Serveur d'exploration sur le cobalt au Maghreb

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Magnetic approach in some mixed Cobalt (II) hydroxynitrates compounds

Identifieur interne : 000189 ( PascalFrancis/Corpus ); précédent : 000188; suivant : 000190

Magnetic approach in some mixed Cobalt (II) hydroxynitrates compounds

Auteurs : N. Izaoumen ; M. Cherrab ; K. Rissouli ; K. Benkhouja ; K. Jaafari ; M. Fahad

Source :

RBID : Pascal:05-0188394

Descripteurs français

English descriptors

Abstract

Among layered compounds, the transition metal hydroxynitrates M(OH)2-x(NO3)x.nH2O (with M= Co, Ni,Cu) are still currently investigated, since they are good precursors for the synthesis of simple or mixed metal oxides with interesting catalytic and electronic properties.From a structural point of view, the hydroxynitrates derive from the CdI2 type stucture of M (OH)2. They can be described as 2D triangular arrays of metal ions with large interplanar distances, and accordingly, they are good candidates for studying bidimensional magnetic systems. Knowing that from a magnetic point view, Co(OH)2 and Co2(OH)3(NO3) were shown to be a genuine examples of layered ferromagnetic systems, with the occurrence of 3d antiferromagnetic order at nearly the same temperature ; we report in this paper the preparation and magnetic properties of layered cobat mixed metal(II) hydroxynitrates CoM(OH)3(NO3) (M= Cu, Ba) hydrated or no which display, according to the metal ion, either ferro or antiferromagnetic interlayer interactions. We discuss the interest in these compounds named hybrid organic-inorganic compounds for the stabilizing ferromagnetic interactions.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 1155-4339
A03   1    @0 J. phys., IV
A05       @2 123
A08 01  1  ENG  @1 Magnetic approach in some mixed Cobalt (II) hydroxynitrates compounds
A09 01  1  ENG  @1 REMCES IX: Proceedings of the 9th International Seminar on the Physical Chemistry of Solid State Materials
A11 01  1    @1 IZAOUMEN (N.)
A11 02  1    @1 CHERRAB (M.)
A11 03  1    @1 RISSOULI (K.)
A11 04  1    @1 BENKHOUJA (K.)
A11 05  1    @1 JAAFARI (K.)
A11 06  1    @1 FAHAD (M.)
A12 01  1    @1 BENLHACHEMI (Abdeljalil) @9 ed.
A12 02  1    @1 BENYAICH (H.) @9 ed.
A12 03  1    @1 BOUABID (Khalid) @9 ed.
A12 04  1    @1 BOUKHARI (A.) @9 ed.
A12 05  1    @1 ELAATMANI (M.) @9 ed.
A12 06  1    @1 ES-SAKHI (B.) @9 ed.
A12 07  1    @1 IHLAL (A.) @9 ed.
A12 08  1    @1 KHAIROUNE (S.) @9 ed.
A12 09  1    @1 MANSOURI (I.) @9 ed.
A12 10  1    @1 NOUNAH (Abderrahman) @9 ed.
A12 11  1    @1 TAHA (Mohamed) @9 ed.
A12 12  1    @1 ZAHIDI (E.) @9 ed.
A14 01      @1 LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20 @2 24000 Eljadida @3 MAR @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut. @Z 5 aut.
A14 02      @1 LPTN, Département de Physique, Faculté des Sciences, Université Chouaib Doukkali, BP. 20 @2 24000 Eljadida @3 MAR @Z 6 aut.
A15 01      @1 Faculté des Sciences, Cité Dakhla @2 Agadir @3 MAR @Z 1 aut. @Z 3 aut. @Z 11 aut.
A15 02      @1 Ecole Supérieure de Technologie @2 Salé Médina @3 MAR @Z 10 aut.
A18 01  1    @1 IBN ZOHR University. Faculty of Sciences @2 Agadir @3 MAR @9 patr.
A20       @1 291-294
A21       @1 2005
A23 01      @0 ENG
A43 01      @1 INIST @2 125C @5 354000126872900520
A44       @0 0000 @1 © 2005 INIST-CNRS. All rights reserved.
A45       @0 10 ref.
A47 01  1    @0 05-0188394
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Journal de physique. IV
A66 01      @0 FRA
C01 01    ENG  @0 Among layered compounds, the transition metal hydroxynitrates M(OH)2-x(NO3)x.nH2O (with M= Co, Ni,Cu) are still currently investigated, since they are good precursors for the synthesis of simple or mixed metal oxides with interesting catalytic and electronic properties.From a structural point of view, the hydroxynitrates derive from the CdI2 type stucture of M (OH)2. They can be described as 2D triangular arrays of metal ions with large interplanar distances, and accordingly, they are good candidates for studying bidimensional magnetic systems. Knowing that from a magnetic point view, Co(OH)2 and Co2(OH)3(NO3) were shown to be a genuine examples of layered ferromagnetic systems, with the occurrence of 3d antiferromagnetic order at nearly the same temperature ; we report in this paper the preparation and magnetic properties of layered cobat mixed metal(II) hydroxynitrates CoM(OH)3(NO3) (M= Cu, Ba) hydrated or no which display, according to the metal ion, either ferro or antiferromagnetic interlayer interactions. We discuss the interest in these compounds named hybrid organic-inorganic compounds for the stabilizing ferromagnetic interactions.
C02 01  3    @0 001B70E25
C03 01  3  FRE  @0 Synthèse @5 02
C03 01  3  ENG  @0 Synthesis @5 02
C03 02  3  FRE  @0 Ordre magnétique @5 03
C03 02  3  ENG  @0 Magnetic ordering @5 03
C03 03  3  FRE  @0 Antiferromagnétisme @5 04
C03 03  3  ENG  @0 Antiferromagnetism @5 04
C03 04  3  FRE  @0 Propriété magnétique @5 06
C03 04  3  ENG  @0 Magnetic properties @5 06
C03 05  3  FRE  @0 Interaction échange @5 08
C03 05  3  ENG  @0 Exchange interactions @5 08
C03 06  3  FRE  @0 Ferromagnétisme @5 10
C03 06  3  ENG  @0 Ferromagnetism @5 10
C03 07  3  FRE  @0 Hydrate @2 NA @5 14
C03 07  3  ENG  @0 Hydrates @2 NA @5 14
C03 08  X  FRE  @0 Cobalt Hydroxynitrate @2 NC @2 NA @5 15
C03 08  X  ENG  @0 Cobalt Hydroxides nitrates @2 NC @2 NA @5 15
C03 08  X  SPA  @0 Hidroxinitrato @2 NC @2 NA @5 15
C03 09  3  FRE  @0 Cristal lamellaire @5 16
C03 09  3  ENG  @0 Layered crystals @5 16
C03 10  X  FRE  @0 Nickel Hydroxynitrate @2 NC @2 NA @5 17
C03 10  X  ENG  @0 Nickel Hydroxides nitrates @2 NC @2 NA @5 17
C03 10  X  SPA  @0 Hidroxinitrato @2 NC @2 NA @5 17
C03 11  X  FRE  @0 Cuivre Hydroxynitrate @2 NC @2 NA @5 18
C03 11  X  ENG  @0 Copper Hydroxides nitrates @2 NC @2 NA @5 18
C03 11  X  SPA  @0 Hidroxinitrato @2 NC @2 NA @5 18
C03 12  3  FRE  @0 Composé n éléments @5 19
C03 12  3  ENG  @0 Multi-element compounds @5 19
C03 13  3  FRE  @0 7525 @4 INC @5 56
C07 01  3  FRE  @0 Métal transition composé @5 48
C07 01  3  ENG  @0 Transition element compounds @5 48
C07 02  3  FRE  @0 Composé minéral @5 49
C07 02  3  ENG  @0 Inorganic compounds @5 49
N21       @1 129
N44 01      @1 PSI
N82       @1 PSI
pR  
A30 01  1  ENG  @1 REMCES International Seminar on the Physical Chemistry of Solid State Materials @2 9 @3 Agadir MAR @4 2002-10-30

