Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran
Identifieur interne : 000246 ( Hal/Corpus ); précédent : 000245; suivant : 000247Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran
Auteurs : Casimir Togbé ; Luc-Sy Tran ; Dong Liu ; Daniel Felsmann ; Patrick Osswald ; Pierre-Alexandre Glaude ; Baptiste Sirjean ; René Fournet ; Frédérique Battin-Leclerc ; Katharina Kohse-HoeinghausSource :
- Combustion and Flame [ 0010-2180 ] ; 2014-03.
Abstract
This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I, 2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (phi = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.
Url:
DOI: 10.1016/j.combustflame.2013.05.026
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Hal:hal-01275924Le document en format XML
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Part III: 2,5-Dimethylfuran</title><author><name sortKey="Togbe, Casimir" sort="Togbe, Casimir" uniqKey="Togbe C" first="Casimir" last="Togbé">Casimir Togbé</name></author><author><name sortKey="Tran, Luc Sy" sort="Tran, Luc Sy" uniqKey="Tran L" first="Luc-Sy" last="Tran">Luc-Sy Tran</name><affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno><idno type="RNSR">201320573K</idno><idno type="IdUnivLorraine">[UL]RQC--</idno><orgName>Laboratoire Réactions et Génie des Procédés</orgName><orgName type="acronym">LRGP</orgName><date type="start">2013-01-01</date><desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine><country key="FR"></country></address><ref type="url">http://lrgp.univ-lorraine.fr/</ref></desc><listRelation><relation active="#struct-413289" type="direct"></relation><relation name="UMR7274" active="#struct-441569" type="direct"></relation></listRelation><tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno><idno type="IdUnivLorraine">[UL]100--</idno><orgName>Université de Lorraine</orgName><orgName type="acronym">UL</orgName><date type="start">2012-01-01</date><desc><address><addrLine>34 cours Léopold - 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ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine><country key="FR"></country></address><ref type="url">http://lrgp.univ-lorraine.fr/</ref></desc><listRelation><relation active="#struct-413289" type="direct"></relation><relation name="UMR7274" active="#struct-441569" type="direct"></relation></listRelation><tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno><idno type="IdUnivLorraine">[UL]100--</idno><orgName>Université de Lorraine</orgName><orgName type="acronym">UL</orgName><date type="start">2012-01-01</date><desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine><country key="FR"></country></address><ref type="url">http://www.univ-lorraine.fr/</ref></desc></org></tutelle><tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno><idno type="IdRef">02636817X</idno><orgName>Centre National de la Recherche Scientifique</orgName><orgName type="acronym">CNRS</orgName><date type="start">1939-10-19</date><desc><address><country key="FR"></country></address><ref type="url">http://www.cnrs.fr/</ref></desc></org></tutelle></tutelles></hal:affiliation></affiliation></author><author><name sortKey="Sirjean, Baptiste" sort="Sirjean, Baptiste" uniqKey="Sirjean B" first="Baptiste" last="Sirjean">Baptiste Sirjean</name><affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno><idno type="RNSR">201320573K</idno><idno type="IdUnivLorraine">[UL]RQC--</idno><orgName>Laboratoire Réactions et Génie des Procédés</orgName><orgName type="acronym">LRGP</orgName><date type="start">2013-01-01</date><desc><address><addrLine>Université de Lorraine - 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ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine><country key="FR"></country></address><ref type="url">http://lrgp.univ-lorraine.fr/</ref></desc><listRelation><relation active="#struct-413289" type="direct"></relation><relation name="UMR7274" active="#struct-441569" type="direct"></relation></listRelation></org></tutelle><tutelle active="#struct-413289" type="indirect"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno><idno type="IdUnivLorraine">[UL]100--</idno><orgName>Université de Lorraine</orgName><orgName type="acronym">UL</orgName><date type="start">2012-01-01</date><desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine><country key="FR"></country></address><ref type="url">http://www.univ-lorraine.fr/</ref></desc></org></tutelle><tutelle name="UMR7274" active="#struct-441569" type="indirect"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno><idno type="IdRef">02636817X</idno><orgName>Centre National de la Recherche Scientifique</orgName><orgName type="acronym">CNRS</orgName><date type="start">1939-10-19</date><desc><address><country key="FR"></country></address><ref type="url">http://www.cnrs.fr/</ref></desc></org></tutelle></tutelles></hal:affiliation></affiliation></author><author><name sortKey="Kohse Hoeinghaus, Katharina" sort="Kohse Hoeinghaus, Katharina" uniqKey="Kohse Hoeinghaus K" first="Katharina" last="Kohse-Hoeinghaus">Katharina Kohse-Hoeinghaus</name></author></analytic><idno type="DOI">10.1016/j.combustflame.2013.05.026</idno><series><title level="j">Combustion and Flame</title><idno type="ISSN">0010-2180</idno><imprint><date type="datePub">2014-03</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I, 2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (phi = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</div></front></TEI><hal api="V3"><titleStmt><title xml:lang="en">Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran</title><author role="aut"><persName><forename type="first">Casimir</forename><surname>Togbé</surname></persName><email></email><idno type="halauthor">892545</idno></author><author role="aut"><persName><forename type="first">Luc-Sy</forename><surname>Tran</surname></persName><email></email><idno