CobaltMaghrebV1, PascalFrancis, Corpus, bibRecord, 000231

KHCoP2O7.2H2O: a novel acidic pyrophosphate

Identifieur interne : 000231 ( PascalFrancis/Corpus ); précédent : 000230; suivant : 000232

KHCoP2O7.2H2O: a novel acidic pyrophosphate

Auteurs : Mohamed Harcharras ; Kees Goubitz ; Abdelaziz Ennaciri ; Hassane Assaaoudi ; Henk Schenk

Source :

Acta crystallographica. Section C, Crystal structure communications [ 0108-2701 ] ; 2003.

RBID : Pascal:03-0311020

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Diffraction RX, Structure cristalline, Potassium Diphosphate, Hydrogène Diphosphate, Cobalt Diphosphate, Hydrate, 6166F, KHCoP2O7, Co H K O P.

English descriptors

KwdEn :
- Cobalt Pyrophosphates, Crystal structure, Experimental study, Hydrates, Hydrogen Pyrophosphates, Potassium Pyrophosphates, XRD.

Abstract

Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P₂O₇.2H₂O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP₂O₇.2H₂O (M = Mn and Zn). The structure consists of alternating layers, built from HP₂O₇3- acidic pyrophosphate groups and CoO₆ octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO₄ groups, with the bridging O atom on a mirror plane.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0108-2701`
A02	`01`			`@0 ACSCEE`
A03		`1`		`@0 Acta crystallogr., Sect. C Cryst. struct. commun.`
A05				`@2 59`
A06				`@3 p.6`
A08	`01`	`1`	`ENG`	`@1 KHCoP₂O₇.2H₂O: a novel acidic pyrophosphate`
A11	`01`	`1`		`@1 HARCHARRAS (Mohamed)`
A11	`02`	`1`		`@1 GOUBITZ (Kees)`
A11	`03`	`1`		`@1 ENNACIRI (Abdelaziz)`
A11	`04`	`1`		`@1 ASSAAOUDI (Hassane)`
A11	`05`	`1`		`@1 SCHENK (Henk)`
A14	`01`			`@1 Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133 @2 14000 Kenitra @3 MAR @Z 1 aut. @Z 3 aut. @Z 4 aut.`
A14	`02`			`@1 Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166 @2 1018 WV Amsterdam @3 NLD @Z 2 aut. @Z 5 aut.`
A20				`@2 i57-i58`
A21				`@1 2003`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 5160C @5 354000111280070070`
A44				`@0 0000 @1 © 2003 INIST-CNRS. All rights reserved.`
A45				`@0 25 ref.`
A47	`01`	`1`		`@0 03-0311020`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Acta crystallographica. Section C, Crystal structure communications`
A66	`01`			`@0 GBR`
C01	`01`		`ENG`	@0 Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P₂O₇.2H₂O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP₂O₇.2H₂O (M = Mn and Zn). The structure consists of alternating layers, built from HP₂O₇3- acidic pyrophosphate groups and CoO₆ octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO₄ groups, with the bridging O atom on a mirror plane.
C02	`01`	`3`		`@0 001B60A66F4`
C03	`01`	`3`	`FRE`	`@0 Etude expérimentale @5 01`
C03	`01`	`3`	`ENG`	`@0 Experimental study @5 01`
C03	`02`	`3`	`FRE`	`@0 Diffraction RX @5 02`
C03	`02`	`3`	`ENG`	`@0 XRD @5 02`
C03	`03`	`3`	`FRE`	`@0 Structure cristalline @5 03`
C03	`03`	`3`	`ENG`	`@0 Crystal structure @5 03`
C03	`04`	`3`	`FRE`	`@0 Potassium Diphosphate @2 NC @2 NA @5 07`
C03	`04`	`3`	`ENG`	`@0 Potassium Pyrophosphates @2 NC @2 NA @5 07`
C03	`05`	`3`	`FRE`	`@0 Hydrogène Diphosphate @2 NC @2 NA @5 08`
C03	`05`	`3`	`ENG`	`@0 Hydrogen Pyrophosphates @2 NC @2 NA @5 08`
C03	`06`	`3`	`FRE`	`@0 Cobalt Diphosphate @2 NC @2 NA @5 09`
C03	`06`	`3`	`ENG`	`@0 Cobalt Pyrophosphates @2 NC @2 NA @5 09`
C03	`07`	`3`	`FRE`	`@0 Hydrate @2 NA @5 10`
C03	`07`	`3`	`ENG`	`@0 Hydrates @2 NA @5 10`
C03	`08`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 56`
C03	`09`	`3`	`FRE`	`@0 KHCoP2O7 @4 INC @5 92`
C03	`10`	`3`	`FRE`	`@0 Co H K O P @4 INC @5 93`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 04`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 04`
C07	`02`	`3`	`FRE`	`@0 Phosphate @2 NA @5 05`
C07	`02`	`3`	`ENG`	`@0 Phosphates @2 NA @5 05`
C07	`03`	`3`	`FRE`	`@0 Diphosphate @2 NA @5 06`
C07	`03`	`3`	`ENG`	`@0 Pyrophosphates @2 NA @5 06`
C07	`04`	`3`	`FRE`	`@0 Métal transition composé @5 11`
C07	`04`	`3`	`ENG`	`@0 Transition element compounds @5 11`
N21				`@1 209`
N82				`@1 PSI`

