CobaltMaghrebV1, PascalFrancis, Corpus, bibRecord, 000156

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

Identifieur interne : 000156 ( PascalFrancis/Corpus ); précédent : 000155; suivant : 000157

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

Auteurs : Francesco Capitelli ; Brahim El Bali ; Rachid Essehli ; Mohammed Lachkar ; Veronica Valentini ; Giorgio Mattei ; Jan Taraba ; Zdirak Zak

Source :

Zeitschrift für Kristallographie [ 0044-2968 ] ; 2006.

RBID : Pascal:06-0526554

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Mode vibration, Liaison hydrogène, Spectre Raman, Spectre IR, Spectre transformée Fourier, Diffraction RX, Structure cristalline, Ethylène, Ammonium phosphate, Cristal centrosymétrique, Matériau hybride, Réseau triclinique, Cobalt phosphate, Nickel phosphate, 6166F.

English descriptors

KwdEn :
- Ammonium phosphates, Centrosymmetrical crystals, Cobalt phosphates, Crystal structure, Ethylene, Experimental study, Fourier transform spectra, Hybrid material, Hydrogen bonds, Infrared spectra, Nickel phosphates, Raman spectra, Triclinic lattices, Vibrational modes, XRD.

Abstract

New ethylenediammonium diphosphates (NH₃(CH₂)₂NH₃)₂[Me(HP₂O₇)₂ . 2 H₂O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å³ (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å³ (2). The three-dimensional network is built up by discrete Me(HP₂O₇)₂ . 2 H₂O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

