Magnetic approach in some mixed Cobalt (II) hydroxynitrates compounds
Identifieur interne : 000186 ( PascalFrancis/Checkpoint ); précédent : 000185; suivant : 000187Magnetic approach in some mixed Cobalt (II) hydroxynitrates compounds
Auteurs : N. Izaoumen [Maroc] ; M. Cherrab [Maroc] ; K. Rissouli [Maroc] ; K. Benkhouja [Maroc] ; K. Jaafari [Maroc] ; M. Fahad [Maroc]Source :
- Journal de physique. IV [ 1155-4339 ] ; 2005.
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Abstract
Among layered compounds, the transition metal hydroxynitrates M(OH)2-x(NO3)x.nH2O (with M= Co, Ni,Cu) are still currently investigated, since they are good precursors for the synthesis of simple or mixed metal oxides with interesting catalytic and electronic properties.From a structural point of view, the hydroxynitrates derive from the CdI2 type stucture of M (OH)2. They can be described as 2D triangular arrays of metal ions with large interplanar distances, and accordingly, they are good candidates for studying bidimensional magnetic systems. Knowing that from a magnetic point view, Co(OH)2 and Co2(OH)3(NO3) were shown to be a genuine examples of layered ferromagnetic systems, with the occurrence of 3d antiferromagnetic order at nearly the same temperature ; we report in this paper the preparation and magnetic properties of layered cobat mixed metal(II) hydroxynitrates CoM(OH)3(NO3) (M= Cu, Ba) hydrated or no which display, according to the metal ion, either ferro or antiferromagnetic interlayer interactions. We discuss the interest in these compounds named hybrid organic-inorganic compounds for the stabilizing ferromagnetic interactions.
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Fahad</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LPTN, Département de Physique, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1><s2>24000 Eljadida</s2><s3>MAR</s3><sZ>6 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>24000 Eljadida</wicri:noRegion><orgName type="university">Université Chouaib Doukkali</orgName><placeName><settlement type="city">El Jadida</settlement><region type="region" nuts="2">Casablanca-Settat</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">05-0188394</idno><date when="2005">2005</date><idno type="stanalyst">PASCAL 05-0188394 INIST</idno><idno type="RBID">Pascal:05-0188394</idno><idno type="wicri:Area/PascalFrancis/Corpus">000189</idno><idno type="wicri:Area/PascalFrancis/Curation">000106</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000186</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000186</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Magnetic approach in some mixed Cobalt (II) hydroxynitrates compounds</title><author><name sortKey="Izaoumen, N" sort="Izaoumen, N" uniqKey="Izaoumen N" first="N." last="Izaoumen">N. Izaoumen</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1><s2>24000 Eljadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>24000 Eljadida</wicri:noRegion><orgName type="university">Université Chouaib Doukkali</orgName><placeName><settlement type="city">El Jadida</settlement><region type="region" nuts="2">Casablanca-Settat</region></placeName></affiliation></author><author><name sortKey="Cherrab, M" sort="Cherrab, M" uniqKey="Cherrab M" first="M." last="Cherrab">M. Cherrab</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1><s2>24000 Eljadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>24000 Eljadida</wicri:noRegion><orgName type="university">Université Chouaib Doukkali</orgName><placeName><settlement type="city">El Jadida</settlement><region type="region" nuts="2">Casablanca-Settat</region></placeName></affiliation></author><author><name sortKey="Rissouli, K" sort="Rissouli, K" uniqKey="Rissouli K" first="K." last="Rissouli">K. Rissouli</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1><s2>24000 Eljadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>24000 Eljadida</wicri:noRegion><orgName type="university">Université Chouaib Doukkali</orgName><placeName><settlement type="city">El Jadida</settlement><region type="region" nuts="2">Casablanca-Settat</region></placeName></affiliation></author><author><name sortKey="Benkhouja, K" sort="Benkhouja, K" uniqKey="Benkhouja K" first="K." last="Benkhouja">K. Benkhouja</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1><s2>24000 Eljadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>24000 Eljadida</wicri:noRegion><orgName type="university">Université Chouaib Doukkali</orgName><placeName><settlement type="city">El Jadida</settlement><region type="region" nuts="2">Casablanca-Settat</region></placeName></affiliation></author><author><name sortKey="Jaafari, K" sort="Jaafari, K" uniqKey="Jaafari K" first="K." last="Jaafari">K. Jaafari</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1><s2>24000 Eljadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>24000 Eljadida</wicri:noRegion><orgName type="university">Université Chouaib Doukkali</orgName><placeName><settlement type="city">El Jadida</settlement><region type="region" nuts="2">Casablanca-Settat</region></placeName></affiliation></author><author><name sortKey="Fahad, M" sort="Fahad, M" uniqKey="Fahad M" first="M." last="Fahad">M. Fahad</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LPTN, Département de Physique, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1><s2>24000 Eljadida</s2><s3>MAR</s3><sZ>6 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>24000 Eljadida</wicri:noRegion><orgName type="university">Université Chouaib Doukkali</orgName><placeName><settlement type="city">El Jadida</settlement><region type="region" nuts="2">Casablanca-Settat</region></placeName></affiliation></author></analytic><series><title level="j" type="main">Journal de physique. IV</title><title level="j" type="abbreviated">J. phys., IV</title><idno type="ISSN">1155-4339</idno><imprint><date when="2005">2005</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Journal de physique. IV</title><title level="j" type="abbreviated">J. phys., IV</title><idno type="ISSN">1155-4339</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Antiferromagnetism</term><term>Cobalt Hydroxides nitrates</term><term>Copper Hydroxides nitrates</term><term>Exchange interactions</term><term>Ferromagnetism</term><term>Hydrates</term><term>Layered crystals</term><term>Magnetic ordering</term><term>Magnetic properties</term><term>Multi-element compounds</term><term>Nickel Hydroxides nitrates</term><term>Synthesis</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Synthèse</term><term>Ordre magnétique</term><term>Antiferromagnétisme</term><term>Propriété magnétique</term><term>Interaction échange</term><term>Ferromagnétisme</term><term>Hydrate</term><term>Cobalt Hydroxynitrate</term><term>Cristal lamellaire</term><term>Nickel Hydroxynitrate</term><term>Cuivre Hydroxynitrate</term><term>Composé n éléments</term><term>7525</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Among layered compounds, the transition metal hydroxynitrates M(OH)<sub>2-x</sub>(NO<sub>3</sub>)<sub>x</sub>.nH<sub>2</sub>O (with M= Co, Ni,Cu) are still currently investigated, since they are good precursors for the synthesis of simple or mixed metal oxides with interesting catalytic and electronic properties.From a structural point of view, the hydroxynitrates derive from the CdI<sub>2</sub> type stucture of M (OH)<sub>2</sub>. They can be described as 2D triangular arrays of metal ions with large interplanar distances, and accordingly, they are good candidates for studying bidimensional magnetic systems. Knowing that from a magnetic point view, Co(OH)<sub>2</sub> and Co<sub>2</sub>(OH)<sub>3</sub>(NO<sub>3</sub>) were shown to be a genuine examples of layered ferromagnetic systems, with the occurrence of 3d antiferromagnetic order at nearly the same temperature ; we report in this paper the preparation and magnetic properties of layered cobat mixed metal(II) hydroxynitrates CoM(OH)<sub>3</sub>(NO<sub>3</sub>) (M= Cu, Ba) hydrated or no which display, according to the metal ion, either ferro or antiferromagnetic interlayer interactions. We discuss the interest in these compounds named hybrid organic-inorganic compounds for the stabilizing ferromagnetic interactions.