Format Inist (serveur)

NO :	PASCAL 03-0311020 INIST
ET :	KHCoP₂O₇.2H₂O: a novel acidic pyrophosphate
AU :	HARCHARRAS (Mohamed); GOUBITZ (Kees); ENNACIRI (Abdelaziz); ASSAAOUDI (Hassane); SCHENK (Henk)
AF :	Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133/14000 Kenitra/Maroc (1 aut., 3 aut., 4 aut.); Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166/1018 WV Amsterdam/Pays-Bas (2 aut., 5 aut.)
DT :	Publication en série; Niveau analytique
SO :	Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Royaume-Uni; Da. 2003; Vol. 59; No. p.6; i57-i58; Bibl. 25 ref.
LA :	Anglais
EA :	Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P₂O₇.2H₂O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP₂O₇.2H₂O (M = Mn and Zn). The structure consists of alternating layers, built from HP₂O₇3- acidic pyrophosphate groups and CoO₆ octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO₄ groups, with the bridging O atom on a mirror plane.
CC :	001B60A66F4
FD :	Etude expérimentale; Diffraction RX; Structure cristalline; Potassium Diphosphate; Hydrogène Diphosphate; Cobalt Diphosphate; Hydrate; 6166F; KHCoP2O7; Co H K O P
FG :	Composé minéral; Phosphate; Diphosphate; Métal transition composé
ED :	Experimental study; XRD; Crystal structure; Potassium Pyrophosphates; Hydrogen Pyrophosphates; Cobalt Pyrophosphates; Hydrates
EG :	Inorganic compounds; Phosphates; Pyrophosphates; Transition element compounds
LO :	INIST-5160C.354000111280070070
ID :	03-0311020

