CobaltMaghrebV1, PascalFrancis, Checkpoint, bibRecord, 000226

KHCoP2O7.2H2O: a novel acidic pyrophosphate

Identifieur interne : 000226 ( PascalFrancis/Checkpoint ); précédent : 000225; suivant : 000227

KHCoP2O7.2H2O: a novel acidic pyrophosphate

Auteurs : Mohamed Harcharras [Maroc] ; Kees Goubitz [Pays-Bas] ; Abdelaziz Ennaciri [Maroc] ; Hassane Assaaoudi [Maroc] ; Henk Schenk [Pays-Bas]

Source :

Acta crystallographica. Section C, Crystal structure communications [ 0108-2701 ] ; 2003.

RBID : Pascal:03-0311020

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Diffraction RX, Structure cristalline, Potassium Diphosphate, Hydrogène Diphosphate, Cobalt Diphosphate, Hydrate, 6166F, KHCoP2O7, Co H K O P.

English descriptors

KwdEn :
- Cobalt Pyrophosphates, Crystal structure, Experimental study, Hydrates, Hydrogen Pyrophosphates, Potassium Pyrophosphates, XRD.

Abstract

Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P₂O₇.2H₂O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP₂O₇.2H₂O (M = Mn and Zn). The structure consists of alternating layers, built from HP₂O₇3- acidic pyrophosphate groups and CoO₆ octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO₄ groups, with the bridging O atom on a mirror plane.

Affiliations:

Maroc, Pays-Bas

Links toward previous steps (curation, corpus...)

to stream PascalFrancis, to step Corpus: 000231
to stream PascalFrancis, to step Curation: 000064

