CobaltMaghrebV1, Pmc, Checkpoint, bibRecord, 000173

β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6

Identifieur interne : 000173 ( Pmc/Checkpoint ); précédent : 000172; suivant : 000174

β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6

Auteurs : Riadh Marzouki [Tunisie] ; Wafa Frigui [Tunisie] ; Abderrahmen Guesmi [Tunisie] ; Mohamed Faouzi Zid [Tunisie] ; Ahmed Driss [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3790335

Abstract

The title compound, tetrasodium lithium cobalt aluminium hexa(orthoarsenate), was synthesized by a solid state reaction route. In the crystal structure, Co²⁺ ions are partially substituted by Al³⁺ in an octahedral environment [M1 with site symmetry 2/m; occupancy ratio Co:Al = 0.286 (10):0.714 (10)]. The charge compensation is ensured by Li⁺ cations sharing a tetrahedral site with Co²⁺ ions [M2 with site symmetry 2; occupancy ratio Co:Li = 0.690 (5):0.310 (5)]. The anionic unit is formed by two octahedra and three tetrahedra linked only by corners. The CoM1M2As₂O₁₉ units associate to an open three-dimensional framework containing tunnels propagating along the a-axis direction. One Na⁺ cation is located in the periphery of the tunnels while the other two are situated in the centres: all Na⁺ cations exhibit half-occupancy. The structure of the studied material is compared with those of various related minerals reported in the literature.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790335

DOI: 10.1107/S1600536813025233
PubMed: 24098157
PubMed Central: 3790335

Affiliations:

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to stream Pmc, to step Corpus: 000370
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PMC:3790335

