CobaltMaghrebV1, PascalFrancis, Checkpoint, bibRecord, 000161

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

Identifieur interne : 000161 ( PascalFrancis/Checkpoint ); précédent : 000160; suivant : 000162

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

Auteurs : Francesco Capitelli [Italie] ; Brahim El Bali [Maroc] ; Rachid Essehli [Maroc] ; Mohammed Lachkar [Maroc] ; Veronica Valentini [Italie] ; Giorgio Mattei [Italie] ; Jan Taraba [République tchèque] ; Zdirak Zak [République tchèque]

Source :

Zeitschrift für Kristallographie [ 0044-2968 ] ; 2006.

RBID : Pascal:06-0526554

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Mode vibration, Liaison hydrogène, Spectre Raman, Spectre IR, Spectre transformée Fourier, Diffraction RX, Structure cristalline, Ethylène, Ammonium phosphate, Cristal centrosymétrique, Matériau hybride, Réseau triclinique, Cobalt phosphate, Nickel phosphate, 6166F.

English descriptors

KwdEn :
- Ammonium phosphates, Centrosymmetrical crystals, Cobalt phosphates, Crystal structure, Ethylene, Experimental study, Fourier transform spectra, Hybrid material, Hydrogen bonds, Infrared spectra, Nickel phosphates, Raman spectra, Triclinic lattices, Vibrational modes, XRD.

Abstract

New ethylenediammonium diphosphates (NH₃(CH₂)₂NH₃)₂[Me(HP₂O₇)₂ . 2 H₂O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å³ (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å³ (2). The three-dimensional network is built up by discrete Me(HP₂O₇)₂ . 2 H₂O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.

Affiliations:

Links toward previous steps (curation, corpus...)

to stream PascalFrancis, to step Corpus: 000156
to stream PascalFrancis, to step Curation: 000139

Links to Exploration step

Pascal:06-0526554

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">New isostructural ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy</title>
<author><name sortKey="Capitelli, Francesco" sort="Capitelli, Francesco" uniqKey="Capitelli F" first="Francesco" last="Capitelli">Francesco Capitelli</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Istituto di Cristallografia (IC-CNR), sezione di Bari, Via Amendola 122/o</s1>
<s2>70126 Bari</s2>
<s3>ITA</s3>
<sZ>1 aut.</sZ>
</inist:fA14>
<country>Italie</country>
<wicri:noRegion>70126 Bari</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="El Bali, Brahim" sort="El Bali, Brahim" uniqKey="El Bali B" first="Brahim" last="El Bali">Brahim El Bali</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
<s2>30000 Fès</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>30000 Fès</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Essehli, Rachid" sort="Essehli, Rachid" uniqKey="Essehli R" first="Rachid" last="Essehli">Rachid Essehli</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
<s2>30000 Fès</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>30000 Fès</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Lachkar, Mohammed" sort="Lachkar, Mohammed" uniqKey="Lachkar M" first="Mohammed" last="Lachkar">Mohammed Lachkar</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
<s2>30000 Fès</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>30000 Fès</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Valentini, Veronica" sort="Valentini, Veronica" uniqKey="Valentini V" first="Veronica" last="Valentini">Veronica Valentini</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10</s1>
<s2>00016 Monterotondo Stazione (Roma)</s2>
<s3>ITA</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Italie</country>
<wicri:noRegion>00016 Monterotondo Stazione (Roma)</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Mattei, Giorgio" sort="Mattei, Giorgio" uniqKey="Mattei G" first="Giorgio" last="Mattei">Giorgio Mattei</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10</s1>
<s2>00016 Monterotondo Stazione (Roma)</s2>
<s3>ITA</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Italie</country>
<wicri:noRegion>00016 Monterotondo Stazione (Roma)</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Taraba, Jan" sort="Taraba, Jan" uniqKey="Taraba J" first="Jan" last="Taraba">Jan Taraba</name>
<affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
<s3>CZE</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>République tchèque</country>
<placeName><settlement type="city">Brno</settlement>
<region>Moravie</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Zak, Zdirak" sort="Zak, Zdirak" uniqKey="Zak Z" first="Zdirak" last="Zak">Zdirak Zak</name>
<affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
<s3>CZE</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>République tchèque</country>
<placeName><settlement type="city">Brno</settlement>
<region>Moravie</region>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">06-0526554</idno>
<date when="2006">2006</date>
<idno type="stanalyst">PASCAL 06-0526554 INIST</idno>
<idno type="RBID">Pascal:06-0526554</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000156</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000139</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">000161</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000161</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">New isostructural ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy</title>
<author><name sortKey="Capitelli, Francesco" sort="Capitelli, Francesco" uniqKey="Capitelli F" first="Francesco" last="Capitelli">Francesco Capitelli</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Istituto di Cristallografia (IC-CNR), sezione di Bari, Via Amendola 122/o</s1>
<s2>70126 Bari</s2>
<s3>ITA</s3>
<sZ>1 aut.</sZ>
</inist:fA14>
<country>Italie</country>
<wicri:noRegion>70126 Bari</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="El Bali, Brahim" sort="El Bali, Brahim" uniqKey="El Bali B" first="Brahim" last="El Bali">Brahim El Bali</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
<s2>30000 Fès</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>30000 Fès</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Essehli, Rachid" sort="Essehli, Rachid" uniqKey="Essehli R" first="Rachid" last="Essehli">Rachid Essehli</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
<s2>30000 Fès</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>30000 Fès</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Lachkar, Mohammed" sort="Lachkar, Mohammed" uniqKey="Lachkar M" first="Mohammed" last="Lachkar">Mohammed Lachkar</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
<s2>30000 Fès</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>30000 Fès</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Valentini, Veronica" sort="Valentini, Veronica" uniqKey="Valentini V" first="Veronica" last="Valentini">Veronica Valentini</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10</s1>
<s2>00016 Monterotondo Stazione (Roma)</s2>
<s3>ITA</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Italie</country>
<wicri:noRegion>00016 Monterotondo Stazione (Roma)</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Mattei, Giorgio" sort="Mattei, Giorgio" uniqKey="Mattei G" first="Giorgio" last="Mattei">Giorgio Mattei</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10</s1>
<s2>00016 Monterotondo Stazione (Roma)</s2>
<s3>ITA</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Italie</country>
<wicri:noRegion>00016 Monterotondo Stazione (Roma)</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Taraba, Jan" sort="Taraba, Jan" uniqKey="Taraba J" first="Jan" last="Taraba">Jan Taraba</name>
<affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
<s3>CZE</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>République tchèque</country>
<placeName><settlement type="city">Brno</settlement>
<region>Moravie</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Zak, Zdirak" sort="Zak, Zdirak" uniqKey="Zak Z" first="Zdirak" last="Zak">Zdirak Zak</name>
<affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
<s3>CZE</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>République tchèque</country>
<placeName><settlement type="city">Brno</settlement>
<region>Moravie</region>
</placeName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Zeitschrift für Kristallographie</title>
<title level="j" type="abbreviated">Z. Kristallogr.</title>
<idno type="ISSN">0044-2968</idno>
<imprint><date when="2006">2006</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Zeitschrift für Kristallographie</title>
<title level="j" type="abbreviated">Z. Kristallogr.</title>
<idno type="ISSN">0044-2968</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Ammonium phosphates</term>
<term>Centrosymmetrical crystals</term>
<term>Cobalt phosphates</term>
<term>Crystal structure</term>
<term>Ethylene</term>
<term>Experimental study</term>
<term>Fourier transform spectra</term>
<term>Hybrid material</term>
<term>Hydrogen bonds</term>