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1155-4339</s0></fA01><fA03 i2="1"><s0>J. phys., IV</s0></fA03><fA05><s2>123</s2></fA05><fA08 i1="01" i2="1" l="ENG"><s1>Magnetic approach in some mixed Cobalt (II) hydroxynitrates compounds</s1></fA08><fA09 i1="01" i2="1" l="ENG"><s1>REMCES IX: Proceedings of the 9th International Seminar on the Physical Chemistry of Solid State Materials</s1></fA09><fA11 i1="01" i2="1"><s1>IZAOUMEN (N.)</s1></fA11><fA11 i1="02" i2="1"><s1>CHERRAB (M.)</s1></fA11><fA11 i1="03" i2="1"><s1>RISSOULI (K.)</s1></fA11><fA11 i1="04" i2="1"><s1>BENKHOUJA (K.)</s1></fA11><fA11 i1="05" i2="1"><s1>JAAFARI (K.)</s1></fA11><fA11 i1="06" i2="1"><s1>FAHAD (M.)</s1></fA11><fA12 i1="01" i2="1"><s1>BENLHACHEMI (Abdeljalil)</s1><s9>ed.</s9></fA12><fA12 i1="02" i2="1"><s1>BENYAICH (H.)</s1><s9>ed.</s9></fA12><fA12 i1="03" i2="1"><s1>BOUABID (Khalid)</s1><s9>ed.</s9></fA12><fA12 i1="04" i2="1"><s1>BOUKHARI (A.)</s1><s9>ed.</s9></fA12><fA12 i1="05" i2="1"><s1>ELAATMANI (M.)</s1><s9>ed.</s9></fA12><fA12 i1="06" i2="1"><s1>ES-SAKHI (B.)</s1><s9>ed.</s9></fA12><fA12 i1="07" i2="1"><s1>IHLAL (A.)</s1><s9>ed.</s9></fA12><fA12 i1="08" i2="1"><s1>KHAIROUNE (S.)</s1><s9>ed.</s9></fA12><fA12 i1="09" i2="1"><s1>MANSOURI (I.)</s1><s9>ed.</s9></fA12><fA12 i1="10" i2="1"><s1>NOUNAH (Abderrahman)</s1><s9>ed.</s9></fA12><fA12 i1="11" i2="1"><s1>TAHA (Mohamed)</s1><s9>ed.</s9></fA12><fA12 i1="12" i2="1"><s1>ZAHIDI (E.)</s1><s9>ed.</s9></fA12><fA14 i1="01"><s1>LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1><s2>24000 Eljadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></fA14><fA14 i1="02"><s1>LPTN, Département de Physique, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1><s2>24000 Eljadida</s2><s3>MAR</s3><sZ>6 aut.</sZ></fA14><fA15 i1="01"><s1>Faculté des Sciences, Cité Dakhla</s1><s2>Agadir</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ><sZ>11 aut.</sZ></fA15><fA15 i1="02"><s1>Ecole Supérieure de Technologie</s1><s2>Salé Médina</s2><s3>MAR</s3><sZ>10 aut.</sZ></fA15><fA18 i1="01" i2="1"><s1>IBN ZOHR University. Faculty of Sciences</s1><s2>Agadir</s2><s3>MAR</s3><s9>patr.</s9></fA18><fA20><s1>291-294</s1></fA20><fA21><s1>2005</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>125C</s2><s5>354000126872900520</s5></fA43><fA44><s0>0000</s0><s1>© 2005 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>10 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>05-0188394</s0></fA47><fA60><s1>P</s1><s2>C</s2></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Journal de physique. IV</s0></fA64><fA66 i1="01"><s0>FRA</s0></fA66><fC01 i1="01" l="ENG"><s0>Among layered compounds, the transition metal hydroxynitrates M(OH)<sub>2-x</sub>(NO<sub>3</sub>)<sub>x</sub>.nH<sub>2</sub>O (with M= Co, Ni,Cu) are still currently investigated, since they are good precursors for the synthesis of simple or mixed metal oxides with interesting catalytic and electronic properties.From a structural point of view, the hydroxynitrates derive from the CdI<sub>2</sub> type stucture of M (OH)<sub>2</sub>. They can be described as 2D triangular arrays of metal ions with large interplanar distances, and accordingly, they are good candidates for studying bidimensional magnetic systems. Knowing that from a magnetic point view, Co(OH)<sub>2</sub> and Co<sub>2</sub>(OH)<sub>3</sub>(NO<sub>3</sub>) were shown to be a genuine examples of layered ferromagnetic systems, with the occurrence of 3d antiferromagnetic order at nearly the same temperature ; we report in this paper the preparation and magnetic properties of layered cobat mixed metal(II) hydroxynitrates CoM(OH)<sub>3</sub>(NO<sub>3</sub>) (M= Cu, Ba) hydrated or no which display, according to the metal ion, either ferro or antiferromagnetic interlayer interactions. We discuss the interest in these compounds named hybrid organic-inorganic compounds for the stabilizing ferromagnetic interactions.