Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na8-2xM4+x2+(P2O7)4 formulation (M = Mg, Mn, Co, Ni)
Identifieur interne : 000319 ( PascalFrancis/Checkpoint ); précédent : 000318; suivant : 000320Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na8-2xM4+x2+(P2O7)4 formulation (M = Mg, Mn, Co, Ni)
Auteurs : N. Dridi [Maroc] ; A. Boukhari [Maroc] ; J. M. Reau [France]Source :
- Solid state ionics [ 0167-2738 ] ; 1998.
Descripteurs français
- Pascal (Inist)
- Etude expérimentale, Cristal, Verre, Conductivité électrique, Conductivité ionique, Sodium phosphate, Magnésium phosphate, Manganèse phosphate, Cobalt phosphate, Nickel phosphate, Mg Na O P, Mn Na O P, Co Na O P, Na Ni O P, 6630H, 7260, Na8-2xMg4+x(P2O7)4, Na8-2xMn4+x(P2O7)4, Na8-2xCo4+x(P2O7)4, Na8-2xNi4+x(P2O7)4.
- Wicri :
- topic : Verre.
English descriptors
- KwdEn :
Abstract
Double phosphates of Na8-2xM2+4+-x(P2O7)4 formulation (M = Mg, Mn, Co, Ni) have been isolated either in the crystalline state or in the glassy form and, for a given M2+ cation, glasses are of the same composition as the crystalline phase. Na+ ion conductivity in the glasses is discussed as a function of sodium content and optical basicity. The various electrical parameters determined for the glasses, where M = Mn, Co and Ni, are compared with those of the corresponding crystalline phases.
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Av. Ibn Batouta, B.P. 1014</s1><s2>Rabat</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Maroc</country><placeName><settlement type="city">Rabat</settlement><region nuts="2">Rabat-Salé-Kénitra</region></placeName></affiliation></author><author><name sortKey="Reau, J M" sort="Reau, J M" uniqKey="Reau J" first="J. M." last="Reau">J. M. Reau</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institut de Chimie de la Matière Condensée de Bordeaux, 162 Av. Dr. A. Schweitzer</s1><s2>33608 Pessac</s2><s3>FRA</s3><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">Pessac</settlement></placeName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">98-0332037</idno><date when="1998">1998</date><idno type="stanalyst">PASCAL 98-0332037 INIST</idno><idno type="RBID">Pascal:98-0332037</idno><idno type="wicri:Area/PascalFrancis/Corpus">000320</idno><idno type="wicri:Area/PascalFrancis/Curation">000383</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000319</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000319</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na<sub>8-2x</sub>M<sub>4+x2+(P2</sub>O<sub>7</sub>)<sub>4</sub> formulation (M = Mg, Mn, Co, Ni)</title><author><name sortKey="Dridi, N" sort="Dridi, N" uniqKey="Dridi N" first="N." last="Dridi">N. Dridi</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014</s1><s2>Rabat</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Maroc</country><placeName><settlement type="city">Rabat</settlement><region nuts="2">Rabat-Salé-Kénitra</region></placeName></affiliation></author><author><name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014</s1><s2>Rabat</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Maroc</country><placeName><settlement type="city">Rabat</settlement><region nuts="2">Rabat-Salé-Kénitra</region></placeName></affiliation></author><author><name sortKey="Reau, J M" sort="Reau, J M" uniqKey="Reau J" first="J. M." last="Reau">J. M. Reau</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institut de Chimie de la Matière Condensée de Bordeaux, 162 Av. Dr. A. Schweitzer</s1><s2>33608 Pessac</s2><s3>FRA</s3><sZ>3 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Nouvelle-Aquitaine</region><region type="old region" nuts="2">Aquitaine</region><settlement type="city">Pessac</settlement></placeName></affiliation></author></analytic><series><title level="j" type="main">Solid state ionics</title><title level="j" type="abbreviated">Solid state ion.