CobaltMaghrebV1, PascalFrancis, Curation, bibRecord, 000065

Crystal structure of new hexahydrate dicobalt pyrophosphate Co2P2O7.6 H2O: comparison with Co2P2O7.2 H2O, α-, β- and γ-Co2P2O7

Identifieur interne : 000065 ( PascalFrancis/Curation ); précédent : 000064; suivant : 000066

Crystal structure of new hexahydrate dicobalt pyrophosphate Co2P2O7.6 H2O: comparison with Co2P2O7.2 H2O, α-, β- and γ-Co2P2O7

Auteurs : F. Capitelli [Italie] ; M. Harcharras [Maroc] ; H. Assaaoudi [Maroc] ; A. Ennaciri [Maroc] ; A. G. G. Moliterni [Italie] ; V. Bertolasi [Italie]

Source :

Zeitschrift für Kristallographie [ 0044-2968 ] ; 2003.

RBID : Pascal:03-0320033

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Diffraction RX, Structure cristalline, Mode empilement, Liaison hydrogène, Conformation, Cobalt Diphosphate, Cobalt Diphosphate, Hydrate, 6166F, Co2P2O7, Co O P.

English descriptors

KwdEn :
- Cobalt Diphosphates, Cobalt Pyrophosphates, Conformation, Crystal structure, Experimental study, Hydrates, Hydrogen bonds, Stacking sequence, XRD.

Abstract

A new dicobalt pyrophosphate, Co₂P₂O₇.6 H₂O, has been synthesized and characterized by single crystal X-ray diffraction. The compound belongs to the monoclinic space group P2₁/n, and its unit cell dimensions are: a = 7.2077(2), b = 18.3373(5), c = 7.6762(2) Å, β = 92.4356(15)°, V = 1013.64(5) Å³, Z = 4. The structural parameters were refined to an R index of 0.0570 for 1937 reflections with I > 2σ(I_o). The framework of this pyrophosphate is made by the packing of layers of discrete CoO₆ octahedra connected by double tetrahedra P₂O₇ groups. The (P₂O₇)^4- anion group shows bent eclipsed conformation. A comparative study among anhydrous (α-, β- and γ-Co₂P₂O₇) and hydrated forms (Co₂P₂O₇ . 2 H₂O) of dicobalt pyrophosphates known in literature is presented.

