β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6
Identifieur interne : 000369 ( Pmc/Curation ); précédent : 000368; suivant : 000370β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6
Auteurs : Riadh Marzouki [Tunisie] ; Wafa Frigui [Tunisie] ; Abderrahmen Guesmi [Tunisie] ; Mohamed Faouzi Zid [Tunisie] ; Ahmed Driss [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.
Abstract
The title compound, tetrasodium lithium cobalt aluminium hexa(orthoarsenate), was synthesized by a solid state reaction route. In the crystal structure, Co2+ ions are partially substituted by Al3+ in an octahedral environment [
Url:
DOI: 10.1107/S1600536813025233
PubMed: 24098157
PubMed Central: 3790335
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PMC:3790335Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">β-Xenophyllite-type Na<sub>4</sub>
Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</title>
<author><name sortKey="Marzouki, Riadh" sort="Marzouki, Riadh" uniqKey="Marzouki R" first="Riadh" last="Marzouki">Riadh Marzouki</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Frigui, Wafa" sort="Frigui, Wafa" uniqKey="Frigui W" first="Wafa" last="Frigui">Wafa Frigui</name>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">β-Xenophyllite-type Na<sub>4</sub>
Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</title>
<author><name sortKey="Marzouki, Riadh" sort="Marzouki, Riadh" uniqKey="Marzouki R" first="Riadh" last="Marzouki">Riadh Marzouki</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Frigui, Wafa" sort="Frigui, Wafa" uniqKey="Frigui W" first="Wafa" last="Frigui">Wafa Frigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2013">2013</date>
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<front><div type="abstract" xml:lang="en"><p>The title compound, tetrasodium lithium cobalt aluminium hexa(orthoarsenate), was synthesized by a solid state reaction route. In the crystal structure, Co<sup>2+</sup>
ions are partially substituted by Al<sup>3+</sup>
in an octahedral environment [<italic>M</italic>
1 with site symmetry 2/<italic>m</italic>
; occupancy ratio Co:Al = 0.286 (10):0.714 (10)]. The charge compensation is ensured by Li<sup>+</sup>
cations sharing a tetrahedral site with Co<sup>2+</sup>
ions [<italic>M</italic>
2 with site symmetry 2; occupancy ratio Co:Li = 0.690 (5):0.310 (5)]. The anionic unit is formed by two octahedra and three tetrahedra linked only by corners. The Co<italic>M</italic>
1<italic>M</italic>
2As<sub>2</sub>
O<sub>19</sub>
units associate to an open three-dimensional framework containing tunnels propagating along the <italic>a-</italic>
axis direction. One Na<sup>+</sup>
cation is located in the periphery of the tunnels while the other two are situated in the centres: all Na<sup>+</sup>
cations exhibit half-occupancy. The structure of the studied material is compared with those of various related minerals reported in the literature.</p>
</div>
</front>
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<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="iso-abbrev">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title>
</journal-title-group>
<issn pub-type="epub">1600-5368</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
</journal-meta>
<article-meta><article-id pub-id-type="pmid">24098157</article-id>
<article-id pub-id-type="pmc">3790335</article-id>
<article-id pub-id-type="publisher-id">vn2076</article-id>
<article-id pub-id-type="doi">10.1107/S1600536813025233</article-id>
<article-id pub-id-type="coden">ACSEBH</article-id>
<article-id pub-id-type="pii">S1600536813025233</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Inorganic Papers</subject>
</subj-group>
</article-categories>
<title-group><article-title>β-Xenophyllite-type Na<sub>4</sub>
Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</article-title>
<alt-title><italic>Na<sub>4</sub>
Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Marzouki</surname>
<given-names>Riadh</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Frigui</surname>
<given-names>Wafa</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Guesmi</surname>
<given-names>Abderrahmen</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Zid</surname>
<given-names>Mohamed Faouzi</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Driss</surname>
<given-names>Ahmed</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<aff id="a"><label>a</label>
Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>faouzi.zid@fst.rnu.tn</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>10</month>
<year>2013</year>
</pub-date>
<pub-date pub-type="epub"><day>21</day>
<month>9</month>
<year>2013</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>21</day>
<month>9</month>
<year>2013</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
. </pmc-comment>
<volume>69</volume>
<issue>Pt 10</issue>
<issue-id pub-id-type="publisher-id">e131000</issue-id>
<fpage>i65</fpage>
<lpage>i66</lpage>
<history><date date-type="received"><day>02</day>
<month>9</month>
<year>2013</year>
</date>
<date date-type="accepted"><day>11</day>
<month>9</month>
<year>2013</year>
</date>
</history>
<permissions><copyright-statement>© Marzouki et al. 2013</copyright-statement>
<copyright-year>2013</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536813025233">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract><p>The title compound, tetrasodium lithium cobalt aluminium hexa(orthoarsenate), was synthesized by a solid state reaction route. In the crystal structure, Co<sup>2+</sup>
ions are partially substituted by Al<sup>3+</sup>
in an octahedral environment [<italic>M</italic>
1 with site symmetry 2/<italic>m</italic>
; occupancy ratio Co:Al = 0.286 (10):0.714 (10)]. The charge compensation is ensured by Li<sup>+</sup>
cations sharing a tetrahedral site with Co<sup>2+</sup>
ions [<italic>M</italic>
2 with site symmetry 2; occupancy ratio Co:Li = 0.690 (5):0.310 (5)]. The anionic unit is formed by two octahedra and three tetrahedra linked only by corners. The Co<italic>M</italic>
1<italic>M</italic>
2As<sub>2</sub>
O<sub>19</sub>
units associate to an open three-dimensional framework containing tunnels propagating along the <italic>a-</italic>
axis direction. One Na<sup>+</sup>
cation is located in the periphery of the tunnels while the other two are situated in the centres: all Na<sup>+</sup>
cations exhibit half-occupancy. The structure of the studied material is compared with those of various related minerals reported in the literature.</p>
</abstract>
</article-meta>
</front>
</pmc>
</record>
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