CobaltMaghrebV1, PascalFrancis, Curation, bibRecord, 000039

Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba2Co(CO3)2F2

Identifieur interne : 000039 ( PascalFrancis/Curation ); précédent : 000038; suivant : 000040

Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba2Co(CO3)2F2

Auteurs : A. Ben Ali [France] ; V. Maisonneuve [France] ; S. Kodjikian [France] ; L. S. Smiri [Tunisie] ; M. Leblanc [France]

Source :

Solid state sciences [ 1293-2558 ] ; 2002.

RBID : Pascal:02-0230687

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Préparation chimique, Synthèse hydrothermale, Diffraction RX, Structure cristalline, Susceptibilité magnétique, Aimantation, Antiferromagnétisme, Baryum composé, Cobalt composé, 6166F, 7530C, Ba2Co(CO3)2F2, Ba C Co F O, Fluorocarbonate.

English descriptors

KwdEn :
- Antiferromagnetism, Barium compounds, Chemical preparation, Cobalt compounds, Crystal structure, Experimental study, Fluorocarbonates, Hydrothermal synthesis, Magnetic susceptibility, Magnetization, XRD.

Abstract

The structure of Ba₂Co(CO₃)₂F₂, obtained by hydrothermal synthesis, is determined from X-ray single crystal diffraction data (1085 unique reflections, R = 0.034, R_W = 0.078). Ba₂Co(CO₃)₂F₂ is orthorhombic, space group Pbca (Z = 4), with a = 6.6226(6), b = 11.494(2), c = 9.021(2) Å and V = 686.7(4) Å³. It can be described from infinite (010) layers of [CoO₄F₂] octahedra and CO^2-₃ entities or from [BaO₃F]∞ sheets of [BaO₇F₃] polyhedra. Antiferromagnetic order occurs below T_N 6 K.

A01	`01`	`1`		`@0 1293-2558`
A03		`1`		`@0 Solid state sci.`
A05				`@2 4`
A06				`@2 4`
A08	`01`	`1`	`ENG`	`@1 Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba₂Co(CO₃)₂F₂`
A11	`01`	`1`		`@1 BEN ALI (A.)`
A11	`02`	`1`		`@1 MAISONNEUVE (V.)`
A11	`03`	`1`		`@1 KODJIKIAN (S.)`
A11	`04`	`1`		`@1 SMIRI (L. S.)`
A11	`05`	`1`		`@1 LEBLANC (M.)`
A14	`01`			`@1 Laboratoire des Fluorures, UMR 6010 CNRS, Faculté des Sciences, Université du Maine, avenue O. Messiaen @2 72085 Le Mans @3 FRA @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 5 aut.`
A14	`02`			`@1 Laboratoire de Chimie Inorganique et Structurale, Faculté des Sciences de Bizerte @2 7021 Jarzouna @3 TUN @Z 4 aut.`
A20				`@1 503-506`
A21				`@1 2002`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 11118 @5 354000100892180100`
A44				`@0 0000 @1 © 2002 INIST-CNRS. All rights reserved.`
A45				`@0 13 ref.`
A47	`01`	`1`		`@0 02-0230687`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Solid state sciences`
A66	`01`			`@0 FRA`
C01	`01`		`ENG`	@0 The structure of Ba₂Co(CO₃)₂F₂, obtained by hydrothermal synthesis, is determined from X-ray single crystal diffraction data (1085 unique reflections, R = 0.034, R_W = 0.078). Ba₂Co(CO₃)₂F₂ is orthorhombic, space group Pbca (Z = 4), with a = 6.6226(6), b = 11.494(2), c = 9.021(2) Å and V = 686.7(4) Å³. It can be described from infinite (010) layers of [CoO₄F₂] octahedra and CO^2-₃ entities or from [BaO₃F]∞ sheets of [BaO₇F₃] polyhedra. Antiferromagnetic order occurs below T_N 6 K.
C02	`01`	`3`		`@0 001B60A66F4`
C02	`02`	`3`		`@0 001B70E30C`
C03	`01`	`3`	`FRE`	`@0 Etude expérimentale @5 01`
C03	`01`	`3`	`ENG`	`@0 Experimental study @5 01`
C03	`02`	`3`	`FRE`	`@0 Préparation chimique @5 02`
C03	`02`	`3`	`ENG`	`@0 Chemical preparation @5 02`
C03	`03`	`3`	`FRE`	`@0 Synthèse hydrothermale @5 03`
C03	`03`	`3`	`ENG`	`@0 Hydrothermal synthesis @5 03`
C03	`04`	`3`	`FRE`	`@0 Diffraction RX @5 05`
C03	`04`	`3`	`ENG`	`@0 XRD @5 05`
C03	`05`	`3`	`FRE`	`@0 Structure cristalline @5 06`
C03	`05`	`3`	`ENG`	`@0 Crystal structure @5 06`
C03	`06`	`3`	`FRE`	`@0 Susceptibilité magnétique @5 07`
C03	`06`	`3`	`ENG`	`@0 Magnetic susceptibility @5 07`
C03	`07`	`3`	`FRE`	`@0 Aimantation @5 08`
C03	`07`	`3`	`ENG`	`@0 Magnetization @5 08`
C03	`08`	`3`	`FRE`	`@0 Antiferromagnétisme @5 09`
C03	`08`	`3`	`ENG`	`@0 Antiferromagnetism @5 09`
C03	`09`	`3`	`FRE`	`@0 Baryum composé @5 11`
C03	`09`	`3`	`ENG`	`@0 Barium compounds @5 11`
C03	`10`	`3`	`FRE`	`@0 Cobalt composé @5 12`
C03	`10`	`3`	`ENG`	`@0 Cobalt compounds @5 12`
C03	`11`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 56`
C03	`12`	`3`	`FRE`	`@0 7530C @2 PAC @4 INC @5 57`
C03	`13`	`3`	`FRE`	`@0 Ba2Co(CO3)2F2 @4 INC @5 94`
C03	`14`	`3`	`FRE`	`@0 Ba C Co F O @4 INC @5 95`
C03	`15`	`3`	`FRE`	`@0 Fluorocarbonate @4 CD @5 96`
C03	`15`	`3`	`ENG`	`@0 Fluorocarbonates @4 CD @5 96`
C07	`01`	`3`	`FRE`	`@0 Fluorure @2 NA @5 16`
C07	`01`	`3`	`ENG`	`@0 Fluorides @2 NA @5 16`
C07	`02`	`3`	`FRE`	`@0 Carbonate @2 NA @5 17`
C07	`02`	`3`	`ENG`	`@0 Carbonates @2 NA @5 17`
C07	`03`	`3`	`FRE`	`@0 Composé minéral @5 18`
C07	`03`	`3`	`ENG`	`@0 Inorganic compounds @5 18`
C07	`04`	`3`	`FRE`	`@0 Métal transition composé @5 81`
C07	`04`	`3`	`ENG`	`@0 Transition element compounds @5 81`
N21				`@1 140`
N82				`@1 PSI`