Links to Exploration step

Pascal:03-0311020

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">KHCoP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O: a novel acidic pyrophosphate</title>
<author><name sortKey="Harcharras, Mohamed" sort="Harcharras, Mohamed" uniqKey="Harcharras M" first="Mohamed" last="Harcharras">Mohamed Harcharras</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Goubitz, Kees" sort="Goubitz, Kees" uniqKey="Goubitz K" first="Kees" last="Goubitz">Kees Goubitz</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>1018 WV Amsterdam</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Ennaciri, Abdelaziz" sort="Ennaciri, Abdelaziz" uniqKey="Ennaciri A" first="Abdelaziz" last="Ennaciri">Abdelaziz Ennaciri</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Assaaoudi, Hassane" sort="Assaaoudi, Hassane" uniqKey="Assaaoudi H" first="Hassane" last="Assaaoudi">Hassane Assaaoudi</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Schenk, Henk" sort="Schenk, Henk" uniqKey="Schenk H" first="Henk" last="Schenk">Henk Schenk</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>1018 WV Amsterdam</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">03-0311020</idno>
<date when="2003">2003</date>
<idno type="stanalyst">PASCAL 03-0311020 INIST</idno>
<idno type="RBID">Pascal:03-0311020</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000231</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000064</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">000226</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000226</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">KHCoP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O: a novel acidic pyrophosphate</title>
<author><name sortKey="Harcharras, Mohamed" sort="Harcharras, Mohamed" uniqKey="Harcharras M" first="Mohamed" last="Harcharras">Mohamed Harcharras</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Goubitz, Kees" sort="Goubitz, Kees" uniqKey="Goubitz K" first="Kees" last="Goubitz">Kees Goubitz</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>1018 WV Amsterdam</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Ennaciri, Abdelaziz" sort="Ennaciri, Abdelaziz" uniqKey="Ennaciri A" first="Abdelaziz" last="Ennaciri">Abdelaziz Ennaciri</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Assaaoudi, Hassane" sort="Assaaoudi, Hassane" uniqKey="Assaaoudi H" first="Hassane" last="Assaaoudi">Hassane Assaaoudi</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>14000 Kenitra</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Schenk, Henk" sort="Schenk, Henk" uniqKey="Schenk H" first="Henk" last="Schenk">Henk Schenk</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Pays-Bas</country>
<wicri:noRegion>1018 WV Amsterdam</wicri:noRegion>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
<imprint><date when="2003">2003</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt Pyrophosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Hydrates</term>
<term>Hydrogen Pyrophosphates</term>
<term>Potassium Pyrophosphates</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Potassium Diphosphate</term>
<term>Hydrogène Diphosphate</term>
<term>Cobalt Diphosphate</term>
<term>Hydrate</term>
<term>6166F</term>
<term>KHCoP2O7</term>
<term>Co H K O P</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O (M = Mn and Zn). The structure consists of alternating layers, built from HP<sub>2</sub>
O<sub>7</sub>
3- acidic pyrophosphate groups and CoO<sub>6</sub>
 octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO<sub>4</sub>
 groups, with the bridging O atom on a mirror plane.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0108-2701</s0>
</fA01>
<fA02 i1="01"><s0>ACSCEE</s0>
</fA02>
<fA03 i2="1"><s0>Acta crystallogr., Sect. C Cryst. struct. commun.</s0>
</fA03>
<fA05><s2>59</s2>
</fA05>
<fA06><s3>p.6</s3>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>KHCoP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O: a novel acidic pyrophosphate</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>HARCHARRAS (Mohamed)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>GOUBITZ (Kees)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>ENNACIRI (Abdelaziz)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>ASSAAOUDI (Hassane)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>SCHENK (Henk)</s1>
</fA11>
<fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA20><s2>i57-i58</s2>
</fA20>
<fA21><s1>2003</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>5160C</s2>
<s5>354000111280070070</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2003 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>25 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>03-0311020</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Acta crystallographica. Section C, Crystal structure communications</s0>
</fA64>
<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O (M = Mn and Zn). The structure consists of alternating layers, built from HP<sub>2</sub>
O<sub>7</sub>
3- acidic pyrophosphate groups and CoO<sub>6</sub>
 octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO<sub>4</sub>
 groups, with the bridging O atom on a mirror plane.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F4</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Potassium Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Potassium Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Hydrogène Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>08</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Hydrogen Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Cobalt Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Cobalt Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Hydrate</s0>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Hydrates</s0>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>KHCoP2O7</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Co H K O P</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>04</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>04</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Phosphate</s0>
<s2>NA</s2>
<s5>05</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Phosphates</s0>
<s2>NA</s2>
<s5>05</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE"><s0>Diphosphate</s0>
<s2>NA</s2>
<s5>06</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG"><s0>Pyrophosphates</s0>
<s2>NA</s2>
<s5>06</s5>
</fC07>
<fC07 i1="04" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>11</s5>
</fC07>
<fC07 i1="04" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>11</s5>
</fC07>
<fN21><s1>209</s1>
</fN21>
<fN82><s1>PSI</s1>
</fN82>
</pA>
</standard>
</inist>
<affiliations><list><country><li>Maroc</li>
<li>Pays-Bas</li>
</country>
</list>
<tree><country name="Maroc"><noRegion><name sortKey="Harcharras, Mohamed" sort="Harcharras, Mohamed" uniqKey="Harcharras M" first="Mohamed" last="Harcharras">Mohamed Harcharras</name>
</noRegion>
<name sortKey="Assaaoudi, Hassane" sort="Assaaoudi, Hassane" uniqKey="Assaaoudi H" first="Hassane" last="Assaaoudi">Hassane Assaaoudi</name>
<name sortKey="Ennaciri, Abdelaziz" sort="Ennaciri, Abdelaziz" uniqKey="Ennaciri A" first="Abdelaziz" last="Ennaciri">Abdelaziz Ennaciri</name>
</country>
<country name="Pays-Bas"><noRegion><name sortKey="Goubitz, Kees" sort="Goubitz, Kees" uniqKey="Goubitz K" first="Kees" last="Goubitz">Kees Goubitz</name>
</noRegion>
<name sortKey="Schenk, Henk" sort="Schenk, Henk" uniqKey="Schenk H" first="Henk" last="Schenk">Henk Schenk</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/PascalFrancis/Checkpoint

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000226 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/PascalFrancis/Checkpoint/biblio.hfd -nk 000226 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    CobaltMaghrebV1
   |flux=    PascalFrancis
   |étape=   Checkpoint
   |type=    RBID
   |clé=     Pascal:03-0311020
   |texte=   KHCoP2O7.2H2O: a novel acidic pyrophosphate
}}

This area was generated with Dilib version V0.6.32.
Data generation: Tue Nov 14 12:56:51 2017. Site generation: Mon Feb 12 07:59:49 2024

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

KHCoP2O7.2H2O: a novel acidic pyrophosphate

KHCoP2O7.2H2O: a novel acidic pyrophosphate

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri