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Zn1-xCoxO diluted magnetic semiconductors synthesized under hydrothermal conditions

Identifieur interne : 000129 ( PascalFrancis/Curation ); précédent : 000128; suivant : 000130

Zn1-xCoxO diluted magnetic semiconductors synthesized under hydrothermal conditions

Auteurs : M. Bouloudenine [France, Algérie] ; N. Viart [France] ; S. Colis [France] ; A. Dinia [France]

Source :

RBID : Pascal:06-0371434

Descripteurs français

English descriptors

Abstract

Polycrystalline Zn1-xCoxO magnetic semiconductors were synthesized by hydrothermal technique from aqueous solutions of Zn and Co acetates using potassium hydroxide KOH as hydrolytic catalyst. The structural and magnetic properties of the samples were investigated as a function of acetates and KOH concentrations. The results show that the highest amount of Co that can be successfully inserted in the ZnO matrix is around 10%, when using concentrations of 0.5 and 0.77 mol/L of acetate and KOH, respectively. For the Zn0.9Co0.1O sample, X-ray diffraction indicates a pure ZnO würtzite structure free of parasitic phases in agreement with optical measurements that reveal the presence of Co2+ cations in substitution of Zn2+. The magnetization measurements show a paramagnetic behaviour and no evidence of ferromagnetism. This may be due to the absence of free carriers.
pA  
A01 01  1    @0 0920-5861
A02 01      @0 CATTEA
A03   1    @0 Catal. today
A05       @2 113
A06       @2 3-4
A08 01  1  ENG  @1 Zn1-xCoxO diluted magnetic semiconductors synthesized under hydrothermal conditions
A09 01  1  ENG  @1 Catalysis, Nanomaterials and Environment
A11 01  1    @1 BOULOUDENINE (M.)
A11 02  1    @1 VIART (N.)
A11 03  1    @1 COLIS (S.)
A11 04  1    @1 DINIA (A.)
A12 01  1    @1 GARIN (François) @9 ed.
A12 02  1    @1 MAAMACHE (Mustapha) @9 ed.
A12 03  1    @1 SCHMERBER (Guy) @9 ed.
A12 04  1    @1 DEMANGEAT (Claude) @9 ed.
A14 01      @1 Institut de Physique et Chimie des Matériaux de Strasbourg, IPCMS, Groupe des Matériaux Inorganiques, CNRS-UMR 7504, ULP-ECPM, 23 Rue du Loess, BP 43 @2 67034 Strasbourg @3 FRA @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut.
A14 02      @1 Université de Annaba, Faculté des Sciences, Département de Physique, BP 12 @2 Annaba 23000 @3 DZA @Z 1 aut.
A15 01      @1 Laboratoire des Matériaux, Surfaces et Procédés pour la Catalyse (LMSPC), UMR 7515-CNRS-ULP-ECPM, 25 rue Becquerel @2 67087 Strasbourg @3 FRA @Z 1 aut.
A15 02      @1 Département de Physique, Faculté des Sciences, Université Ferhat Abbas @2 1900 Sétif @3 DZA @Z 2 aut.
A15 03      @1 Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), Université Louis Pasteur, UMR 7504-CNRS-ULP, 23 rue du Loess, BP 43 @2 67034 Strasbourg @3 FRA @Z 3 aut. @Z 4 aut.
A20       @1 240-244
A21       @1 2006
A23 01      @0 ENG
A43 01      @1 INIST @2 21357 @5 354000142867030170
A44       @0 0000 @1 © 2006 INIST-CNRS. All rights reserved.
A45       @0 31 ref.
A47 01  1    @0 06-0371434
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Catalysis today
A66 01      @0 NLD
C01 01    ENG  @0 Polycrystalline Zn1-xCoxO magnetic semiconductors were synthesized by hydrothermal technique from aqueous solutions of Zn and Co acetates using potassium hydroxide KOH as hydrolytic catalyst. The structural and magnetic properties of the samples were investigated as a function of acetates and KOH concentrations. The results show that the highest amount of Co that can be successfully inserted in the ZnO matrix is around 10%, when using concentrations of 0.5 and 0.77 mol/L of acetate and KOH, respectively. For the Zn0.9Co0.1O sample, X-ray diffraction indicates a pure ZnO würtzite structure free of parasitic phases in agreement with optical measurements that reveal the presence of Co2+ cations in substitution of Zn2+. The magnetization measurements show a paramagnetic behaviour and no evidence of ferromagnetism. This may be due to the absence of free carriers.
C02 01  X    @0 001C01A03
C03 01  X  FRE  @0 Semiconducteur @5 01
C03 01  X  ENG  @0 Semiconductor materials @5 01
C03 01  X  SPA  @0 Semiconductor(material) @5 01
C03 02  X  FRE  @0 Condition hydrothermale @5 02
C03 02  X  ENG  @0 Hydrothermal condition @5 02
C03 02  X  SPA  @0 Condición hidrotermal @5 02
C03 03  3  FRE  @0 Métal transition composé @5 03
C03 03  3  ENG  @0 Transition element compounds @5 03
C03 04  X  FRE  @0 Film @5 04
C03 04  X  ENG  @0 Film @5 04
C03 04  X  SPA  @0 Película @5 04
C03 05  X  FRE  @0 Catalyse hétérogène @5 05
C03 05  X  ENG  @0 Heterogeneous catalysis @5 05
C03 05  X  SPA  @0 Catálisis heterogénea @5 05
C03 06  X  FRE  @0 Zinc Oxyde @2 NC @2 NA @5 06
C03 06  X  ENG  @0 Zinc Oxides @2 NC @2 NA @5 06
C03 06  X  SPA  @0 Zinc Óxido @2 NC @2 NA @5 06
C03 07  X  FRE  @0 Cobalt Oxyde @2 NC @2 NA @5 07
C03 07  X  ENG  @0 Cobalt Oxides @2 NC @2 NA @5 07
C03 07  X  SPA  @0 Cobalto Óxido @2 NC @2 NA @5 07
N21       @1 247
pR  
A30 01  1  ENG  @1 Colloquium on Environment, Materials, Physics and Energy @3 Ouargla DZA @4 2004-12-11