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Le document en format XML

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Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
</title>
<author><name sortKey="Ben Ali, A" sort="Ben Ali, A" uniqKey="Ben Ali A" first="A." last="Ben Ali">A. Ben Ali</name>
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<s3>FRA</s3>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba<sub>2</sub>
Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
</title>
<author><name sortKey="Ben Ali, A" sort="Ben Ali, A" uniqKey="Ben Ali A" first="A." last="Ben Ali">A. Ben Ali</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire des Fluorures, UMR 6010 CNRS, Faculté des Sciences, Université du Maine, avenue O. Messiaen</s1>
<s2>72085 Le Mans</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
</affiliation>
</author>
<author><name sortKey="Maisonneuve, V" sort="Maisonneuve, V" uniqKey="Maisonneuve V" first="V." last="Maisonneuve">V. Maisonneuve</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire des Fluorures, UMR 6010 CNRS, Faculté des Sciences, Université du Maine, avenue O. Messiaen</s1>
<s2>72085 Le Mans</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
</affiliation>
</author>
<author><name sortKey="Kodjikian, S" sort="Kodjikian, S" uniqKey="Kodjikian S" first="S." last="Kodjikian">S. Kodjikian</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire des Fluorures, UMR 6010 CNRS, Faculté des Sciences, Université du Maine, avenue O. Messiaen</s1>
<s2>72085 Le Mans</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
</affiliation>
</author>
<author><name sortKey="Smiri, L S" sort="Smiri, L S" uniqKey="Smiri L" first="L. S." last="Smiri">L. S. Smiri</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de Chimie Inorganique et Structurale, Faculté des Sciences de Bizerte</s1>
<s2>7021 Jarzouna</s2>
<s3>TUN</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
</affiliation>
</author>
<author><name sortKey="Leblanc, M" sort="Leblanc, M" uniqKey="Leblanc M" first="M." last="Leblanc">M. Leblanc</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire des Fluorures, UMR 6010 CNRS, Faculté des Sciences, Université du Maine, avenue O. Messiaen</s1>
<s2>72085 Le Mans</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>France</country>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Solid state sciences</title>
<title level="j" type="abbreviated">Solid state sci.</title>
<idno type="ISSN">1293-2558</idno>
<imprint><date when="2002">2002</date>
</imprint>
</series>
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</sourceDesc>
<seriesStmt><title level="j" type="main">Solid state sciences</title>
<title level="j" type="abbreviated">Solid state sci.</title>
<idno type="ISSN">1293-2558</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Antiferromagnetism</term>
<term>Barium compounds</term>
<term>Chemical preparation</term>
<term>Cobalt compounds</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Fluorocarbonates</term>
<term>Hydrothermal synthesis</term>
<term>Magnetic susceptibility</term>
<term>Magnetization</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Préparation chimique</term>
<term>Synthèse hydrothermale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Susceptibilité magnétique</term>
<term>Aimantation</term>
<term>Antiferromagnétisme</term>
<term>Baryum composé</term>
<term>Cobalt composé</term>
<term>6166F</term>
<term>7530C</term>
<term>Ba2Co(CO3)2F2</term>
<term>Ba C Co F O</term>
<term>Fluorocarbonate</term>
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<front><div type="abstract" xml:lang="en">The structure of Ba<sub>2</sub>
Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
, obtained by hydrothermal synthesis, is determined from X-ray single crystal diffraction data (1085 unique reflections, R = 0.034, R<sub>W</sub>
 = 0.078). Ba<sub>2</sub>
Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
 is orthorhombic, space group Pbca (Z = 4), with a = 6.6226(6), b = 11.494(2), c = 9.021(2) Å and V = 686.7(4) Å<sup>3</sup>
. It can be described from infinite (010) layers of [CoO<sub>4</sub>
F<sub>2</sub>
] octahedra and CO<sup>2-</sup>
<sub>3</sub>
 entities or from [BaO<sub>3</sub>
F]∞ sheets of [BaO<sub>7</sub>
F<sub>3</sub>
] polyhedra. Antiferromagnetic order occurs below T<sub>N</sub>
  6 K.</div>
</front>
</TEI>
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</fA05>
<fA06><s2>4</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba<sub>2</sub>
Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>BEN ALI (A.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>MAISONNEUVE (V.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>KODJIKIAN (S.)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>SMIRI (L. S.)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>LEBLANC (M.)</s1>
</fA11>
<fA14 i1="01"><s1>Laboratoire des Fluorures, UMR 6010 CNRS, Faculté des Sciences, Université du Maine, avenue O. Messiaen</s1>
<s2>72085 Le Mans</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire de Chimie Inorganique et Structurale, Faculté des Sciences de Bizerte</s1>
<s2>7021 Jarzouna</s2>
<s3>TUN</s3>
<sZ>4 aut.</sZ>
</fA14>
<fA20><s1>503-506</s1>
</fA20>
<fA21><s1>2002</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>11118</s2>
<s5>354000100892180100</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2002 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>13 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>02-0230687</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
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<fA64 i1="01" i2="1"><s0>Solid state sciences</s0>
</fA64>
<fA66 i1="01"><s0>FRA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>The structure of Ba<sub>2</sub>
Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
, obtained by hydrothermal synthesis, is determined from X-ray single crystal diffraction data (1085 unique reflections, R = 0.034, R<sub>W</sub>
 = 0.078). Ba<sub>2</sub>
Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
 is orthorhombic, space group Pbca (Z = 4), with a = 6.6226(6), b = 11.494(2), c = 9.021(2) Å and V = 686.7(4) Å<sup>3</sup>
. It can be described from infinite (010) layers of [CoO<sub>4</sub>
F<sub>2</sub>
] octahedra and CO<sup>2-</sup>
<sub>3</sub>
 entities or from [BaO<sub>3</sub>
F]∞ sheets of [BaO<sub>7</sub>
F<sub>3</sub>
] polyhedra. Antiferromagnetic order occurs below T<sub>N</sub>
  6 K.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F4</s0>
</fC02>
<fC02 i1="02" i2="3"><s0>001B70E30C</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Préparation chimique</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Chemical preparation</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Synthèse hydrothermale</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Hydrothermal synthesis</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>XRD</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Susceptibilité magnétique</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Magnetic susceptibility</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Aimantation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Magnetization</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Antiferromagnétisme</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Antiferromagnetism</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Baryum composé</s0>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Barium compounds</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Cobalt composé</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Cobalt compounds</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>7530C</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Ba2Co(CO3)2F2</s0>
<s4>INC</s4>
<s5>94</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Ba C Co F O</s0>
<s4>INC</s4>
<s5>95</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Fluorocarbonate</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG"><s0>Fluorocarbonates</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Fluorure</s0>
<s2>NA</s2>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Fluorides</s0>
<s2>NA</s2>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Carbonate</s0>
<s2>NA</s2>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Carbonates</s0>
<s2>NA</s2>
<s5>17</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>18</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>18</s5>
</fC07>
<fC07 i1="04" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>81</s5>
</fC07>
<fC07 i1="04" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>81</s5>
</fC07>
<fN21><s1>140</s1>
</fN21>
<fN82><s1>PSI</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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	Serveur d'exploration sur le cobalt au Maghreb
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Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba2Co(CO3)2F2

Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba2Co(CO3)2F2

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