A01	`01`	`1`		`@0 0044-2968`
A02	`01`			`@0 ZEKRDZ`
A03		`1`		`@0 Z. Kristallogr.`
A05				`@2 218`
A06				`@2 5`
A08	`01`	`1`	`ENG`	`@1 Crystal structure of new hexahydrate dicobalt pyrophosphate Co₂P₂O₇.6 H₂O: comparison with Co₂P₂O₇.2 H₂O, α-, β- and γ-Co₂P₂O₇`
A11	`01`	`1`		`@1 CAPITELLI (F.)`
A11	`02`	`1`		`@1 HARCHARRAS (M.)`
A11	`03`	`1`		`@1 ASSAAOUDI (H.)`
A11	`04`	`1`		`@1 ENNACIRI (A.)`
A11	`05`	`1`		`@1 MOLITERNI (A. G. G.)`
A11	`06`	`1`		`@1 BERTOLASI (V.)`
A14	`01`			`@1 CNR - Institute of Crystallography (IC), c/o Dipartimento Geomineralogico, Via Orabona 4 @2 70125 Bari @3 ITA @Z 1 aut. @Z 5 aut.`
A14	`02`			`@1 Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University Ibn Tofail; B.P.133 @2 14000 Kenitra @3 MAR @Z 2 aut. @Z 3 aut. @Z 4 aut.`
A14	`03`			`@1 Dipartimento di Chimica and Centro di Strutturistica Diffrattometrica, University di Ferrara, via Borsari 46 @2 44100 Ferrara @3 ITA @Z 6 aut.`
A20				`@1 345-350`
A21				`@1 2003`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 915 @5 354000111143530030`
A44				`@0 0000 @1 © 2003 INIST-CNRS. All rights reserved.`
A45				`@0 36 ref.`
A47	`01`	`1`		`@0 03-0320033`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Zeitschrift für Kristallographie`
A66	`01`			`@0 DEU`
C01	`01`		`ENG`	@0 A new dicobalt pyrophosphate, Co₂P₂O₇.6 H₂O, has been synthesized and characterized by single crystal X-ray diffraction. The compound belongs to the monoclinic space group P2₁/n, and its unit cell dimensions are: a = 7.2077(2), b = 18.3373(5), c = 7.6762(2) Å, β = 92.4356(15)°, V = 1013.64(5) Å³, Z = 4. The structural parameters were refined to an R index of 0.0570 for 1937 reflections with I > 2σ(I_o). The framework of this pyrophosphate is made by the packing of layers of discrete CoO₆ octahedra connected by double tetrahedra P₂O₇ groups. The (P₂O₇)^4- anion group shows bent eclipsed conformation. A comparative study among anhydrous (α-, β- and γ-Co₂P₂O₇) and hydrated forms (Co₂P₂O₇ . 2 H₂O) of dicobalt pyrophosphates known in literature is presented.
C02	`01`	`3`		`@0 001B60A66F4`
C03	`01`	`3`	`FRE`	`@0 Etude expérimentale @5 01`
C03	`01`	`3`	`ENG`	`@0 Experimental study @5 01`
C03	`02`	`3`	`FRE`	`@0 Diffraction RX @5 02`
C03	`02`	`3`	`ENG`	`@0 XRD @5 02`
C03	`03`	`3`	`FRE`	`@0 Structure cristalline @5 03`
C03	`03`	`3`	`ENG`	`@0 Crystal structure @5 03`
C03	`04`	`X`	`FRE`	`@0 Mode empilement @5 04`
C03	`04`	`X`	`ENG`	`@0 Stacking sequence @5 04`
C03	`04`	`X`	`SPA`	`@0 Modo apilamiento @5 04`
C03	`05`	`3`	`FRE`	`@0 Liaison hydrogène @5 05`
C03	`05`	`3`	`ENG`	`@0 Hydrogen bonds @5 05`
C03	`06`	`X`	`FRE`	`@0 Conformation @5 06`
C03	`06`	`X`	`ENG`	`@0 Conformation @5 06`
C03	`06`	`X`	`SPA`	`@0 Conformación @5 06`
C03	`07`	`X`	`FRE`	`@0 Cobalt Diphosphate @2 NC @2 NA @5 07`
C03	`07`	`X`	`ENG`	`@0 Cobalt Diphosphates @2 NC @2 NA @5 07`
C03	`07`	`X`	`SPA`	`@0 Difosfato @2 NC @2 NA @5 07`
C03	`08`	`3`	`FRE`	`@0 Cobalt Diphosphate @2 NC @2 NA @5 08`
C03	`08`	`3`	`ENG`	`@0 Cobalt Pyrophosphates @2 NC @2 NA @5 08`
C03	`09`	`3`	`FRE`	`@0 Hydrate @2 NA @5 09`
C03	`09`	`3`	`ENG`	`@0 Hydrates @2 NA @5 09`
C03	`10`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 56`
C03	`11`	`3`	`FRE`	`@0 Co2P2O7 @4 INC @5 93`
C03	`12`	`3`	`FRE`	`@0 Co O P @4 INC @5 94`
C07	`01`	`3`	`FRE`	`@0 Phosphate @2 NA @5 16`
C07	`01`	`3`	`ENG`	`@0 Phosphates @2 NA @5 16`
C07	`02`	`3`	`FRE`	`@0 Composé minéral @5 81`
C07	`02`	`3`	`ENG`	`@0 Inorganic compounds @5 81`
C07	`03`	`3`	`FRE`	`@0 Métal transition composé @5 82`
C07	`03`	`3`	`ENG`	`@0 Transition element compounds @5 82`
N21				`@1 216`
N82				`@1 PSI`

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Pascal:03-0320033

Le document en format XML

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P<sub>2</sub>
O<sub>7</sub>
.6 H<sub>2</sub>
O: comparison with Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
.2 H<sub>2</sub>
O, α-, β- and γ-Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
</title>
<author><name sortKey="Capitelli, F" sort="Capitelli, F" uniqKey="Capitelli F" first="F." last="Capitelli">F. Capitelli</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Crystal structure of new hexahydrate dicobalt pyrophosphate Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
.6 H<sub>2</sub>
O: comparison with Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
.2 H<sub>2</sub>
O, α-, β- and γ-Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
</title>
<author><name sortKey="Capitelli, F" sort="Capitelli, F" uniqKey="Capitelli F" first="F." last="Capitelli">F. Capitelli</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>CNR - Institute of Crystallography (IC), c/o Dipartimento Geomineralogico, Via Orabona 4</s1>
<s2>70125 Bari</s2>
<s3>ITA</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Italie</country>
</affiliation>
</author>
<author><name sortKey="Harcharras, M" sort="Harcharras, M" uniqKey="Harcharras M" first="M." last="Harcharras">M. Harcharras</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University Ibn Tofail; B.P.133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
</affiliation>
</author>
<author><name sortKey="Assaaoudi, H" sort="Assaaoudi, H" uniqKey="Assaaoudi H" first="H." last="Assaaoudi">H. Assaaoudi</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University Ibn Tofail; B.P.133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
</affiliation>
</author>
<author><name sortKey="Ennaciri, A" sort="Ennaciri, A" uniqKey="Ennaciri A" first="A." last="Ennaciri">A. Ennaciri</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University Ibn Tofail; B.P.133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
</affiliation>
</author>
<author><name sortKey="Moliterni, A G G" sort="Moliterni, A G G" uniqKey="Moliterni A" first="A. G. G." last="Moliterni">A. G. G. Moliterni</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>CNR - Institute of Crystallography (IC), c/o Dipartimento Geomineralogico, Via Orabona 4</s1>
<s2>70125 Bari</s2>
<s3>ITA</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
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<country>Italie</country>
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<author><name sortKey="Bertolasi, V" sort="Bertolasi, V" uniqKey="Bertolasi V" first="V." last="Bertolasi">V. Bertolasi</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Dipartimento di Chimica and Centro di Strutturistica Diffrattometrica, University di Ferrara, via Borsari 46</s1>
<s2>44100 Ferrara</s2>
<s3>ITA</s3>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Italie</country>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Zeitschrift für Kristallographie</title>
<title level="j" type="abbreviated">Z. Kristallogr.</title>
<idno type="ISSN">0044-2968</idno>
<imprint><date when="2003">2003</date>
</imprint>
</series>
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</sourceDesc>
<seriesStmt><title level="j" type="main">Zeitschrift für Kristallographie</title>
<title level="j" type="abbreviated">Z. Kristallogr.</title>
<idno type="ISSN">0044-2968</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt Diphosphates</term>
<term>Cobalt Pyrophosphates</term>
<term>Conformation</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Hydrates</term>
<term>Hydrogen bonds</term>
<term>Stacking sequence</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Mode empilement</term>
<term>Liaison hydrogène</term>
<term>Conformation</term>
<term>Cobalt Diphosphate</term>
<term>Cobalt Diphosphate</term>
<term>Hydrate</term>
<term>6166F</term>
<term>Co2P2O7</term>
<term>Co O P</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">A new dicobalt pyrophosphate, Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
.6 H<sub>2</sub>
O, has been synthesized and characterized by single crystal X-ray diffraction. The compound belongs to the monoclinic space group P2<sub>1</sub>
/n, and its unit cell dimensions are: a = 7.2077(2), b = 18.3373(5), c = 7.6762(2) Å, β = 92.4356(15)°, V = 1013.64(5) Å<sup>3</sup>
, Z = 4. The structural parameters were refined to an R index of 0.0570 for 1937 reflections with I > 2σ(I<sub>o</sub>
). The framework of this pyrophosphate is made by the packing of layers of discrete CoO<sub>6</sub>
 octahedra connected by double tetrahedra P<sub>2</sub>
O<sub>7</sub>
 groups. The (P<sub>2</sub>
O<sub>7</sub>
)<sup>4-</sup>
 anion group shows bent eclipsed conformation. A comparative study among anhydrous (α-, β- and γ-Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
) and hydrated forms (Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
 . 2 H<sub>2</sub>
O) of dicobalt pyrophosphates known in literature is presented.</div>
</front>
</TEI>