</title><idno type="ISSN">0167-2738</idno><imprint><date when="1998">1998</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Solid state ionics</title><title level="j" type="abbreviated">Solid state ion.</title><idno type="ISSN">0167-2738</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt phosphates</term><term>Crystals</term><term>Electrical conductivity</term><term>Experimental study</term><term>Glass</term><term>Ionic conductivity</term><term>Magnesium phosphates</term><term>Manganese phosphates</term><term>Nickel phosphates</term><term>Sodium phosphates</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Cristal</term><term>Verre</term><term>Conductivité électrique</term><term>Conductivité ionique</term><term>Sodium phosphate</term><term>Magnésium phosphate</term><term>Manganèse phosphate</term><term>Cobalt phosphate</term><term>Nickel phosphate</term><term>Mg Na O P</term><term>Mn Na O P</term><term>Co Na O P</term><term>Na Ni O P</term><term>6630H</term><term>7260</term><term>Na8-2xMg4+x(P2O7)4</term><term>Na8-2xMn4+x(P2O7)4</term><term>Na8-2xCo4+x(P2O7)4</term><term>Na8-2xNi4+x(P2O7)4</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Verre</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Double phosphates of Na<sub>8-2x</sub>M<sup>2+</sup><sub>4+-x</sub>(P<sub>2</sub>O<sub>7</sub>)<sub>4</sub> formulation (M = Mg, Mn, Co, Ni) have been isolated either in the crystalline state or in the glassy form and, for a given M<sup>2+</sup> cation, glasses are of the same composition as the crystalline phase. Na<sup>+</sup> ion conductivity in the glasses is discussed as a function of sodium content and optical basicity. The various electrical parameters determined for the glasses, where M = Mn, Co and Ni, are compared with those of the corresponding crystalline phases.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0167-2738</s0></fA01><fA02 i1="01"><s0>SSIOD3</s0></fA02><fA03 i2="1"><s0>Solid state ion.</s0></fA03><fA05><s2>110</s2></fA05><fA06><s2>1-2</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na<sub>8-2x</sub>M<sub>4+x2+(P2</sub>O<sub>7</sub>)<sub>4</sub> formulation (M = Mg, Mn, Co, Ni)</s1></fA08><fA11 i1="01" i2="1"><s1>DRIDI (N.)</s1></fA11><fA11 i1="02" i2="1"><s1>BOUKHARI (A.)</s1></fA11><fA11 i1="03" i2="1"><s1>REAU (J. M.)</s1></fA11><fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014</s1><s2>Rabat</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></fA14><fA14 i1="02"><s1>Institut de Chimie de la Matière Condensée de Bordeaux, 162 Av. Dr. A. Schweitzer</s1><s2>33608 Pessac</s2><s3>FRA</s3><sZ>3 aut.</sZ></fA14><fA20><s1>131-136</s1></fA20><fA21><s1>1998</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>18305</s2><s5>354000072249430160</s5></fA43><fA44><s0>0000</s0><s1>© 1998 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>19 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>98-0332037</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i2="1"><s0>Solid state ionics</s0></fA64><fA66 i1="01"><s0>NLD</s0></fA66><fC01 i1="01" l="ENG"><s0>Double phosphates of Na<sub>8-2x</sub>M<sup>2+</sup><sub>4+-x</sub>(P<sub>2</sub>O<sub>7</sub>)<sub>4</sub> formulation (M = Mg, Mn, Co, Ni) have been isolated either in the crystalline state or in the glassy form and, for a given M<sup>2+</sup> cation, glasses are of the same composition as the crystalline phase. Na<sup>+</sup> ion conductivity in the glasses is discussed as a function of sodium content and optical basicity. The various electrical parameters determined for the glasses, where M = Mn, Co and Ni, are compared with those of the corresponding crystalline phases.