type="halauthor">1182623</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">Dong</forename><surname>Liu</surname></persName><email></email><idno type="halauthor">330287</idno></author><author role="aut"><persName><forename type="first">Daniel</forename><surname>Felsmann</surname></persName><email></email><idno type="halauthor">1296351</idno></author><author role="aut"><persName><forename type="first">Patrick</forename><surname>Osswald</surname></persName><email></email><idno type="halauthor">1296352</idno></author><author role="rsp"><persName><forename type="first">Pierre-Alexandre</forename><surname>Glaude</surname></persName><email>pierre-alexandre.glaude@univ-lorraine.fr</email><idno type="halauthor">879633</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">Baptiste</forename><surname>Sirjean</surname></persName><email>baptiste.sirjean@univ-lorraine.fr</email><idno type="halauthor">826296</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">René</forename><surname>Fournet</surname></persName><email>rene.fournet@univ-lorraine.fr</email><idno type="halauthor">807196</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">Frédérique</forename><surname>Battin-Leclerc</surname></persName><email>frederique.battin-leclerc@univ-lorraine.fr</email><idno type="halauthor">755940</idno><affiliation ref="#struct-400164"></affiliation></author><author role="aut"><persName><forename type="first">Katharina</forename><surname>Kohse-Hoeinghaus</surname></persName><email></email><idno type="halauthor">299984</idno></author><editor role="depositor"><persName><forename>LRGP</forename><surname>UL</surname></persName><email>ddoc-appuirecherche-lrgp@univ-lorraine.fr</email></editor></titleStmt><editionStmt><edition n="v1" type="current"><date type="whenSubmitted">2016-02-18 14:59:42</date><date type="whenModified">2016-05-10 16:53:27</date><date type="whenReleased">2016-02-18 14:59:42</date><date type="whenProduced">2014-03</date></edition><respStmt><resp>contributor</resp><name key="329568"><persName><forename>LRGP</forename><surname>UL</surname></persName><email>ddoc-appuirecherche-lrgp@univ-lorraine.fr</email></name></respStmt></editionStmt><publicationStmt><distributor>CCSD</distributor><idno type="halId">hal-01275924</idno><idno type="halUri">https://hal.univ-lorraine.fr/hal-01275924</idno><idno type="halBibtex">togbe:hal-01275924</idno><idno type="halRefHtml">Combustion and Flame, Elsevier, 2014, 161 (3), pp.780-797. <10.1016/j.combustflame.2013.05.026></idno><idno type="halRef">Combustion and Flame, Elsevier, 2014, 161 (3), pp.780-797. <10.1016/j.combustflame.2013.05.026></idno></publicationStmt><seriesStmt><idno type="stamp" n="UNIV-LORRAINE">Université de Lorraine</idno><idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno><idno type="stamp" n="LRGP-UL">LRGP</idno></seriesStmt><notesStmt><note type="audience" n="2">International</note><note type="popular" n="0">No</note><note type="peer" n="1">Yes</note></notesStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran</title><author role="aut"><persName><forename type="first">Casimir</forename><surname>Togbé</surname></persName><idno type="halAuthorId">892545</idno></author><author role="aut"><persName><forename type="first">Luc-Sy</forename><surname>Tran</surname></persName><idno type="halAuthorId">1182623</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">Dong</forename><surname>Liu</surname></persName><idno type="halAuthorId">330287</idno></author><author role="aut"><persName><forename type="first">Daniel</forename><surname>Felsmann</surname></persName><idno type="halAuthorId">1296351</idno></author><author role="aut"><persName><forename type="first">Patrick</forename><surname>Osswald</surname></persName><idno type="halAuthorId">1296352</idno></author><author role="rsp"><persName><forename type="first">Pierre-Alexandre</forename><surname>Glaude</surname></persName><email>pierre-alexandre.glaude@univ-lorraine.fr</email><idno type="halAuthorId">879633</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">Baptiste</forename><surname>Sirjean</surname></persName><email>baptiste.sirjean@univ-lorraine.fr</email><idno type="halAuthorId">826296</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">René</forename><surname>Fournet</surname></persName><email>rene.fournet@univ-lorraine.fr</email><idno type="halAuthorId">807196</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">Frédérique</forename><surname>Battin-Leclerc</surname></persName><email>frederique.battin-leclerc@univ-lorraine.fr</email><idno type="halAuthorId">755940</idno><affiliation ref="#struct-400164"></affiliation></author><author role="aut"><persName><forename type="first">Katharina</forename><surname>Kohse-Hoeinghaus</surname></persName><idno type="halAuthorId">299984</idno></author></analytic><monogr><idno type="halJournalId" status="VALID">11902</idno><idno type="issn">0010-2180</idno><title level="j">Combustion and Flame</title><imprint><publisher>Elsevier</publisher><biblScope unit="volume">161</biblScope><biblScope unit="issue">3</biblScope><biblScope unit="pp">780-797</biblScope><date type="datePub">2014-03</date></imprint></monogr><idno type="doi">10.1016/j.combustflame.2013.05.026</idno></biblStruct></sourceDesc><profileDesc><langUsage><language ident="en">English</language></langUsage><textClass><classCode scheme="halDomain" n="chim">Chemical Sciences</classCode><classCode scheme="halTypology" n="ART">Journal articles</classCode></textClass><abstract xml:lang="en">This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I, 2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (phi = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</abstract></profileDesc></hal></record>Pour manipuler ce document sous Unix (Dilib)
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