On the performance of a highly loaded Co/SiO2 catalyst in the gas phase hydrogenation of crotonaldehyde thermal treatments: catalyst structure-selectivity relationship
Identifieur interne : 000101 ( PascalFrancis/Curation ); précédent : 000100; suivant : 000102On the performance of a highly loaded Co/SiO2 catalyst in the gas phase hydrogenation of crotonaldehyde thermal treatments: catalyst structure-selectivity relationship
Auteurs : F. Djerboua [Algérie] ; D. Benachour [Algérie] ; R. Touroude [France]Source :
- Applied catalysis. A, General [ 0926-860X ] ; 2005.
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- Pascal (Inist)
- Wicri :
English descriptors
- KwdEn :
Abstract
This paper reports on the performance and its relation with the structure of a highly loaded (41 wt.%) Co/SiO2 catalyst in the gas phase hydrogenation of crotonaldehyde when varying the thermal treatments to which the catalyst precursor has been subjected. The optimum calcination and reduction temperatures were identified where the highest selectivity to crotyl alcohol (around 90%) was obtained with the catalyst calcined at 400 °C and reduced at 350 °C even at conversions as high as 60%. Higher temperature of calcination was found to lower the crotyl alcohol selectivity. Both, lower and higher reduction temperatures will not favour the crotyl alcohol formation. These results were interpreted and correlated with the surface structure of the catalyst which was shown by temperature programmed reduction (TPR) and X-ray photoelectron spectroscopy (XPS) analysis. Depending on the thermal conditions imposed, the surface consisted of either Co metal, or coexisting metal and its oxide; structure which favours the high crotyl alcohol selectivity. By TEM analysis, large particles (diameter exceeding 50 nm) were identified after reduction at 350 °C. A global activation energy of 44 kJ/mol was obtained with this catalyst. In the light of the obtained results a discussion on the reaction mechanism involving metal, metal-oxide double sites has been put forward. It was emphasised that, for selective hydrogenation of crotonaldehyde into unsaturated alcohol, Co catalysts compete favourably with platinum based catalysts.
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catalyst in the gas phase hydrogenation of crotonaldehyde thermal treatments: catalyst structure-selectivity relationship</title>
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<front><div type="abstract" xml:lang="en">This paper reports on the performance and its relation with the structure of a highly loaded (41 wt.%) Co/SiO<sub>2</sub>
catalyst in the gas phase hydrogenation of crotonaldehyde when varying the thermal treatments to which the catalyst precursor has been subjected. The optimum calcination and reduction temperatures were identified where the highest selectivity to crotyl alcohol (around 90%) was obtained with the catalyst calcined at 400 °C and reduced at 350 °C even at conversions as high as 60%. Higher temperature of calcination was found to lower the crotyl alcohol selectivity. Both, lower and higher reduction temperatures will not favour the crotyl alcohol formation. These results were interpreted and correlated with the surface structure of the catalyst which was shown by temperature programmed reduction (TPR) and X-ray photoelectron spectroscopy (XPS) analysis. Depending on the thermal conditions imposed, the surface consisted of either Co metal, or coexisting metal and its oxide; structure which favours the high crotyl alcohol selectivity. By TEM analysis, large particles (diameter exceeding 50 nm) were identified after reduction at 350 °C. A global activation energy of 44 kJ/mol was obtained with this catalyst. In the light of the obtained results a discussion on the reaction mechanism involving metal, metal-oxide double sites has been put forward. It was emphasised that, for selective hydrogenation of crotonaldehyde into unsaturated alcohol, Co catalysts compete favourably with platinum based catalysts.</div>
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<fA14 i1="02"><s1>LMSPC, UMR 7515 du CNRS ECPM.ULP, 25 rue Becquerel</s1>
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<fC01 i1="01" l="ENG"><s0>This paper reports on the performance and its relation with the structure of a highly loaded (41 wt.%) Co/SiO<sub>2</sub>
catalyst in the gas phase hydrogenation of crotonaldehyde when varying the thermal treatments to which the catalyst precursor has been subjected. The optimum calcination and reduction temperatures were identified where the highest selectivity to crotyl alcohol (around 90%) was obtained with the catalyst calcined at 400 °C and reduced at 350 °C even at conversions as high as 60%. Higher temperature of calcination was found to lower the crotyl alcohol selectivity. Both, lower and higher reduction temperatures will not favour the crotyl alcohol formation. These results were interpreted and correlated with the surface structure of the catalyst which was shown by temperature programmed reduction (TPR) and X-ray photoelectron spectroscopy (XPS) analysis. Depending on the thermal conditions imposed, the surface consisted of either Co metal, or coexisting metal and its oxide; structure which favours the high crotyl alcohol selectivity. By TEM analysis, large particles (diameter exceeding 50 nm) were identified after reduction at 350 °C. A global activation energy of 44 kJ/mol was obtained with this catalyst. In the light of the obtained results a discussion on the reaction mechanism involving metal, metal-oxide double sites has been put forward. It was emphasised that, for selective hydrogenation of crotonaldehyde into unsaturated alcohol, Co catalysts compete favourably with platinum based catalysts.</s0>
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<s2>NK</s2>
<s2>FX</s2>
<s5>01</s5>
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<s2>NK</s2>
<s2>FX</s2>
<s5>01</s5>
</fC03>
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<s2>NK</s2>
<s2>FX</s2>
<s5>01</s5>
</fC03>
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<s5>02</s5>
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<s5>02</s5>
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<s5>02</s5>
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<s5>03</s5>
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<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Fase gaseosa</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Hydrogénation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Hydrogenation</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Hidrogenación</s0>
<s5>04</s5>
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<s5>05</s5>
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<s5>05</s5>
</fC03>
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<s5>05</s5>
</fC03>
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<s5>06</s5>
</fC03>
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<s5>06</s5>
</fC03>
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<s5>07</s5>
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<s5>07</s5>
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<s5>08</s5>
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<s5>08</s5>
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<s5>09</s5>
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<s5>09</s5>
</fC03>
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<s5>09</s5>
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<s2>NC</s2>
<s5>12</s5>
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<s2>NC</s2>
<s5>12</s5>
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<fC03 i1="10" i2="X" l="SPA"><s0>Cobalto</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
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<s4>INC</s4>
<s5>32</s5>
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<s5>10</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Enaldehyde</s0>
<s5>10</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Enaldehido</s0>
<s5>10</s5>
</fC07>
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<s2>NC</s2>
<s5>11</s5>
</fC07>
<fC07 i1="02" i2="X" l="ENG"><s0>Transition metal</s0>
<s2>NC</s2>
<s5>11</s5>
</fC07>
<fC07 i1="02" i2="X" l="SPA"><s0>Metal transición</s0>
<s2>NC</s2>
<s5>11</s5>
</fC07>
<fN21><s1>115</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
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<fN82><s1>OTO</s1>
</fN82>
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