Links to Exploration step

Pascal:03-0311020

Le document en format XML

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O<sub>7</sub>
.2H<sub>2</sub>
O: a novel acidic pyrophosphate</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">KHCoP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O: a novel acidic pyrophosphate</title>
<author><name sortKey="Harcharras, Mohamed" sort="Harcharras, Mohamed" uniqKey="Harcharras M" first="Mohamed" last="Harcharras">Mohamed Harcharras</name>
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<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Goubitz, Kees" sort="Goubitz, Kees" uniqKey="Goubitz K" first="Kees" last="Goubitz">Kees Goubitz</name>
<affiliation><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Ennaciri, Abdelaziz" sort="Ennaciri, Abdelaziz" uniqKey="Ennaciri A" first="Abdelaziz" last="Ennaciri">Abdelaziz Ennaciri</name>
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<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Assaaoudi, Hassane" sort="Assaaoudi, Hassane" uniqKey="Assaaoudi H" first="Hassane" last="Assaaoudi">Hassane Assaaoudi</name>
<affiliation><inist:fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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</affiliation>
</author>
<author><name sortKey="Schenk, Henk" sort="Schenk, Henk" uniqKey="Schenk H" first="Henk" last="Schenk">Henk Schenk</name>
<affiliation><inist:fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
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</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
<imprint><date when="2003">2003</date>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt Pyrophosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Hydrates</term>
<term>Hydrogen Pyrophosphates</term>
<term>Potassium Pyrophosphates</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Potassium Diphosphate</term>
<term>Hydrogène Diphosphate</term>
<term>Cobalt Diphosphate</term>
<term>Hydrate</term>
<term>6166F</term>
<term>KHCoP2O7</term>
<term>Co H K O P</term>
</keywords>
</textClass>
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</teiHeader>
<front><div type="abstract" xml:lang="en">Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O (M = Mn and Zn). The structure consists of alternating layers, built from HP<sub>2</sub>
O<sub>7</sub>
3- acidic pyrophosphate groups and CoO<sub>6</sub>
 octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO<sub>4</sub>
 groups, with the bridging O atom on a mirror plane.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0108-2701</s0>
</fA01>
<fA02 i1="01"><s0>ACSCEE</s0>
</fA02>
<fA03 i2="1"><s0>Acta crystallogr., Sect. C Cryst. struct. commun.</s0>
</fA03>
<fA05><s2>59</s2>
</fA05>
<fA06><s3>p.6</s3>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>KHCoP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O: a novel acidic pyrophosphate</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>HARCHARRAS (Mohamed)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>GOUBITZ (Kees)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>ENNACIRI (Abdelaziz)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>ASSAAOUDI (Hassane)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>SCHENK (Henk)</s1>
</fA11>
<fA14 i1="01"><s1>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133</s1>
<s2>14000 Kenitra</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166</s1>
<s2>1018 WV Amsterdam</s2>
<s3>NLD</s3>
<sZ>2 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA20><s2>i57-i58</s2>
</fA20>
<fA21><s1>2003</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>5160C</s2>
<s5>354000111280070070</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2003 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>25 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>03-0311020</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Acta crystallographica. Section C, Crystal structure communications</s0>
</fA64>
<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O (M = Mn and Zn). The structure consists of alternating layers, built from HP<sub>2</sub>
O<sub>7</sub>
3- acidic pyrophosphate groups and CoO<sub>6</sub>
 octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO<sub>4</sub>
 groups, with the bridging O atom on a mirror plane.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F4</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Potassium Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Potassium Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Hydrogène Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>08</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Hydrogen Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Cobalt Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Cobalt Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Hydrate</s0>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Hydrates</s0>
<s2>NA</s2>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>KHCoP2O7</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Co H K O P</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>04</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>04</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Phosphate</s0>
<s2>NA</s2>
<s5>05</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Phosphates</s0>
<s2>NA</s2>
<s5>05</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE"><s0>Diphosphate</s0>
<s2>NA</s2>
<s5>06</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG"><s0>Pyrophosphates</s0>
<s2>NA</s2>
<s5>06</s5>
</fC07>
<fC07 i1="04" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>11</s5>
</fC07>
<fC07 i1="04" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>11</s5>
</fC07>
<fN21><s1>209</s1>
</fN21>
<fN82><s1>PSI</s1>
</fN82>
</pA>
</standard>
<server><NO>PASCAL 03-0311020 INIST</NO>
<ET>KHCoP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O: a novel acidic pyrophosphate</ET>
<AU>HARCHARRAS (Mohamed); GOUBITZ (Kees); ENNACIRI (Abdelaziz); ASSAAOUDI (Hassane); SCHENK (Henk)</AU>
<AF>Laboratory of Spectroscopy, Department of Chemistry, Faculty of Sciences, University the Tofail, BP 133/14000 Kenitra/Maroc (1 aut., 3 aut., 4 aut.); Laboratory for Crystallography, Institute of Molecular Chemistry, Faculty of Sciences, Universiteit van Amsterdam, Nieuwe Achtergracht 166/1018 WV Amsterdam/Pays-Bas (2 aut., 5 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Royaume-Uni; Da. 2003; Vol. 59; No. p.6; i57-i58; Bibl. 25 ref.</SO>
<LA>Anglais</LA>
<EA>Potassium cobalt hydrogenpyrophosphate dihydrate, KHCo-P<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O, crystallizes in the orthorhombic space group Pnma. This salt is isotypic with KHMP<sub>2</sub>
O<sub>7</sub>
.2H<sub>2</sub>
O (M = Mn and Zn). The structure consists of alternating layers, built from HP<sub>2</sub>
O<sub>7</sub>
3- acidic pyrophosphate groups and CoO<sub>6</sub>
 octahedra, joined by potassium ions and bridging hydrogen bonds. The Co, K and water O atoms lie on mirror planes. The pyrophosphate group consists of two symmetry-related PO<sub>4</sub>
 groups, with the bridging O atom on a mirror plane.</EA>
<CC>001B60A66F4</CC>
<FD>Etude expérimentale; Diffraction RX; Structure cristalline; Potassium Diphosphate; Hydrogène Diphosphate; Cobalt Diphosphate; Hydrate; 6166F; KHCoP2O7; Co H K O P</FD>
<FG>Composé minéral; Phosphate; Diphosphate; Métal transition composé</FG>
<ED>Experimental study; XRD; Crystal structure; Potassium Pyrophosphates; Hydrogen Pyrophosphates; Cobalt Pyrophosphates; Hydrates</ED>
<EG>Inorganic compounds; Phosphates; Pyrophosphates; Transition element compounds</EG>
<LO>INIST-5160C.354000111280070070</LO>
<ID>03-0311020</ID>
</server>
</inist>
</record>

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KHCoP2O7.2H2O: a novel acidic pyrophosphate

KHCoP2O7.2H2O: a novel acidic pyrophosphate

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