Crystal structure of bis-(2-amino-5-chloro-pyridinium) tetra-chlorido-cobaltate(II).
Identifieur interne : 000011 ( PubMed/Curation ); précédent : 000010; suivant : 000012Crystal structure of bis-(2-amino-5-chloro-pyridinium) tetra-chlorido-cobaltate(II).
Auteurs : Marwa Mghandef [Tunisie] ; Habib Boughzala [Tunisie]Source :
- Acta crystallographica. Section E, Crystallographic communications ; 2015.
Abstract
The title salt, (C5H6ClN2)2[CoCl4], was synthesized by slow evaporation of an aqueous solution at room temperature. The asymmetric unit consists of two essentially planar (C5H6ClN2)(+) cations [maximum deviations = 0.010 (3) and 0.014 (3) Å] that are nearly perpendicular to each other [dihedral angle = 84.12 (7)°]. They are bonded through N-H⋯Cl hydrogen bonds to distorted [CoCl4](2-) tetra-hedra, leading to the formation of undulating layers parallel to (100). The structure is isotypic with the Zn analogue [Kefi et. al (2011). Acta Cryst. E67, m355-m356.].
DOI: 10.1107/S2056989015007707
PubMed: 25995878
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<front><div type="abstract" xml:lang="en">The title salt, (C5H6ClN2)2[CoCl4], was synthesized by slow evaporation of an aqueous solution at room temperature. The asymmetric unit consists of two essentially planar (C5H6ClN2)(+) cations [maximum deviations = 0.010 (3) and 0.014 (3) Å] that are nearly perpendicular to each other [dihedral angle = 84.12 (7)°]. They are bonded through N-H⋯Cl hydrogen bonds to distorted [CoCl4](2-) tetra-hedra, leading to the formation of undulating layers parallel to (100). The structure is isotypic with the Zn analogue [Kefi et. al (2011). Acta Cryst. E67, m355-m356.].</div>
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<ArticleTitle>Crystal structure of bis-(2-amino-5-chloro-pyridinium) tetra-chlorido-cobaltate(II).</ArticleTitle>
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<Abstract><AbstractText>The title salt, (C5H6ClN2)2[CoCl4], was synthesized by slow evaporation of an aqueous solution at room temperature. The asymmetric unit consists of two essentially planar (C5H6ClN2)(+) cations [maximum deviations = 0.010 (3) and 0.014 (3) Å] that are nearly perpendicular to each other [dihedral angle = 84.12 (7)°]. They are bonded through N-H⋯Cl hydrogen bonds to distorted [CoCl4](2-) tetra-hedra, leading to the formation of undulating layers parallel to (100). The structure is isotypic with the Zn analogue [Kefi et. al (2011). Acta Cryst. E67, m355-m356.].</AbstractText>
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