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">β-Xenophyllite-type Na<sub>4</sub>
Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</title>
<author><name sortKey="Marzouki, Riadh" sort="Marzouki, Riadh" uniqKey="Marzouki R" first="Riadh" last="Marzouki">Riadh Marzouki</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Frigui, Wafa" sort="Frigui, Wafa" uniqKey="Frigui W" first="Wafa" last="Frigui">Wafa Frigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
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<placeName><settlement type="city">Tunis</settlement>
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<orgName type="university" n="3">Université de Tunis - El Manar</orgName>
</affiliation>
</author>
<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">β-Xenophyllite-type Na<sub>4</sub>
Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</title>
<author><name sortKey="Marzouki, Riadh" sort="Marzouki, Riadh" uniqKey="Marzouki R" first="Riadh" last="Marzouki">Riadh Marzouki</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Frigui, Wafa" sort="Frigui, Wafa" uniqKey="Frigui W" first="Wafa" last="Frigui">Wafa Frigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
<placeName><settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
<orgName type="university" n="3">Université de Tunis - El Manar</orgName>
</affiliation>
</author>
<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2013">2013</date>
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<profileDesc><textClass></textClass>
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<front><div type="abstract" xml:lang="en"><p>The title compound, tetrasodium lithium cobalt aluminium hexa(orthoarsenate), was synthesized by a solid state reaction route. In the crystal structure, Co<sup>2+</sup>
 ions are partially substituted by Al<sup>3+</sup>
 in an octahedral environment [<italic>M</italic>
1 with site symmetry 2/<italic>m</italic>
; occupancy ratio Co:Al = 0.286 (10):0.714 (10)]. The charge compensation is ensured by Li<sup>+</sup>
 cations sharing a tetrahedral site with Co<sup>2+</sup>
 ions [<italic>M</italic>
2 with site symmetry 2; occupancy ratio Co:Li = 0.690 (5):0.310 (5)]. The anionic unit is formed by two octahedra and three tetrahedra linked only by corners. The Co<italic>M</italic>
1<italic>M</italic>
2As<sub>2</sub>
O<sub>19</sub>
 units associate to an open three-dimensional framework containing tunnels propagating along the <italic>a-</italic>
axis direction. One Na<sup>+</sup>
 cation is located in the periphery of the tunnels while the other two are situated in the centres: all Na<sup>+</sup>
 cations exhibit half-occupancy. The structure of the studied material is compared with those of various related minerals reported in the literature.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
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<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
  <front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="iso-abbrev">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title>
</journal-title-group>
<issn pub-type="epub">1600-5368</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
</journal-meta>
<article-meta><article-id pub-id-type="pmid">24098157</article-id>
<article-id pub-id-type="pmc">3790335</article-id>
<article-id pub-id-type="publisher-id">vn2076</article-id>
<article-id pub-id-type="doi">10.1107/S1600536813025233</article-id>
<article-id pub-id-type="coden">ACSEBH</article-id>
<article-id pub-id-type="pii">S1600536813025233</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Inorganic Papers</subject>
</subj-group>
</article-categories>
<title-group><article-title>β-Xenophyllite-type Na<sub>4</sub>
Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</article-title>
<alt-title><italic>Na<sub>4</sub>
Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Marzouki</surname>
<given-names>Riadh</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Frigui</surname>
<given-names>Wafa</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Guesmi</surname>
<given-names>Abderrahmen</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Zid</surname>
<given-names>Mohamed Faouzi</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Driss</surname>
<given-names>Ahmed</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<aff id="a"><label>a</label>
Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>faouzi.zid@fst.rnu.tn</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>10</month>
<year>2013</year>
</pub-date>
<pub-date pub-type="epub"><day>21</day>
<month>9</month>
<year>2013</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>21</day>
<month>9</month>
<year>2013</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the 
 							. </pmc-comment>
      <volume>69</volume>
<issue>Pt 10</issue>
<issue-id pub-id-type="publisher-id">e131000</issue-id>
<fpage>i65</fpage>
<lpage>i66</lpage>
<history><date date-type="received"><day>02</day>
<month>9</month>
<year>2013</year>
</date>
<date date-type="accepted"><day>11</day>
<month>9</month>
<year>2013</year>
</date>
</history>
<permissions><copyright-statement>© Marzouki et al. 2013</copyright-statement>
<copyright-year>2013</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536813025233">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract><p>The title compound, tetrasodium lithium cobalt aluminium hexa(orthoarsenate), was synthesized by a solid state reaction route. In the crystal structure, Co<sup>2+</sup>
 ions are partially substituted by Al<sup>3+</sup>
 in an octahedral environment [<italic>M</italic>
1 with site symmetry 2/<italic>m</italic>
; occupancy ratio Co:Al = 0.286 (10):0.714 (10)]. The charge compensation is ensured by Li<sup>+</sup>
 cations sharing a tetrahedral site with Co<sup>2+</sup>
 ions [<italic>M</italic>
2 with site symmetry 2; occupancy ratio Co:Li = 0.690 (5):0.310 (5)]. The anionic unit is formed by two octahedra and three tetrahedra linked only by corners. The Co<italic>M</italic>
1<italic>M</italic>
2As<sub>2</sub>
O<sub>19</sub>
 units associate to an open three-dimensional framework containing tunnels propagating along the <italic>a-</italic>
axis direction. One Na<sup>+</sup>
 cation is located in the periphery of the tunnels while the other two are situated in the centres: all Na<sup>+</sup>
 cations exhibit half-occupancy. The structure of the studied material is compared with those of various related minerals reported in the literature.</p>
</abstract>
</article-meta>
</front>
</pmc>
<affiliations><list><country><li>Tunisie</li>
</country>
<region><li>Gouvernorat de Tunis</li>
</region>
<settlement><li>Tunis</li>
</settlement>
<orgName><li>Université de Tunis - El Manar</li>
</orgName>
</list>
<tree><country name="Tunisie"><noRegion><name sortKey="Marzouki, Riadh" sort="Marzouki, Riadh" uniqKey="Marzouki R" first="Riadh" last="Marzouki">Riadh Marzouki</name>
</noRegion>
<name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
<name sortKey="Frigui, Wafa" sort="Frigui, Wafa" uniqKey="Frigui W" first="Wafa" last="Frigui">Wafa Frigui</name>
<name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
<name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
</country>
</tree>
</affiliations>
</record>

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6

β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki