CobaltMaghrebV1, PascalFrancis, Corpus, bibRecord, 000320

Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na8-2xM4+x2+(P2O7)4 formulation (M = Mg, Mn, Co, Ni)

Identifieur interne : 000320 ( PascalFrancis/Corpus ); précédent : 000319; suivant : 000321

Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na8-2xM4+x2+(P2O7)4 formulation (M = Mg, Mn, Co, Ni)

Auteurs : N. Dridi ; A. Boukhari ; J. M. Reau

Source :

Solid state ionics [ 0167-2738 ] ; 1998.

RBID : Pascal:98-0332037

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Cristal, Verre, Conductivité électrique, Conductivité ionique, Sodium phosphate, Magnésium phosphate, Manganèse phosphate, Cobalt phosphate, Nickel phosphate, Mg Na O P, Mn Na O P, Co Na O P, Na Ni O P, 6630H, 7260, Na8-2xMg4+x(P2O7)4, Na8-2xMn4+x(P2O7)4, Na8-2xCo4+x(P2O7)4, Na8-2xNi4+x(P2O7)4.

English descriptors

KwdEn :
- Cobalt phosphates, Crystals, Electrical conductivity, Experimental study, Glass, Ionic conductivity, Magnesium phosphates, Manganese phosphates, Nickel phosphates, Sodium phosphates.

Abstract

Double phosphates of Na_8-2xM²⁺_4+-x(P₂O₇)₄ formulation (M = Mg, Mn, Co, Ni) have been isolated either in the crystalline state or in the glassy form and, for a given M²⁺ cation, glasses are of the same composition as the crystalline phase. Na⁺ ion conductivity in the glasses is discussed as a function of sodium content and optical basicity. The various electrical parameters determined for the glasses, where M = Mn, Co and Ni, are compared with those of the corresponding crystalline phases.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0167-2738`
A02	`01`			`@0 SSIOD3`
A03		`1`		`@0 Solid state ion.`
A05				`@2 110`
A06				`@2 1-2`
A08	`01`	`1`	`ENG`	`@1 Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na_8-2xM_4+x2+(P2O₇)₄ formulation (M = Mg, Mn, Co, Ni)`
A11	`01`	`1`		`@1 DRIDI (N.)`
A11	`02`	`1`		`@1 BOUKHARI (A.)`
A11	`03`	`1`		`@1 REAU (J. M.)`
A14	`01`			`@1 Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014 @2 Rabat @3 MAR @Z 1 aut. @Z 2 aut.`
A14	`02`			`@1 Institut de Chimie de la Matière Condensée de Bordeaux, 162 Av. Dr. A. Schweitzer @2 33608 Pessac @3 FRA @Z 3 aut.`
A20				`@1 131-136`
A21				`@1 1998`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 18305 @5 354000072249430160`
A44				`@0 0000 @1 © 1998 INIST-CNRS. All rights reserved.`
A45				`@0 19 ref.`
A47	`01`	`1`		`@0 98-0332037`
A60				`@1 P`
A61				`@0 A`
A64		`1`		`@0 Solid state ionics`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 Double phosphates of Na_8-2xM²⁺_4+-x(P₂O₇)₄ formulation (M = Mg, Mn, Co, Ni) have been isolated either in the crystalline state or in the glassy form and, for a given M²⁺ cation, glasses are of the same composition as the crystalline phase. Na⁺ ion conductivity in the glasses is discussed as a function of sodium content and optical basicity. The various electrical parameters determined for the glasses, where M = Mn, Co and Ni, are compared with those of the corresponding crystalline phases.
C02	`01`	`3`		`@0 001B60F30H`
C02	`02`	`3`		`@0 001B70B60`
C03	`01`	`3`	`FRE`	`@0 Etude expérimentale @5 01`
C03	`01`	`3`	`ENG`	`@0 Experimental study @5 01`
C03	`02`	`3`	`FRE`	`@0 Cristal @5 02`
C03	`02`	`3`	`ENG`	`@0 Crystals @5 02`
C03	`03`	`3`	`FRE`	`@0 Verre @5 03`
C03	`03`	`3`	`ENG`	`@0 Glass @5 03`
C03	`04`	`3`	`FRE`	`@0 Conductivité électrique @5 04`
C03	`04`	`3`	`ENG`	`@0 Electrical conductivity @5 04`
C03	`05`	`3`	`FRE`	`@0 Conductivité ionique @5 05`
C03	`05`	`3`	`ENG`	`@0 Ionic conductivity @5 05`
C03	`06`	`3`	`FRE`	`@0 Sodium phosphate @2 NK @5 06`
C03	`06`	`3`	`ENG`	`@0 Sodium phosphates @2 NK @5 06`
C03	`07`	`3`	`FRE`	`@0 Magnésium phosphate @2 NK @5 07`
C03	`07`	`3`	`ENG`	`@0 Magnesium phosphates @2 NK @5 07`
C03	`08`	`3`	`FRE`	`@0 Manganèse phosphate @2 NK @5 08`
C03	`08`	`3`	`ENG`	`@0 Manganese phosphates @2 NK @5 08`
C03	`09`	`3`	`FRE`	`@0 Cobalt phosphate @2 NK @5 09`
C03	`09`	`3`	`ENG`	`@0 Cobalt phosphates @2 NK @5 09`
C03	`10`	`3`	`FRE`	`@0 Nickel phosphate @2 NK @5 10`
C03	`10`	`3`	`ENG`	`@0 Nickel phosphates @2 NK @5 10`
C03	`11`	`3`	`FRE`	`@0 Mg Na O P @4 INC @5 52`
C03	`12`	`3`	`FRE`	`@0 Mn Na O P @4 INC @5 53`
C03	`13`	`3`	`FRE`	`@0 Co Na O P @4 INC @5 54`
C03	`14`	`3`	`FRE`	`@0 Na Ni O P @4 INC @5 55`
C03	`15`	`3`	`FRE`	`@0 6630H @2 PAC @4 INC @5 56`
C03	`16`	`3`	`FRE`	`@0 7260 @2 PAC @4 INC @5 57`
C03	`17`	`3`	`FRE`	`@0 Na8-2xMg4+x(P2O7)4 @4 INC @5 92`
C03	`18`	`3`	`FRE`	`@0 Na8-2xMn4+x(P2O7)4 @4 INC @5 93`
C03	`19`	`3`	`FRE`	`@0 Na8-2xCo4+x(P2O7)4 @4 INC @5 94`
C03	`20`	`3`	`FRE`	`@0 Na8-2xNi4+x(P2O7)4 @4 INC @5 95`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 16`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 16`
C07	`02`	`3`	`FRE`	`@0 Métal transition composé @5 17`
C07	`02`	`3`	`ENG`	`@0 Transition element compounds @5 17`
N21				`@1 222`

Format Inist (serveur)

NO :	PASCAL 98-0332037 INIST
ET :	Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na_8-2xM_4+x2+(P2O₇)₄ formulation (M = Mg, Mn, Co, Ni)
AU :	DRIDI (N.); BOUKHARI (A.); REAU (J. M.)
AF :	Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014/Rabat/Maroc (1 aut., 2 aut.); Institut de Chimie de la Matière Condensée de Bordeaux, 162 Av. Dr. A. Schweitzer/33608 Pessac/France (3 aut.)
DT :	Publication en série; Niveau analytique
SO :	Solid state ionics; ISSN 0167-2738; Coden SSIOD3; Pays-Bas; Da. 1998; Vol. 110; No. 1-2; Pp. 131-136; Bibl. 19 ref.
LA :	Anglais
EA :	Double phosphates of Na_8-2xM²⁺_4+-x(P₂O₇)₄ formulation (M = Mg, Mn, Co, Ni) have been isolated either in the crystalline state or in the glassy form and, for a given M²⁺ cation, glasses are of the same composition as the crystalline phase. Na⁺ ion conductivity in the glasses is discussed as a function of sodium content and optical basicity. The various electrical parameters determined for the glasses, where M = Mn, Co and Ni, are compared with those of the corresponding crystalline phases.
CC :	001B60F30H; 001B70B60
FD :	Etude expérimentale; Cristal; Verre; Conductivité électrique; Conductivité ionique; Sodium phosphate; Magnésium phosphate; Manganèse phosphate; Cobalt phosphate; Nickel phosphate; Mg Na O P; Mn Na O P; Co Na O P; Na Ni O P; 6630H; 7260; Na8-2xMg4+x(P2O7)4; Na8-2xMn4+x(P2O7)4; Na8-2xCo4+x(P2O7)4; Na8-2xNi4+x(P2O7)4
FG :	Composé minéral; Métal transition composé
ED :	Experimental study; Crystals; Glass; Electrical conductivity; Ionic conductivity; Sodium phosphates; Magnesium phosphates; Manganese phosphates; Cobalt phosphates; Nickel phosphates
EG :	Inorganic compounds; Transition element compounds
LO :	INIST-18305.354000072249430160
ID :	98-0332037

Links to Exploration step

Pascal:98-0332037

Le document en format XML

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M<sub>4+x2+(P2</sub>
O<sub>7</sub>
)<sub>4</sub>
 formulation (M = Mg, Mn, Co, Ni)</title>
<author><name sortKey="Dridi, N" sort="Dridi, N" uniqKey="Dridi N" first="N." last="Dridi">N. Dridi</name>
<affiliation><inist:fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
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<author><name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
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<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
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<author><name sortKey="Reau, J M" sort="Reau, J M" uniqKey="Reau J" first="J. M." last="Reau">J. M. Reau</name>
<affiliation><inist:fA14 i1="02"><s1>Institut de Chimie de la Matière Condensée de Bordeaux, 162 Av. Dr. A. Schweitzer</s1>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na<sub>8-2x</sub>
M<sub>4+x2+(P2</sub>
O<sub>7</sub>
)<sub>4</sub>
 formulation (M = Mg, Mn, Co, Ni)</title>
<author><name sortKey="Dridi, N" sort="Dridi, N" uniqKey="Dridi N" first="N." last="Dridi">N. Dridi</name>
<affiliation><inist:fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
<affiliation><inist:fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Reau, J M" sort="Reau, J M" uniqKey="Reau J" first="J. M." last="Reau">J. M. Reau</name>
<affiliation><inist:fA14 i1="02"><s1>Institut de Chimie de la Matière Condensée de Bordeaux, 162 Av. Dr. A. Schweitzer</s1>
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<sZ>3 aut.</sZ>
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</affiliation>
</author>
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<series><title level="j" type="main">Solid state ionics</title>
<title level="j" type="abbreviated">Solid state ion.</title>
<idno type="ISSN">0167-2738</idno>
<imprint><date when="1998">1998</date>
</imprint>
</series>
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<seriesStmt><title level="j" type="main">Solid state ionics</title>
<title level="j" type="abbreviated">Solid state ion.</title>
<idno type="ISSN">0167-2738</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt phosphates</term>
<term>Crystals</term>
<term>Electrical conductivity</term>
<term>Experimental study</term>
<term>Glass</term>
<term>Ionic conductivity</term>
<term>Magnesium phosphates</term>
<term>Manganese phosphates</term>
<term>Nickel phosphates</term>
<term>Sodium phosphates</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Cristal</term>
<term>Verre</term>
<term>Conductivité électrique</term>
<term>Conductivité ionique</term>
<term>Sodium phosphate</term>
<term>Magnésium phosphate</term>
<term>Manganèse phosphate</term>
<term>Cobalt phosphate</term>
<term>Nickel phosphate</term>
<term>Mg Na O P</term>
<term>Mn Na O P</term>
<term>Co Na O P</term>
<term>Na Ni O P</term>
<term>6630H</term>
<term>7260</term>
<term>Na8-2xMg4+x(P2O7)4</term>
<term>Na8-2xMn4+x(P2O7)4</term>
<term>Na8-2xCo4+x(P2O7)4</term>
<term>Na8-2xNi4+x(P2O7)4</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Double phosphates of Na<sub>8-2x</sub>
M<sup>2+</sup>
<sub>4+-x</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>4</sub>
 formulation (M = Mg, Mn, Co, Ni) have been isolated either in the crystalline state or in the glassy form and, for a given M<sup>2+</sup>
 cation, glasses are of the same composition as the crystalline phase. Na<sup>+</sup>
 ion conductivity in the glasses is discussed as a function of sodium content and optical basicity. The various electrical parameters determined for the glasses, where M = Mn, Co and Ni, are compared with those of the corresponding crystalline phases.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0167-2738</s0>
</fA01>
<fA02 i1="01"><s0>SSIOD3</s0>
</fA02>
<fA03 i2="1"><s0>Solid state ion.</s0>
</fA03>
<fA05><s2>110</s2>
</fA05>
<fA06><s2>1-2</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na<sub>8-2x</sub>
M<sub>4+x2+(P2</sub>
O<sub>7</sub>
)<sub>4</sub>
 formulation (M = Mg, Mn, Co, Ni)</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>DRIDI (N.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>BOUKHARI (A.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>REAU (J. M.)</s1>
</fA11>
<fA14 i1="01"><s1>Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Institut de Chimie de la Matière Condensée de Bordeaux, 162 Av. Dr. A. Schweitzer</s1>
<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>3 aut.</sZ>
</fA14>
<fA20><s1>131-136</s1>
</fA20>
<fA21><s1>1998</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>18305</s2>
<s5>354000072249430160</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 1998 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>19 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>98-0332037</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i2="1"><s0>Solid state ionics</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Double phosphates of Na<sub>8-2x</sub>
M<sup>2+</sup>
<sub>4+-x</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>4</sub>
 formulation (M = Mg, Mn, Co, Ni) have been isolated either in the crystalline state or in the glassy form and, for a given M<sup>2+</sup>
 cation, glasses are of the same composition as the crystalline phase. Na<sup>+</sup>
 ion conductivity in the glasses is discussed as a function of sodium content and optical basicity. The various electrical parameters determined for the glasses, where M = Mn, Co and Ni, are compared with those of the corresponding crystalline phases.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60F30H</s0>
</fC02>
<fC02 i1="02" i2="3"><s0>001B70B60</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Cristal</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Crystals</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Verre</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Glass</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Conductivité électrique</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Electrical conductivity</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Conductivité ionique</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Ionic conductivity</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Sodium phosphate</s0>
<s2>NK</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Sodium phosphates</s0>
<s2>NK</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Magnésium phosphate</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Magnesium phosphates</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Manganèse phosphate</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Manganese phosphates</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Cobalt phosphate</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Cobalt phosphates</s0>
<s2>NK</s2>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Nickel phosphate</s0>
<s2>NK</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Nickel phosphates</s0>
<s2>NK</s2>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Mg Na O P</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>Mn Na O P</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Co Na O P</s0>
<s4>INC</s4>
<s5>54</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Na Ni O P</s0>
<s4>INC</s4>
<s5>55</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>6630H</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>7260</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE"><s0>Na8-2xMg4+x(P2O7)4</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE"><s0>Na8-2xMn4+x(P2O7)4</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>Na8-2xCo4+x(P2O7)4</s0>
<s4>INC</s4>
<s5>94</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE"><s0>Na8-2xNi4+x(P2O7)4</s0>
<s4>INC</s4>
<s5>95</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>17</s5>
</fC07>
<fN21><s1>222</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 98-0332037 INIST</NO>
<ET>Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na<sub>8-2x</sub>
M<sub>4+x2+(P2</sub>
O<sub>7</sub>
)<sub>4</sub>
 formulation (M = Mg, Mn, Co, Ni)</ET>
<AU>DRIDI (N.); BOUKHARI (A.); REAU (J. M.)</AU>
<AF>Laboratoire de Chimie du Solide Appliqué, Université Mohammed V. Av. Ibn Batouta, B.P. 1014/Rabat/Maroc (1 aut., 2 aut.); Institut de Chimie de la Matière Condensée de Bordeaux, 162 Av. Dr. A. Schweitzer/33608 Pessac/France (3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Solid state ionics; ISSN 0167-2738; Coden SSIOD3; Pays-Bas; Da. 1998; Vol. 110; No. 1-2; Pp. 131-136; Bibl. 19 ref.</SO>
<LA>Anglais</LA>
<EA>Double phosphates of Na<sub>8-2x</sub>
M<sup>2+</sup>
<sub>4+-x</sub>
(P<sub>2</sub>
O<sub>7</sub>
)<sub>4</sub>
 formulation (M = Mg, Mn, Co, Ni) have been isolated either in the crystalline state or in the glassy form and, for a given M<sup>2+</sup>
 cation, glasses are of the same composition as the crystalline phase. Na<sup>+</sup>
 ion conductivity in the glasses is discussed as a function of sodium content and optical basicity. The various electrical parameters determined for the glasses, where M = Mn, Co and Ni, are compared with those of the corresponding crystalline phases.</EA>
<CC>001B60F30H; 001B70B60</CC>
<FD>Etude expérimentale; Cristal; Verre; Conductivité électrique; Conductivité ionique; Sodium phosphate; Magnésium phosphate; Manganèse phosphate; Cobalt phosphate; Nickel phosphate; Mg Na O P; Mn Na O P; Co Na O P; Na Ni O P; 6630H; 7260; Na8-2xMg4+x(P2O7)4; Na8-2xMn4+x(P2O7)4; Na8-2xCo4+x(P2O7)4; Na8-2xNi4+x(P2O7)4</FD>
<FG>Composé minéral; Métal transition composé</FG>
<ED>Experimental study; Crystals; Glass; Electrical conductivity; Ionic conductivity; Sodium phosphates; Magnesium phosphates; Manganese phosphates; Cobalt phosphates; Nickel phosphates</ED>
<EG>Inorganic compounds; Transition element compounds</EG>
<LO>INIST-18305.354000072249430160</LO>
<ID>98-0332037</ID>
</server>
</inist>
</record>

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Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na8-2xM4+x2+(P2O7)4 formulation (M = Mg, Mn, Co, Ni)

Influence of the crystalline or glassy state on the electrical properties of double phosphates of Na8-2xM4+x2+(P2O7)4 formulation (M = Mg, Mn, Co, Ni)

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