Format Inist (serveur)

NO : PASCAL 05-0188394 INIST
ET : Magnetic approach in some mixed Cobalt (II) hydroxynitrates compounds
AU : IZAOUMEN (N.); CHERRAB (M.); RISSOULI (K.); BENKHOUJA (K.); JAAFARI (K.); FAHAD (M.); BENLHACHEMI (Abdeljalil); BENYAICH (H.); BOUABID (Khalid); BOUKHARI (A.); ELAATMANI (M.); ES-SAKHI (B.); IHLAL (A.); KHAIROUNE (S.); MANSOURI (I.); NOUNAH (Abderrahman); TAHA (Mohamed); ZAHIDI (E.)
AF : LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20/24000 Eljadida/Maroc (1 aut., 2 aut., 3 aut., 4 aut., 5 aut.); LPTN, Département de Physique, Faculté des Sciences, Université Chouaib Doukkali, BP. 20/24000 Eljadida/Maroc (6 aut.); Faculté des Sciences, Cité Dakhla/Agadir/Maroc (1 aut., 3 aut., 11 aut.); Ecole Supérieure de Technologie/Salé Médina/Maroc (10 aut.)
DT : Publication en série; Congrès; Niveau analytique
SO : Journal de physique. IV; ISSN 1155-4339; France; Da. 2005; Vol. 123; Pp. 291-294; Bibl. 10 ref.
LA : Anglais
EA : Among layered compounds, the transition metal hydroxynitrates M(OH)2-x(NO3)x.nH2O (with M= Co, Ni,Cu) are still currently investigated, since they are good precursors for the synthesis of simple or mixed metal oxides with interesting catalytic and electronic properties.From a structural point of view, the hydroxynitrates derive from the CdI2 type stucture of M (OH)2. They can be described as 2D triangular arrays of metal ions with large interplanar distances, and accordingly, they are good candidates for studying bidimensional magnetic systems. Knowing that from a magnetic point view, Co(OH)2 and Co2(OH)3(NO3) were shown to be a genuine examples of layered ferromagnetic systems, with the occurrence of 3d antiferromagnetic order at nearly the same temperature ; we report in this paper the preparation and magnetic properties of layered cobat mixed metal(II) hydroxynitrates CoM(OH)3(NO3) (M= Cu, Ba) hydrated or no which display, according to the metal ion, either ferro or antiferromagnetic interlayer interactions. We discuss the interest in these compounds named hybrid organic-inorganic compounds for the stabilizing ferromagnetic interactions.
CC : 001B70E25
FD : Synthèse; Ordre magnétique; Antiferromagnétisme; Propriété magnétique; Interaction échange; Ferromagnétisme; Hydrate; Cobalt Hydroxynitrate; Cristal lamellaire; Nickel Hydroxynitrate; Cuivre Hydroxynitrate; Composé n éléments; 7525
FG : Métal transition composé; Composé minéral
ED : Synthesis; Magnetic ordering; Antiferromagnetism; Magnetic properties; Exchange interactions; Ferromagnetism; Hydrates; Cobalt Hydroxides nitrates; Layered crystals; Nickel Hydroxides nitrates; Copper Hydroxides nitrates; Multi-element compounds
EG : Transition element compounds; Inorganic compounds
SD : Hidroxinitrato; Hidroxinitrato; Hidroxinitrato
LO : INIST-125C.354000126872900520
ID : 05-0188394

