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Microstructural characterization of the oxide scale grown at the interface between PSZ top coat and MCrAlY bond coat

Identifieur interne : 000253 ( PascalFrancis/Corpus ); précédent : 000252; suivant : 000254

Microstructural characterization of the oxide scale grown at the interface between PSZ top coat and MCrAlY bond coat

Auteurs : B. Rhouta ; B. Pieraggi

Source :

RBID : Pascal:02-0303530

Descripteurs français

English descriptors

Abstract

The microstructure of alumina scale grown at the CoNiCrAlY / Y-PSZ (yttria- partially stabilized zirconia) interface upon oxidation in air at 1100 °C for 100 h has been investigated by XRD, SEM, TEM and EDS. The oxide scale microstructure of the plasma-sprayed thermal barrier coatings is characterized by a discontinuous evolution of grain size throughout the scale thickness. The columnar alumina grains in contact with MCrAIY as well as the important porosity observed close to Y-PSZ indicate that the scale growth was evolved by an anionic diffusion mechanism. The observation of a well-defined faceted interface between the innermost alumina grains and metallic bond-coat, as well as the occurrence of epitaxy between these phases definitively prove that the better adhesion of alumina to MCrAlY alloy was achieved by the joining of the oxide and metal lattices, rather than by a keying effect due to the internal oxide precipitates. These latter can contribute to alumina adherence by pinning the emitted dislocations resulting from the displacement of interfacial ledges during alumina growth, and thus increase the metallic strength near the interface.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0255-5476
A05       @2 369-372
A06       @3 p.1
A08 01  1  ENG  @1 Microstructural characterization of the oxide scale grown at the interface between PSZ top coat and MCrAlY bond coat
A09 01  1  ENG  @1 High temperature corrosion and protection of materials : Les Embiez, 22-26 May 2000
A09 02  5  FRE  @1 5e colloque international sur la corrosion et la protection des matériaux à haute température
A11 01  1    @1 RHOUTA (B.)
A11 02  1    @1 PIERAGGI (B.)
A12 01  1    @1 STREIFF (Roland) @9 ed.
A12 02  1    @1 WRIGHT (Ian G.) @9 ed.
A12 03  1    @1 KRUTENAT (Richard C.) @9 ed.
A12 04  1    @1 CAILLET (Marcel) @9 ed.
A12 05  1    @1 GALERIE (Alain) @9 ed.
A14 01      @1 Département de Chimie, Faculté des Sciences et Techniques Gueliz, B.P 618 @2 Marrakech @3 MAR @Z 1 aut.
A14 02      @1 ENSCT (CIRIMAT-INPT-UPS UMR 5085) @2 31077 Toulouse @3 FRA @Z 2 aut.
A20       @1 687-694
A21       @1 2001
A23 01      @0 ENG
A26 01      @0 0-87849-877-X
A43 01      @1 INIST @2 21741 @5 354000097020780790
A44       @0 0000 @1 © 2002 INIST-CNRS. All rights reserved.
A45       @0 13 ref.
A47 01  1    @0 02-0303530
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Materials science forum
A66 01      @0 CHE
C01 01    ENG  @0 The microstructure of alumina scale grown at the CoNiCrAlY / Y-PSZ (yttria- partially stabilized zirconia) interface upon oxidation in air at 1100 °C for 100 h has been investigated by XRD, SEM, TEM and EDS. The oxide scale microstructure of the plasma-sprayed thermal barrier coatings is characterized by a discontinuous evolution of grain size throughout the scale thickness. The columnar alumina grains in contact with MCrAIY as well as the important porosity observed close to Y-PSZ indicate that the scale growth was evolved by an anionic diffusion mechanism. The observation of a well-defined faceted interface between the innermost alumina grains and metallic bond-coat, as well as the occurrence of epitaxy between these phases definitively prove that the better adhesion of alumina to MCrAlY alloy was achieved by the joining of the oxide and metal lattices, rather than by a keying effect due to the internal oxide precipitates. These latter can contribute to alumina adherence by pinning the emitted dislocations resulting from the displacement of interfacial ledges during alumina growth, and thus increase the metallic strength near the interface.
C02 01  X    @0 001D11C06E
C02 02  X    @0 240
C03 01  X  FRE  @0 Revêtement non métallique @5 55
C03 01  X  ENG  @0 Non metal coating @5 55
C03 01  X  GER  @0 Nichtmetallischer Ueberzug @5 55
C03 01  X  SPA  @0 Revestimiento no metálico @5 55
C03 02  X  FRE  @0 Couche oxyde @5 56
C03 02  X  ENG  @0 Oxide layer @5 56
C03 02  X  GER  @0 Oxidschicht @5 56
C03 02  X  SPA  @0 Capa óxido @5 56
C03 03  X  FRE  @0 Oxydation @5 57
C03 03  X  ENG  @0 Oxidation @5 57
C03 03  X  GER  @0 Oxidation @5 57
C03 03  X  SPA  @0 Oxidación @5 57
C03 04  X  FRE  @0 Interface @5 58
C03 04  X  ENG  @0 Interface @5 58
C03 04  X  GER  @0 Grenzflaeche @5 58
C03 04  X  SPA  @0 Interfase @5 58
C03 05  X  FRE  @0 Zircone stabilisée @5 59
C03 05  X  ENG  @0 Stabilized zirconia @5 59
C03 05  X  SPA  @0 Zircona estabilizada @5 59
C03 06  3  FRE  @0 Alliage base cobalt @2 NK @5 60
C03 06  3  ENG  @0 Cobalt base alloys @2 NK @5 60
C03 07  X  FRE  @0 Microstructure @5 61
C03 07  X  ENG  @0 Microstructure @5 61
C03 07  X  GER  @0 Mikrogefuege @5 61
C03 07  X  SPA  @0 Microestructura @5 61
C03 08  X  FRE  @0 Air @5 63
C03 08  X  ENG  @0 Air @5 63
C03 08  X  GER  @0 Luft @5 63
C03 08  X  SPA  @0 Aire @5 63
C03 09  X  FRE  @0 Projection plasma @5 64
C03 09  X  ENG  @0 Plasma spraying @5 64
C03 09  X  GER  @0 Plasmaspritzen @5 64
C03 09  X  SPA  @0 Proyección plasma @5 64
C03 10  X  FRE  @0 Traitement surface @5 74
C03 10  X  ENG  @0 Surface treatment @5 74
C03 10  X  GER  @0 Oberflaechenbehandlung @5 74
C03 10  X  SPA  @0 Tratamiento superficie @5 74
N21       @1 175
N82       @1 PSI
pR  
A30 01  1  ENG  @1 International symposium on high temperature corrosion and protection of materials @2 5 @3 Les Embiez FRA @4 2000-05-22
A30 02  1  FRE  @1 Colloque international sur la corrosion et la protection des matériaux à haute température @2 5 @3 Les Embiez FRA @4 2000-05-22