</s0></fC01><fC02 i1="01" i2="3"><s0>001B60F30H</s0></fC02><fC02 i1="02" i2="3"><s0>001B70B60</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0><s5>01</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0><s5>01</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>Cristal</s0><s5>02</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>Crystals</s0><s5>02</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Verre</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Glass</s0><s5>03</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Conductivité électrique</s0><s5>04</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Electrical conductivity</s0><s5>04</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Conductivité ionique</s0><s5>05</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Ionic conductivity</s0><s5>05</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>Sodium phosphate</s0><s2>NK</s2><s5>06</s5></fC03><fC03 i1="06" i2="3" l="ENG"><s0>Sodium phosphates</s0><s2>NK</s2><s5>06</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>Magnésium phosphate</s0><s2>NK</s2><s5>07</s5></fC03><fC03 i1="07" i2="3" l="ENG"><s0>Magnesium phosphates</s0><s2>NK</s2><s5>07</s5></fC03><fC03 i1="08" i2="3" l="FRE"><s0>Manganèse phosphate</s0><s2>NK</s2><s5>08</s5></fC03><fC03 i1="08" i2="3" l="ENG"><s0>Manganese phosphates</s0><s2>NK</s2><s5>08</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Cobalt phosphate</s0><s2>NK</s2><s5>09</s5></fC03><fC03 i1="09" i2="3" l="ENG"><s0>Cobalt phosphates</s0><s2>NK</s2><s5>09</s5></fC03><fC03 i1="10" i2="3" l="FRE"><s0>Nickel phosphate</s0><s2>NK</s2><s5>10</s5></fC03><fC03 i1="10" i2="3" l="ENG"><s0>Nickel phosphates</s0><s2>NK</s2><s5>10</s5></fC03><fC03 i1="11" i2="3" l="FRE"><s0>Mg Na O P</s0><s4>INC</s4><s5>52</s5></fC03><fC03 i1="12" i2="3" l="FRE"><s0>Mn Na O P</s0><s4>INC</s4><s5>53</s5></fC03><fC03 i1="13" i2="3" l="FRE"><s0>Co Na O P</s0><s4>INC</s4><s5>54</s5></fC03><fC03 i1="14" i2="3" l="FRE"><s0>Na Ni O P</s0><s4>INC</s4><s5>55</s5></fC03><fC03 i1="15" i2="3" l="FRE"><s0>6630H</s0><s2>PAC</s2><s4>INC</s4><s5>56</s5></fC03><fC03 i1="16" i2="3" l="FRE"><s0>7260</s0><s2>PAC</s2><s4>INC</s4><s5>57</s5></fC03><fC03 i1="17" i2="3" l="FRE"><s0>Na8-2xMg4+x(P2O7)4</s0><s4>INC</s4><s5>92</s5></fC03><fC03 i1="18" i2="3" l="FRE"><s0>Na8-2xMn4+x(P2O7)4</s0><s4>INC</s4><s5>93</s5></fC03><fC03 i1="19" i2="3" l="FRE"><s0>Na8-2xCo4+x(P2O7)4</s0><s4>INC</s4><s5>94</s5></fC03><fC03 i1="20" i2="3" l="FRE"><s0>Na8-2xNi4+x(P2O7)4</s0><s4>INC</s4><s5>95</s5></fC03><fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0><s5>16</s5></fC07><fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0><s5>16</s5></fC07><fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0><s5>17</s5></fC07><fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0><s5>17</s5></fC07><fN21><s1>222</s1></fN21></pA></standard></inist><affiliations><list><country><li>France</li><li>Maroc</li></country><region><li>Aquitaine</li><li>Nouvelle-Aquitaine</li><li>Rabat-Salé-Kénitra</li></region><settlement><li>Pessac</li><li>Rabat</li></settlement></list><tree><country name="Maroc"><region name="Rabat-Salé-Kénitra"><name sortKey="Dridi, N" sort="Dridi, N" uniqKey="Dridi N" first="N." last="Dridi">N. Dridi</name></region><name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name></country><country name="France"><region name="Nouvelle-Aquitaine"><name sortKey="Reau, J M" sort="Reau, J M" uniqKey="Reau J" first="J. M." last="Reau">J. M. Reau</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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