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Pascal:05-0188394

Le document en format XML

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<term>Antiferromagnetism</term>
<term>Cobalt Hydroxides nitrates</term>
<term>Copper Hydroxides nitrates</term>
<term>Exchange interactions</term>
<term>Ferromagnetism</term>
<term>Hydrates</term>
<term>Layered crystals</term>
<term>Magnetic ordering</term>
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<term>Interaction échange</term>
<term>Ferromagnétisme</term>
<term>Hydrate</term>
<term>Cobalt Hydroxynitrate</term>
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<div type="abstract" xml:lang="en">Among layered compounds, the transition metal hydroxynitrates M(OH)
<sub>2-x</sub>
(NO
<sub>3</sub>
)
<sub>x</sub>
.nH
<sub>2</sub>
O (with M= Co, Ni,Cu) are still currently investigated, since they are good precursors for the synthesis of simple or mixed metal oxides with interesting catalytic and electronic properties.From a structural point of view, the hydroxynitrates derive from the CdI
<sub>2</sub>
type stucture of M (OH)
<sub>2</sub>
. They can be described as 2D triangular arrays of metal ions with large interplanar distances, and accordingly, they are good candidates for studying bidimensional magnetic systems. Knowing that from a magnetic point view, Co(OH)
<sub>2</sub>
and Co
<sub>2</sub>
(OH)
<sub>3</sub>
(NO
<sub>3</sub>
) were shown to be a genuine examples of layered ferromagnetic systems, with the occurrence of 3d antiferromagnetic order at nearly the same temperature ; we report in this paper the preparation and magnetic properties of layered cobat mixed metal(II) hydroxynitrates CoM(OH)
<sub>3</sub>
(NO
<sub>3</sub>
) (M= Cu, Ba) hydrated or no which display, according to the metal ion, either ferro or antiferromagnetic interlayer interactions. We discuss the interest in these compounds named hybrid organic-inorganic compounds for the stabilizing ferromagnetic interactions.</div>
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</fA12>
<fA12 i1="06" i2="1">
<s1>ES-SAKHI (B.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="07" i2="1">
<s1>IHLAL (A.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="08" i2="1">
<s1>KHAIROUNE (S.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="09" i2="1">
<s1>MANSOURI (I.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="10" i2="1">
<s1>NOUNAH (Abderrahman)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="11" i2="1">
<s1>TAHA (Mohamed)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="12" i2="1">
<s1>ZAHIDI (E.)</s1>
<s9>ed.</s9>
</fA12>
<fA14 i1="01">
<s1>LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1>
<s2>24000 Eljadida</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="02">
<s1>LPTN, Département de Physique, Faculté des Sciences, Université Chouaib Doukkali, BP. 20</s1>
<s2>24000 Eljadida</s2>
<s3>MAR</s3>
<sZ>6 aut.</sZ>
</fA14>
<fA15 i1="01">
<s1>Faculté des Sciences, Cité Dakhla</s1>
<s2>Agadir</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>11 aut.</sZ>
</fA15>
<fA15 i1="02">
<s1>Ecole Supérieure de Technologie</s1>
<s2>Salé Médina</s2>
<s3>MAR</s3>
<sZ>10 aut.</sZ>
</fA15>
<fA18 i1="01" i2="1">
<s1>IBN ZOHR University. Faculty of Sciences</s1>
<s2>Agadir</s2>
<s3>MAR</s3>
<s9>patr.</s9>
</fA18>
<fA20>
<s1>291-294</s1>
</fA20>
<fA21>
<s1>2005</s1>
</fA21>
<fA23 i1="01">
<s0>ENG</s0>
</fA23>
<fA43 i1="01">
<s1>INIST</s1>
<s2>125C</s2>
<s5>354000126872900520</s5>
</fA43>
<fA44>
<s0>0000</s0>
<s1>© 2005 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45>
<s0>10 ref.</s0>
</fA45>
<fA47 i1="01" i2="1">
<s0>05-0188394</s0>
</fA47>
<fA60>
<s1>P</s1>
<s2>C</s2>
</fA60>
<fA61>
<s0>A</s0>
</fA61>
<fA64 i1="01" i2="1">
<s0>Journal de physique. IV</s0>
</fA64>
<fA66 i1="01">
<s0>FRA</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>Among layered compounds, the transition metal hydroxynitrates M(OH)
<sub>2-x</sub>
(NO
<sub>3</sub>
)
<sub>x</sub>
.nH
<sub>2</sub>
O (with M= Co, Ni,Cu) are still currently investigated, since they are good precursors for the synthesis of simple or mixed metal oxides with interesting catalytic and electronic properties.From a structural point of view, the hydroxynitrates derive from the CdI
<sub>2</sub>
type stucture of M (OH)
<sub>2</sub>
. They can be described as 2D triangular arrays of metal ions with large interplanar distances, and accordingly, they are good candidates for studying bidimensional magnetic systems. Knowing that from a magnetic point view, Co(OH)
<sub>2</sub>
and Co
<sub>2</sub>
(OH)
<sub>3</sub>
(NO
<sub>3</sub>
) were shown to be a genuine examples of layered ferromagnetic systems, with the occurrence of 3d antiferromagnetic order at nearly the same temperature ; we report in this paper the preparation and magnetic properties of layered cobat mixed metal(II) hydroxynitrates CoM(OH)
<sub>3</sub>
(NO
<sub>3</sub>
) (M= Cu, Ba) hydrated or no which display, according to the metal ion, either ferro or antiferromagnetic interlayer interactions. We discuss the interest in these compounds named hybrid organic-inorganic compounds for the stabilizing ferromagnetic interactions.</s0>
</fC01>
<fC02 i1="01" i2="3">
<s0>001B70E25</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Synthèse</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Synthesis</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE">
<s0>Ordre magnétique</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG">
<s0>Magnetic ordering</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE">
<s0>Antiferromagnétisme</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG">
<s0>Antiferromagnetism</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE">
<s0>Propriété magnétique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG">