</s0></fC01><fC02 i1="01" i2="3"><s0>001B70E25</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Synthèse</s0><s5>02</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Synthesis</s0><s5>02</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>Ordre magnétique</s0><s5>03</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>Magnetic ordering</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Antiferromagnétisme</s0><s5>04</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Antiferromagnetism</s0><s5>04</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Propriété magnétique</s0><s5>06</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Magnetic properties</s0><s5>06</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Interaction échange</s0><s5>08</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Exchange interactions</s0><s5>08</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>Ferromagnétisme</s0><s5>10</s5></fC03><fC03 i1="06" i2="3" l="ENG"><s0>Ferromagnetism</s0><s5>10</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>Hydrate</s0><s2>NA</s2><s5>14</s5></fC03><fC03 i1="07" i2="3" l="ENG"><s0>Hydrates</s0><s2>NA</s2><s5>14</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Cobalt Hydroxynitrate</s0><s2>NC</s2><s2>NA</s2><s5>15</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Cobalt Hydroxides nitrates</s0><s2>NC</s2><s2>NA</s2><s5>15</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Hidroxinitrato</s0><s2>NC</s2><s2>NA</s2><s5>15</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Cristal lamellaire</s0><s5>16</s5></fC03><fC03 i1="09" i2="3" l="ENG"><s0>Layered crystals</s0><s5>16</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>Nickel Hydroxynitrate</s0><s2>NC</s2><s2>NA</s2><s5>17</s5></fC03><fC03 i1="10" i2="X" l="ENG"><s0>Nickel Hydroxides nitrates</s0><s2>NC</s2><s2>NA</s2><s5>17</s5></fC03><fC03 i1="10" i2="X" l="SPA"><s0>Hidroxinitrato</s0><s2>NC</s2><s2>NA</s2><s5>17</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Cuivre Hydroxynitrate</s0><s2>NC</s2><s2>NA</s2><s5>18</s5></fC03><fC03 i1="11" i2="X" l="ENG"><s0>Copper Hydroxides nitrates</s0><s2>NC</s2><s2>NA</s2><s5>18</s5></fC03><fC03 i1="11" i2="X" l="SPA"><s0>Hidroxinitrato</s0><s2>NC</s2><s2>NA</s2><s5>18</s5></fC03><fC03 i1="12" i2="3" l="FRE"><s0>Composé n éléments</s0><s5>19</s5></fC03><fC03 i1="12" i2="3" l="ENG"><s0>Multi-element compounds</s0><s5>19</s5></fC03><fC03 i1="13" i2="3" l="FRE"><s0>7525</s0><s4>INC</s4><s5>56</s5></fC03><fC07 i1="01" i2="3" l="FRE"><s0>Métal transition composé</s0><s5>48</s5></fC07><fC07 i1="01" i2="3" l="ENG"><s0>Transition element compounds</s0><s5>48</s5></fC07><fC07 i1="02" i2="3" l="FRE"><s0>Composé minéral</s0><s5>49</s5></fC07><fC07 i1="02" i2="3" l="ENG"><s0>Inorganic compounds</s0><s5>49</s5></fC07><fN21><s1>129</s1></fN21><fN44 i1="01"><s1>PSI</s1></fN44><fN82><s1>PSI</s1></fN82></pA><pR><fA30 i1="01" i2="1" l="ENG"><s1>REMCES International Seminar on the Physical Chemistry of Solid State Materials</s1><s2>9</s2><s3>Agadir MAR</s3><s4>2002-10-30</s4></fA30></pR></standard></inist><affiliations><list><country><li>Maroc</li></country><region><li>Casablanca-Settat</li></region><settlement><li>El Jadida</li></settlement><orgName><li>Université Chouaib Doukkali</li></orgName></list><tree><country name="Maroc"><region name="Casablanca-Settat"><name sortKey="Izaoumen, N" sort="Izaoumen, N" uniqKey="Izaoumen N" first="N." last="Izaoumen">N. Izaoumen</name></region><name sortKey="Benkhouja, K" sort="Benkhouja, K" uniqKey="Benkhouja K" first="K." last="Benkhouja">K. Benkhouja</name><name sortKey="Cherrab, M" sort="Cherrab, M" uniqKey="Cherrab M" first="M." last="Cherrab">M. Cherrab</name><name sortKey="Fahad, M" sort="Fahad, M" uniqKey="Fahad M" first="M." last="Fahad">M. Fahad</name><name sortKey="Jaafari, K" sort="Jaafari, K" uniqKey="Jaafari K" first="K." last="Jaafari">K. Jaafari</name><name sortKey="Rissouli, K" sort="Rissouli, K" uniqKey="Rissouli K" first="K." last="Rissouli">K. Rissouli</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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