50</biblScope><biblScope unit="issue">(4)</biblScope><biblScope unit="pp">pp. 2296-2306</biblScope><date type="datePub">2011</date></imprint></monogr><idno type="doi">10.1021/ie101834m</idno></biblStruct></sourceDesc><profileDesc><langUsage><language ident="en">English</language></langUsage><textClass><keywords scheme="author"><term xml:lang="fr">Desulfurization</term><term xml:lang="fr">Ionic liquid</term></keywords><classCode scheme="halDomain" n="spi.gproc">Engineering Sciences [physics]/Chemical and Process Engineering</classCode><classCode scheme="halTypology" n="ART">Journal articles</classCode></textClass><abstract xml:lang="en">The aim of this study is to investigate the possible use of ILs as solvents for two separation problems frequently encountered in petroleum industry: {aromatic sulfur compound + aliphatic hydrocarbon} or {nitrogen compound + aliphatic hydrocarbon}. This work is focused on three ILs: 1-ethyl-3-methylimidazolium thiocyanate, 1,3-dimethylimidazolium methylphosphonate, and tris-(2-hydroxyethyl)-methylammonium-methylsulfate. In the first part of this article, a study of new three ternary systems is studied in view of defining the capacity of proposed ILs as solvents for extraction of sulfur and nitrogen containing organic compounds from aliphatic hydrocarbons. Therefore, LLE measurements of ternary mixtures for five systems were measured at 298.15 K and at atmospheric pressure: {thiophene + n-heptane +1-ethyl-3-methylimidazolium thiocyanate}, {thiophene -n-heptane + 1,3-dimethylimidazolium methylphosphonate}, {thiophene + n-heptane + tris-(2-hydroxyethyl)-methylammonium-methylsulfate}, {pyridine + n-heptane + 1-ethyl-3-methylimidazolium thiocyanate}, {pyridine + n-heptane + 1,3-dimethylimidazolium methylphosphonate}. The second section of this article presents results of extraction of synthetic fuels - model gasoline and model diesel by the use of selected ILs. The influence of extraction time or temperature as well as three stepped procedure using each time a fresh portion of ILs on the final fuel contamination was investigated.</abstract></profileDesc></hal></record>Pour manipuler ce document sous Unix (Dilib)
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