Format Inist (serveur)

NO : PASCAL 02-0303530 INIST
FT : 5e colloque international sur la corrosion et la protection des matériaux à haute température
ET : Microstructural characterization of the oxide scale grown at the interface between PSZ top coat and MCrAlY bond coat
AU : RHOUTA (B.); PIERAGGI (B.); STREIFF (Roland); WRIGHT (Ian G.); KRUTENAT (Richard C.); CAILLET (Marcel); GALERIE (Alain)
AF : Département de Chimie, Faculté des Sciences et Techniques Gueliz, B.P 618/Marrakech/Maroc (1 aut.); ENSCT (CIRIMAT-INPT-UPS UMR 5085)/31077 Toulouse/France (2 aut.)
DT : Publication en série; Congrès; Niveau analytique
SO : Materials science forum; ISSN 0255-5476; Suisse; Da. 2001; Vol. 369-372; No. p.1; Pp. 687-694; Bibl. 13 ref.
LA : Anglais
EA : The microstructure of alumina scale grown at the CoNiCrAlY / Y-PSZ (yttria- partially stabilized zirconia) interface upon oxidation in air at 1100 °C for 100 h has been investigated by XRD, SEM, TEM and EDS. The oxide scale microstructure of the plasma-sprayed thermal barrier coatings is characterized by a discontinuous evolution of grain size throughout the scale thickness. The columnar alumina grains in contact with MCrAIY as well as the important porosity observed close to Y-PSZ indicate that the scale growth was evolved by an anionic diffusion mechanism. The observation of a well-defined faceted interface between the innermost alumina grains and metallic bond-coat, as well as the occurrence of epitaxy between these phases definitively prove that the better adhesion of alumina to MCrAlY alloy was achieved by the joining of the oxide and metal lattices, rather than by a keying effect due to the internal oxide precipitates. These latter can contribute to alumina adherence by pinning the emitted dislocations resulting from the displacement of interfacial ledges during alumina growth, and thus increase the metallic strength near the interface.
CC : 001D11C06E; 240
FD : Revêtement non métallique; Couche oxyde; Oxydation; Interface; Zircone stabilisée; Alliage base cobalt; Microstructure; Air; Projection plasma; Traitement surface
ED : Non metal coating; Oxide layer; Oxidation; Interface; Stabilized zirconia; Cobalt base alloys; Microstructure; Air; Plasma spraying; Surface treatment
GD : Nichtmetallischer Ueberzug; Oxidschicht; Oxidation; Grenzflaeche; Mikrogefuege; Luft; Plasmaspritzen; Oberflaechenbehandlung
SD : Revestimiento no metálico; Capa óxido; Oxidación; Interfase; Zircona estabilizada; Microestructura; Aire; Proyección plasma; Tratamiento superficie
LO : INIST-21741.354000097020780790
ID : 02-0303530

Links to Exploration step

Pascal:02-0303530

Le document en format XML

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<div type="abstract" xml:lang="en">The microstructure of alumina scale grown at the CoNiCrAlY / Y-PSZ (yttria- partially stabilized zirconia) interface upon oxidation in air at 1100 °C for 100 h has been investigated by XRD, SEM, TEM and EDS. The oxide scale microstructure of the plasma-sprayed thermal barrier coatings is characterized by a discontinuous evolution of grain size throughout the scale thickness. The columnar alumina grains in contact with MCrAIY as well as the important porosity observed close to Y-PSZ indicate that the scale growth was evolved by an anionic diffusion mechanism. The observation of a well-defined faceted interface between the innermost alumina grains and metallic bond-coat, as well as the occurrence of epitaxy between these phases definitively prove that the better adhesion of alumina to MCrAlY alloy was achieved by the joining of the oxide and metal lattices, rather than by a keying effect due to the internal oxide precipitates. These latter can contribute to alumina adherence by pinning the emitted dislocations resulting from the displacement of interfacial ledges during alumina growth, and thus increase the metallic strength near the interface.</div>
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<s5>74</s5>
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<s0>Tratamiento superficie</s0>
<s5>74</s5>
</fC03>
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<s1>175</s1>
</fN21>
<fN82>
<s1>PSI</s1>
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<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>International symposium on high temperature corrosion and protection of materials</s1>
<s2>5</s2>
<s3>Les Embiez FRA</s3>
<s4>2000-05-22</s4>
</fA30>
<fA30 i1="02" i2="1" l="FRE">
<s1>Colloque international sur la corrosion et la protection des matériaux à haute température</s1>
<s2>5</s2>
<s3>Les Embiez FRA</s3>
<s4>2000-05-22</s4>
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<server>
<NO>PASCAL 02-0303530 INIST</NO>
<FT>5e colloque international sur la corrosion et la protection des matériaux à haute température</FT>
<ET>Microstructural characterization of the oxide scale grown at the interface between PSZ top coat and MCrAlY bond coat</ET>
<AU>RHOUTA (B.); PIERAGGI (B.); STREIFF (Roland); WRIGHT (Ian G.); KRUTENAT (Richard C.); CAILLET (Marcel); GALERIE (Alain)</AU>
<AF>Département de Chimie, Faculté des Sciences et Techniques Gueliz, B.P 618/Marrakech/Maroc (1 aut.); ENSCT (CIRIMAT-INPT-UPS UMR 5085)/31077 Toulouse/France (2 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Materials science forum; ISSN 0255-5476; Suisse; Da. 2001; Vol. 369-372; No. p.1; Pp. 687-694; Bibl. 13 ref.</SO>
<LA>Anglais</LA>
<EA>The microstructure of alumina scale grown at the CoNiCrAlY / Y-PSZ (yttria- partially stabilized zirconia) interface upon oxidation in air at 1100 °C for 100 h has been investigated by XRD, SEM, TEM and EDS. The oxide scale microstructure of the plasma-sprayed thermal barrier coatings is characterized by a discontinuous evolution of grain size throughout the scale thickness. The columnar alumina grains in contact with MCrAIY as well as the important porosity observed close to Y-PSZ indicate that the scale growth was evolved by an anionic diffusion mechanism. The observation of a well-defined faceted interface between the innermost alumina grains and metallic bond-coat, as well as the occurrence of epitaxy between these phases definitively prove that the better adhesion of alumina to MCrAlY alloy was achieved by the joining of the oxide and metal lattices, rather than by a keying effect due to the internal oxide precipitates. These latter can contribute to alumina adherence by pinning the emitted dislocations resulting from the displacement of interfacial ledges during alumina growth, and thus increase the metallic strength near the interface.</EA>
<CC>001D11C06E; 240</CC>
<FD>Revêtement non métallique; Couche oxyde; Oxydation; Interface; Zircone stabilisée; Alliage base cobalt; Microstructure; Air; Projection plasma; Traitement surface</FD>
<ED>Non metal coating; Oxide layer; Oxidation; Interface; Stabilized zirconia; Cobalt base alloys; Microstructure; Air; Plasma spraying; Surface treatment</ED>
<GD>Nichtmetallischer Ueberzug; Oxidschicht; Oxidation; Grenzflaeche; Mikrogefuege; Luft; Plasmaspritzen; Oberflaechenbehandlung</GD>
<SD>Revestimiento no metálico; Capa óxido; Oxidación; Interfase; Zircona estabilizada; Microestructura; Aire; Proyección plasma; Tratamiento superficie</SD>
<LO>INIST-21741.354000097020780790</LO>
<ID>02-0303530</ID>
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