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A02	`01`			`@0 ZEKRDZ`
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A05				`@2 221`
A06				`@2 9`
A08	`01`	`1`	`ENG`	`@1 New isostructural ethylenediammonium diphosphates (NH₃(CH₂)₂NH₃)₂[Me(HP₂O₇)₂ . 2 H₂O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy`
A11	`01`	`1`		`@1 CAPITELLI (Francesco)`
A11	`02`	`1`		`@1 EL BALI (Brahim)`
A11	`03`	`1`		`@1 ESSEHLI (Rachid)`
A11	`04`	`1`		`@1 LACHKAR (Mohammed)`
A11	`05`	`1`		`@1 VALENTINI (Veronica)`
A11	`06`	`1`		`@1 MATTEI (Giorgio)`
A11	`07`	`1`		`@1 TARABA (Jan)`
A11	`08`	`1`		`@1 ZAK (Zdirak)`
A14	`01`			`@1 Istituto di Cristallografia (IC-CNR), sezione di Bari, Via Amendola 122/o @2 70126 Bari @3 ITA @Z 1 aut.`
A14	`02`			`@1 Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas @2 30000 Fès @3 MAR @Z 2 aut. @Z 3 aut. @Z 4 aut.`
A14	`03`			`@1 Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10 @2 00016 Monterotondo Stazione (Roma) @3 ITA @Z 5 aut. @Z 6 aut.`
A14	`04`			`@1 Department of Inorganic Chemistry, Masaryk University, Kotlárska 2 @2 61137 Brno @3 CZE @Z 7 aut. @Z 8 aut.`
A20				`@1 649-655`
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A23	`01`			`@0 ENG`
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A44				`@0 0000 @1 © 2006 INIST-CNRS. All rights reserved.`
A45				`@0 30 ref.`
A47	`01`	`1`		`@0 06-0526554`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Zeitschrift für Kristallographie`
A66	`01`			`@0 DEU`
C01	`01`		`ENG`	@0 New ethylenediammonium diphosphates (NH₃(CH₂)₂NH₃)₂[Me(HP₂O₇)₂ . 2 H₂O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å³ (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å³ (2). The three-dimensional network is built up by discrete Me(HP₂O₇)₂ . 2 H₂O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.
C02	`01`	`3`		`@0 001B60A66F7`
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C03	`01`	`3`	`ENG`	`@0 Experimental study @5 02`
C03	`02`	`3`	`FRE`	`@0 Mode vibration @5 03`
C03	`02`	`3`	`ENG`	`@0 Vibrational modes @5 03`
C03	`03`	`3`	`FRE`	`@0 Liaison hydrogène @5 04`
C03	`03`	`3`	`ENG`	`@0 Hydrogen bonds @5 04`
C03	`04`	`3`	`FRE`	`@0 Spectre Raman @5 05`
C03	`04`	`3`	`ENG`	`@0 Raman spectra @5 05`
C03	`05`	`3`	`FRE`	`@0 Spectre IR @5 06`
C03	`05`	`3`	`ENG`	`@0 Infrared spectra @5 06`
C03	`06`	`3`	`FRE`	`@0 Spectre transformée Fourier @5 07`
C03	`06`	`3`	`ENG`	`@0 Fourier transform spectra @5 07`
C03	`07`	`3`	`FRE`	`@0 Diffraction RX @5 08`
C03	`07`	`3`	`ENG`	`@0 XRD @5 08`
C03	`08`	`3`	`FRE`	`@0 Structure cristalline @5 14`
C03	`08`	`3`	`ENG`	`@0 Crystal structure @5 14`
C03	`09`	`3`	`FRE`	`@0 Ethylène @2 NK @5 15`
C03	`09`	`3`	`ENG`	`@0 Ethylene @2 NK @5 15`
C03	`10`	`3`	`FRE`	`@0 Ammonium phosphate @2 NK @5 16`
C03	`10`	`3`	`ENG`	`@0 Ammonium phosphates @2 NK @5 16`
C03	`11`	`X`	`FRE`	`@0 Cristal centrosymétrique @5 17`
C03	`11`	`X`	`ENG`	`@0 Centrosymmetrical crystals @5 17`
C03	`11`	`X`	`SPA`	`@0 Cristal centrosimétrico @5 17`
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C03	`12`	`X`	`ENG`	`@0 Hybrid material @5 18`
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C03	`13`	`3`	`FRE`	`@0 Réseau triclinique @5 19`
C03	`13`	`3`	`ENG`	`@0 Triclinic lattices @5 19`
C03	`14`	`3`	`FRE`	`@0 Cobalt phosphate @2 NK @5 20`
C03	`14`	`3`	`ENG`	`@0 Cobalt phosphates @2 NK @5 20`
C03	`15`	`3`	`FRE`	`@0 Nickel phosphate @2 NK @5 21`
C03	`15`	`3`	`ENG`	`@0 Nickel phosphates @2 NK @5 21`
C03	`16`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 56`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 48`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 48`
C07	`02`	`3`	`FRE`	`@0 Métal transition composé @5 49`
C07	`02`	`3`	`ENG`	`@0 Transition element compounds @5 49`
C07	`03`	`3`	`FRE`	`@0 Composé organique @5 50`
C07	`03`	`3`	`ENG`	`@0 Organic compounds @5 50`
N21				`@1 346`
N44	`01`			`@1 PSI`
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Format Inist (serveur)

NO :	PASCAL 06-0526554 INIST
ET :	New isostructural ethylenediammonium diphosphates (NH₃(CH₂)₂NH₃)₂[Me(HP₂O₇)₂ . 2 H₂O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy
AU :	CAPITELLI (Francesco); EL BALI (Brahim); ESSEHLI (Rachid); LACHKAR (Mohammed); VALENTINI (Veronica); MATTEI (Giorgio); TARABA (Jan); ZAK (Zdirak)
AF :	Istituto di Cristallografia (IC-CNR), sezione di Bari, Via Amendola 122/o/70126 Bari/Italie (1 aut.); Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas/30000 Fès/Maroc (2 aut., 3 aut., 4 aut.); Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10/00016 Monterotondo Stazione (Roma)/Italie (5 aut., 6 aut.); Department of Inorganic Chemistry, Masaryk University, Kotlárska 2/61137 Brno/Tchèque, République (7 aut., 8 aut.)
DT :	Publication en série; Niveau analytique
SO :	Zeitschrift für Kristallographie; ISSN 0044-2968; Coden ZEKRDZ; Allemagne; Da. 2006; Vol. 221; No. 9; Pp. 649-655; Bibl. 30 ref.
LA :	Anglais
EA :	New ethylenediammonium diphosphates (NH₃(CH₂)₂NH₃)₂[Me(HP₂O₇)₂ . 2 H₂O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å³ (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å³ (2). The three-dimensional network is built up by discrete Me(HP₂O₇)₂ . 2 H₂O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.
CC :	001B60A66F7
FD :	Etude expérimentale; Mode vibration; Liaison hydrogène; Spectre Raman; Spectre IR; Spectre transformée Fourier; Diffraction RX; Structure cristalline; Ethylène; Ammonium phosphate; Cristal centrosymétrique; Matériau hybride; Réseau triclinique; Cobalt phosphate; Nickel phosphate; 6166F
FG :	Composé minéral; Métal transition composé; Composé organique
ED :	Experimental study; Vibrational modes; Hydrogen bonds; Raman spectra; Infrared spectra; Fourier transform spectra; XRD; Crystal structure; Ethylene; Ammonium phosphates; Centrosymmetrical crystals; Hybrid material; Triclinic lattices; Cobalt phosphates; Nickel phosphates
EG :	Inorganic compounds; Transition element compounds; Organic compounds
SD :	Cristal centrosimétrico; Material híbrido
LO :	INIST-915.354000156913560050
ID :	06-0526554