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</fA03>
<fA05><s2>218</s2>
</fA05>
<fA06><s2>5</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Crystal structure of new hexahydrate dicobalt pyrophosphate Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
.6 H<sub>2</sub>
O: comparison with Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
.2 H<sub>2</sub>
O, α-, β- and γ-Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>CAPITELLI (F.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>HARCHARRAS (M.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>ASSAAOUDI (H.)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>ENNACIRI (A.)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>MOLITERNI (A. G. G.)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>BERTOLASI (V.)</s1>
</fA11>
<fA14 i1="01"><s1>CNR - Institute of Crystallography (IC), c/o Dipartimento Geomineralogico, Via Orabona 4</s1>
<s2>70125 Bari</s2>
<s3>ITA</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University Ibn Tofail; B.P.133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Dipartimento di Chimica and Centro di Strutturistica Diffrattometrica, University di Ferrara, via Borsari 46</s1>
<s2>44100 Ferrara</s2>
<s3>ITA</s3>
<sZ>6 aut.</sZ>
</fA14>
<fA20><s1>345-350</s1>
</fA20>
<fA21><s1>2003</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>915</s2>
<s5>354000111143530030</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2003 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>36 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>03-0320033</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Zeitschrift für Kristallographie</s0>
</fA64>
<fA66 i1="01"><s0>DEU</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>A new dicobalt pyrophosphate, Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
.6 H<sub>2</sub>
O, has been synthesized and characterized by single crystal X-ray diffraction. The compound belongs to the monoclinic space group P2<sub>1</sub>
/n, and its unit cell dimensions are: a = 7.2077(2), b = 18.3373(5), c = 7.6762(2) Å, β = 92.4356(15)°, V = 1013.64(5) Å<sup>3</sup>
, Z = 4. The structural parameters were refined to an R index of 0.0570 for 1937 reflections with I > 2σ(I<sub>o</sub>
). The framework of this pyrophosphate is made by the packing of layers of discrete CoO<sub>6</sub>
 octahedra connected by double tetrahedra P<sub>2</sub>
O<sub>7</sub>
 groups. The (P<sub>2</sub>
O<sub>7</sub>
)<sup>4-</sup>
 anion group shows bent eclipsed conformation. A comparative study among anhydrous (α-, β- and γ-Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
) and hydrated forms (Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
 . 2 H<sub>2</sub>
O) of dicobalt pyrophosphates known in literature is presented.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F4</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Mode empilement</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Stacking sequence</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Modo apilamiento</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Liaison hydrogène</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Hydrogen bonds</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Conformation</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Conformation</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Conformación</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Cobalt Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Cobalt Diphosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Difosfato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Cobalt Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Cobalt Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Hydrate</s0>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Hydrates</s0>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Co2P2O7</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>Co O P</s0>
<s4>INC</s4>
<s5>94</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Phosphate</s0>
<s2>NA</s2>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Phosphates</s0>
<s2>NA</s2>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>81</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>81</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>82</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>82</s5>
</fC07>
<fN21><s1>216</s1>
</fN21>
<fN82><s1>PSI</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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   |texte=   Crystal structure of new hexahydrate dicobalt pyrophosphate Co2P2O7.6 H2O: comparison with Co2P2O7.2 H2O, α-, β- and γ-Co2P2O7
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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Crystal structure of new hexahydrate dicobalt pyrophosphate Co2P2O7.6 H2O: comparison with Co2P2O7.2 H2O, α-, β- and γ-Co2P2O7

Crystal structure of new hexahydrate dicobalt pyrophosphate Co2P2O7.6 H2O: comparison with Co2P2O7.2 H2O, α-, β- and γ-Co2P2O7

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