<s0>Magnetic properties</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Interaction échange</s0>
<s5>08</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Exchange interactions</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Ferromagnétisme</s0>
<s5>10</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Ferromagnetism</s0>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Hydrate</s0>
<s2>NA</s2>
<s5>14</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Hydrates</s0>
<s2>NA</s2>
<s5>14</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Cobalt Hydroxynitrate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>15</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Cobalt Hydroxides nitrates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>15</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Hidroxinitrato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>15</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Cristal lamellaire</s0>
<s5>16</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Layered crystals</s0>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Nickel Hydroxynitrate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Nickel Hydroxides nitrates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>17</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Hidroxinitrato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Cuivre Hydroxynitrate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>18</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Copper Hydroxides nitrates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>18</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Hidroxinitrato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Composé n éléments</s0>
<s5>19</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Multi-element compounds</s0>
<s5>19</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>7525</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE">
<s0>Métal transition composé</s0>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG">
<s0>Transition element compounds</s0>
<s5>48</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE">
<s0>Composé minéral</s0>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG">
<s0>Inorganic compounds</s0>
<s5>49</s5>
</fC07>
<fN21>
<s1>129</s1>
</fN21>
<fN44 i1="01">
<s1>PSI</s1>
</fN44>
<fN82>
<s1>PSI</s1>
</fN82>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>REMCES International Seminar on the Physical Chemistry of Solid State Materials</s1>
<s2>9</s2>
<s3>Agadir MAR</s3>
<s4>2002-10-30</s4>
</fA30>
</pR>
</standard>
<server>
<NO>PASCAL 05-0188394 INIST</NO>
<ET>Magnetic approach in some mixed Cobalt (II) hydroxynitrates compounds</ET>
<AU>IZAOUMEN (N.); CHERRAB (M.); RISSOULI (K.); BENKHOUJA (K.); JAAFARI (K.); FAHAD (M.); BENLHACHEMI (Abdeljalil); BENYAICH (H.); BOUABID (Khalid); BOUKHARI (A.); ELAATMANI (M.); ES-SAKHI (B.); IHLAL (A.); KHAIROUNE (S.); MANSOURI (I.); NOUNAH (Abderrahman); TAHA (Mohamed); ZAHIDI (E.)</AU>
<AF>LMCM, Département de Chimie, Faculté des Sciences, Université Chouaib Doukkali, BP. 20/24000 Eljadida/Maroc (1 aut., 2 aut., 3 aut., 4 aut., 5 aut.); LPTN, Département de Physique, Faculté des Sciences, Université Chouaib Doukkali, BP. 20/24000 Eljadida/Maroc (6 aut.); Faculté des Sciences, Cité Dakhla/Agadir/Maroc (1 aut., 3 aut., 11 aut.); Ecole Supérieure de Technologie/Salé Médina/Maroc (10 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Journal de physique. IV; ISSN 1155-4339; France; Da. 2005; Vol. 123; Pp. 291-294; Bibl. 10 ref.</SO>
<LA>Anglais</LA>
<EA>Among layered compounds, the transition metal hydroxynitrates M(OH)
<sub>2-x</sub>
(NO
<sub>3</sub>
)
<sub>x</sub>
.nH
<sub>2</sub>
O (with M= Co, Ni,Cu) are still currently investigated, since they are good precursors for the synthesis of simple or mixed metal oxides with interesting catalytic and electronic properties.From a structural point of view, the hydroxynitrates derive from the CdI
<sub>2</sub>
type stucture of M (OH)
<sub>2</sub>
. They can be described as 2D triangular arrays of metal ions with large interplanar distances, and accordingly, they are good candidates for studying bidimensional magnetic systems. Knowing that from a magnetic point view, Co(OH)
<sub>2</sub>
and Co
<sub>2</sub>
(OH)
<sub>3</sub>
(NO
<sub>3</sub>
) were shown to be a genuine examples of layered ferromagnetic systems, with the occurrence of 3d antiferromagnetic order at nearly the same temperature ; we report in this paper the preparation and magnetic properties of layered cobat mixed metal(II) hydroxynitrates CoM(OH)
<sub>3</sub>
(NO
<sub>3</sub>
) (M= Cu, Ba) hydrated or no which display, according to the metal ion, either ferro or antiferromagnetic interlayer interactions. We discuss the interest in these compounds named hybrid organic-inorganic compounds for the stabilizing ferromagnetic interactions.</EA>
<CC>001B70E25</CC>
<FD>Synthèse; Ordre magnétique; Antiferromagnétisme; Propriété magnétique; Interaction échange; Ferromagnétisme; Hydrate; Cobalt Hydroxynitrate; Cristal lamellaire; Nickel Hydroxynitrate; Cuivre Hydroxynitrate; Composé n éléments; 7525</FD>
<FG>Métal transition composé; Composé minéral</FG>
<ED>Synthesis; Magnetic ordering; Antiferromagnetism; Magnetic properties; Exchange interactions; Ferromagnetism; Hydrates; Cobalt Hydroxides nitrates; Layered crystals; Nickel Hydroxides nitrates; Copper Hydroxides nitrates; Multi-element compounds</ED>
<EG>Transition element compounds; Inorganic compounds</EG>
<SD>Hidroxinitrato; Hidroxinitrato; Hidroxinitrato</SD>
<LO>INIST-125C.354000126872900520</LO>
<ID>05-0188394</ID>
</server>
</inist>
</record>

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