Links to Exploration step

Pascal:06-0526554

Le document en format XML

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[Me(HP<sub>2</sub>
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NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy</title>
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<author><name sortKey="Mattei, Giorgio" sort="Mattei, Giorgio" uniqKey="Mattei G" first="Giorgio" last="Mattei">Giorgio Mattei</name>
<affiliation><inist:fA14 i1="03"><s1>Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10</s1>
<s2>00016 Monterotondo Stazione (Roma)</s2>
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<author><name sortKey="Taraba, Jan" sort="Taraba, Jan" uniqKey="Taraba J" first="Jan" last="Taraba">Jan Taraba</name>
<affiliation><inist:fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
<s3>CZE</s3>
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<sZ>8 aut.</sZ>
</inist:fA14>
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<author><name sortKey="Zak, Zdirak" sort="Zak, Zdirak" uniqKey="Zak Z" first="Zdirak" last="Zak">Zdirak Zak</name>
<affiliation><inist:fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Ammonium phosphates</term>
<term>Centrosymmetrical crystals</term>
<term>Cobalt phosphates</term>
<term>Crystal structure</term>
<term>Ethylene</term>
<term>Experimental study</term>
<term>Fourier transform spectra</term>
<term>Hybrid material</term>
<term>Hydrogen bonds</term>
<term>Infrared spectra</term>
<term>Nickel phosphates</term>
<term>Raman spectra</term>
<term>Triclinic lattices</term>
<term>Vibrational modes</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Mode vibration</term>
<term>Liaison hydrogène</term>
<term>Spectre Raman</term>
<term>Spectre IR</term>
<term>Spectre transformée Fourier</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Ethylène</term>
<term>Ammonium phosphate</term>
<term>Cristal centrosymétrique</term>
<term>Matériau hybride</term>
<term>Réseau triclinique</term>
<term>Cobalt phosphate</term>
<term>Nickel phosphate</term>
<term>6166F</term>
</keywords>
</textClass>
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<front><div type="abstract" xml:lang="en">New ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å<sup>3</sup>
 (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å<sup>3</sup>
 (2). The three-dimensional network is built up by discrete Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.</div>
</front>
</TEI>
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<fA03 i2="1"><s0>Z. Kristallogr.</s0>
</fA03>
<fA05><s2>221</s2>
</fA05>
<fA06><s2>9</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>New isostructural ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>CAPITELLI (Francesco)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>EL BALI (Brahim)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>ESSEHLI (Rachid)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>LACHKAR (Mohammed)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>VALENTINI (Veronica)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>MATTEI (Giorgio)</s1>
</fA11>
<fA11 i1="07" i2="1"><s1>TARABA (Jan)</s1>
</fA11>
<fA11 i1="08" i2="1"><s1>ZAK (Zdirak)</s1>
</fA11>
<fA14 i1="01"><s1>Istituto di Cristallografia (IC-CNR), sezione di Bari, Via Amendola 122/o</s1>
<s2>70126 Bari</s2>
<s3>ITA</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
<s2>30000 Fès</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10</s1>
<s2>00016 Monterotondo Stazione (Roma)</s2>
<s3>ITA</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</fA14>
<fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
<s3>CZE</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</fA14>
<fA20><s1>649-655</s1>
</fA20>
<fA21><s1>2006</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>915</s2>
<s5>354000156913560050</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2006 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>30 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>06-0526554</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Zeitschrift für Kristallographie</s0>
</fA64>
<fA66 i1="01"><s0>DEU</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>New ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å<sup>3</sup>
 (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å<sup>3</sup>
 (2). The three-dimensional network is built up by discrete Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F7</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Mode vibration</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Vibrational modes</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Liaison hydrogène</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Hydrogen bonds</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Spectre Raman</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Raman spectra</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Spectre IR</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Infrared spectra</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Spectre transformée Fourier</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Fourier transform spectra</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>XRD</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>14</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>14</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Ethylène</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Ethylene</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Ammonium phosphate</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Ammonium phosphates</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Cristal centrosymétrique</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Centrosymmetrical crystals</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Cristal centrosimétrico</s0>
<s5>17</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Matériau hybride</s0>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Hybrid material</s0>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Material híbrido</s0>
<s5>18</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Réseau triclinique</s0>
<s5>19</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>Triclinic lattices</s0>
<s5>19</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Cobalt phosphate</s0>
<s2>NK</s2>
<s5>20</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Cobalt phosphates</s0>
<s2>NK</s2>
<s5>20</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Nickel phosphate</s0>
<s2>NK</s2>
<s5>21</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG"><s0>Nickel phosphates</s0>
<s2>NK</s2>
<s5>21</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>48</s5>
</fC07>
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<s5>48</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>49</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE"><s0>Composé organique</s0>
<s5>50</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG"><s0>Organic compounds</s0>
<s5>50</s5>
</fC07>
<fN21><s1>346</s1>
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<fN82><s1>PSI</s1>
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<server><NO>PASCAL 06-0526554 INIST</NO>
<ET>New isostructural ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy</ET>
<AU>CAPITELLI (Francesco); EL BALI (Brahim); ESSEHLI (Rachid); LACHKAR (Mohammed); VALENTINI (Veronica); MATTEI (Giorgio); TARABA (Jan); ZAK (Zdirak)</AU>
<AF>Istituto di Cristallografia (IC-CNR), sezione di Bari, Via Amendola 122/o/70126 Bari/Italie (1 aut.); Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas/30000 Fès/Maroc (2 aut., 3 aut., 4 aut.); Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10/00016 Monterotondo Stazione (Roma)/Italie (5 aut., 6 aut.); Department of Inorganic Chemistry, Masaryk University, Kotlárska 2/61137 Brno/Tchèque, République (7 aut., 8 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Zeitschrift für Kristallographie; ISSN 0044-2968; Coden ZEKRDZ; Allemagne; Da. 2006; Vol. 221; No. 9; Pp. 649-655; Bibl. 30 ref.</SO>
<LA>Anglais</LA>
<EA>New ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å<sup>3</sup>
 (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å<sup>3</sup>
 (2). The three-dimensional network is built up by discrete Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.</EA>
<CC>001B60A66F7</CC>
<FD>Etude expérimentale; Mode vibration; Liaison hydrogène; Spectre Raman; Spectre IR; Spectre transformée Fourier; Diffraction RX; Structure cristalline; Ethylène; Ammonium phosphate; Cristal centrosymétrique; Matériau hybride; Réseau triclinique; Cobalt phosphate; Nickel phosphate; 6166F</FD>
<FG>Composé minéral; Métal transition composé; Composé organique</FG>
<ED>Experimental study; Vibrational modes; Hydrogen bonds; Raman spectra; Infrared spectra; Fourier transform spectra; XRD; Crystal structure; Ethylene; Ammonium phosphates; Centrosymmetrical crystals; Hybrid material; Triclinic lattices; Cobalt phosphates; Nickel phosphates</ED>
<EG>Inorganic compounds; Transition element compounds; Organic compounds</EG>
<SD>Cristal centrosimétrico; Material híbrido</SD>
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New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

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