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Pascal:06-0371434

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O diluted magnetic semiconductors synthesized under hydrothermal conditions</title>
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<term>Transition element compounds</term>
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<div type="abstract" xml:lang="en">Polycrystalline Zn
<sub>1-x</sub>
Co
<sub>x</sub>
O magnetic semiconductors were synthesized by hydrothermal technique from aqueous solutions of Zn and Co acetates using potassium hydroxide KOH as hydrolytic catalyst. The structural and magnetic properties of the samples were investigated as a function of acetates and KOH concentrations. The results show that the highest amount of Co that can be successfully inserted in the ZnO matrix is around 10%, when using concentrations of 0.5 and 0.77 mol/L of acetate and KOH, respectively. For the Zn
<sub>0.9</sub>
Co
<sub>0.1</sub>
O sample, X-ray diffraction indicates a pure ZnO würtzite structure free of parasitic phases in agreement with optical measurements that reveal the presence of Co
<sup>2+</sup>
cations in substitution of Zn
<sup>2+</sup>
. The magnetization measurements show a paramagnetic behaviour and no evidence of ferromagnetism. This may be due to the absence of free carriers.</div>
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O diluted magnetic semiconductors synthesized under hydrothermal conditions</s1>
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<fC01 i1="01" l="ENG">
<s0>Polycrystalline Zn
<sub>1-x</sub>
Co
<sub>x</sub>
O magnetic semiconductors were synthesized by hydrothermal technique from aqueous solutions of Zn and Co acetates using potassium hydroxide KOH as hydrolytic catalyst. The structural and magnetic properties of the samples were investigated as a function of acetates and KOH concentrations. The results show that the highest amount of Co that can be successfully inserted in the ZnO matrix is around 10%, when using concentrations of 0.5 and 0.77 mol/L of acetate and KOH, respectively. For the Zn
<sub>0.9</sub>
Co
<sub>0.1</sub>
O sample, X-ray diffraction indicates a pure ZnO würtzite structure free of parasitic phases in agreement with optical measurements that reveal the presence of Co
<sup>2+</sup>
cations in substitution of Zn
<sup>2+</sup>
. The magnetization measurements show a paramagnetic behaviour and no evidence of ferromagnetism. This may be due to the absence of free carriers.</s0>
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<s5>04</s5>
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<s0>Film</s0>
<s5>04</s5>
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<fC03 i1="04" i2="X" l="SPA">
<s0>Película</s0>
<s5>04</s5>
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<s0>Catalyse hétérogène</s0>
<s5>05</s5>
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<fC03 i1="05" i2="X" l="ENG">
<s0>Heterogeneous catalysis</s0>
<s5>05</s5>
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<s0>Catálisis heterogénea</s0>
<s5>05</s5>
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<s0>Zinc Oxyde</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
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<fC03 i1="06" i2="X" l="ENG">
<s0>Zinc Oxides</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Zinc Óxido</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Cobalt Oxyde</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Cobalt Oxides</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Cobalto Óxido</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fN21>
<s1>247</s1>
</fN21>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>Colloquium on Environment, Materials, Physics and Energy</s1>
<s3>Ouargla DZA</s3>
<s4>2004-12-11</s4>
</fA30>
</pR>
</standard>
</inist>
</record>

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