<term>Infrared spectra</term>
<term>Nickel phosphates</term>
<term>Raman spectra</term>
<term>Triclinic lattices</term>
<term>Vibrational modes</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Mode vibration</term>
<term>Liaison hydrogène</term>
<term>Spectre Raman</term>
<term>Spectre IR</term>
<term>Spectre transformée Fourier</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Ethylène</term>
<term>Ammonium phosphate</term>
<term>Cristal centrosymétrique</term>
<term>Matériau hybride</term>
<term>Réseau triclinique</term>
<term>Cobalt phosphate</term>
<term>Nickel phosphate</term>
<term>6166F</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">New ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å<sup>3</sup>
 (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å<sup>3</sup>
 (2). The three-dimensional network is built up by discrete Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0044-2968</s0>
</fA01>
<fA02 i1="01"><s0>ZEKRDZ</s0>
</fA02>
<fA03 i2="1"><s0>Z. Kristallogr.</s0>
</fA03>
<fA05><s2>221</s2>
</fA05>
<fA06><s2>9</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>New isostructural ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>CAPITELLI (Francesco)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>EL BALI (Brahim)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>ESSEHLI (Rachid)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>LACHKAR (Mohammed)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>VALENTINI (Veronica)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>MATTEI (Giorgio)</s1>
</fA11>
<fA11 i1="07" i2="1"><s1>TARABA (Jan)</s1>
</fA11>
<fA11 i1="08" i2="1"><s1>ZAK (Zdirak)</s1>
</fA11>
<fA14 i1="01"><s1>Istituto di Cristallografia (IC-CNR), sezione di Bari, Via Amendola 122/o</s1>
<s2>70126 Bari</s2>
<s3>ITA</s3>
<sZ>1 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
<s2>30000 Fès</s2>
<s3>MAR</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10</s1>
<s2>00016 Monterotondo Stazione (Roma)</s2>
<s3>ITA</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</fA14>
<fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
<s3>CZE</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</fA14>
<fA20><s1>649-655</s1>
</fA20>
<fA21><s1>2006</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>915</s2>
<s5>354000156913560050</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2006 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>30 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>06-0526554</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Zeitschrift für Kristallographie</s0>
</fA64>
<fA66 i1="01"><s0>DEU</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>New ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å<sup>3</sup>
 (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å<sup>3</sup>
 (2). The three-dimensional network is built up by discrete Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F7</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Mode vibration</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Vibrational modes</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Liaison hydrogène</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Hydrogen bonds</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Spectre Raman</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Raman spectra</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Spectre IR</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Infrared spectra</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Spectre transformée Fourier</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Fourier transform spectra</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>XRD</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>14</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>14</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Ethylène</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Ethylene</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Ammonium phosphate</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Ammonium phosphates</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Cristal centrosymétrique</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Centrosymmetrical crystals</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Cristal centrosimétrico</s0>
<s5>17</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Matériau hybride</s0>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Hybrid material</s0>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Material híbrido</s0>
<s5>18</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Réseau triclinique</s0>
<s5>19</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>Triclinic lattices</s0>
<s5>19</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Cobalt phosphate</s0>
<s2>NK</s2>
<s5>20</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Cobalt phosphates</s0>
<s2>NK</s2>
<s5>20</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Nickel phosphate</s0>
<s2>NK</s2>
<s5>21</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG"><s0>Nickel phosphates</s0>
<s2>NK</s2>
<s5>21</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>48</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>49</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE"><s0>Composé organique</s0>
<s5>50</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG"><s0>Organic compounds</s0>
<s5>50</s5>
</fC07>
<fN21><s1>346</s1>
</fN21>
<fN44 i1="01"><s1>PSI</s1>
</fN44>
<fN82><s1>PSI</s1>
</fN82>
</pA>
</standard>
</inist>
<affiliations><list><country><li>Italie</li>
<li>Maroc</li>
<li>République tchèque</li>
</country>
<region><li>Moravie</li>
</region>
<settlement><li>Brno</li>
</settlement>
</list>
<tree><country name="Italie"><noRegion><name sortKey="Capitelli, Francesco" sort="Capitelli, Francesco" uniqKey="Capitelli F" first="Francesco" last="Capitelli">Francesco Capitelli</name>
</noRegion>
<name sortKey="Mattei, Giorgio" sort="Mattei, Giorgio" uniqKey="Mattei G" first="Giorgio" last="Mattei">Giorgio Mattei</name>
<name sortKey="Valentini, Veronica" sort="Valentini, Veronica" uniqKey="Valentini V" first="Veronica" last="Valentini">Veronica Valentini</name>
</country>
<country name="Maroc"><noRegion><name sortKey="El Bali, Brahim" sort="El Bali, Brahim" uniqKey="El Bali B" first="Brahim" last="El Bali">Brahim El Bali</name>
</noRegion>
<name sortKey="Essehli, Rachid" sort="Essehli, Rachid" uniqKey="Essehli R" first="Rachid" last="Essehli">Rachid Essehli</name>
<name sortKey="Lachkar, Mohammed" sort="Lachkar, Mohammed" uniqKey="Lachkar M" first="Mohammed" last="Lachkar">Mohammed Lachkar</name>
</country>
<country name="République tchèque"><region name="Moravie"><name sortKey="Taraba, Jan" sort="Taraba, Jan" uniqKey="Taraba J" first="Jan" last="Taraba">Jan Taraba</name>
</region>
<name sortKey="Zak, Zdirak" sort="Zak, Zdirak" uniqKey="Zak Z" first="Zdirak" last="Zak">Zdirak Zak</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/PascalFrancis/Checkpoint

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000161 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/PascalFrancis/Checkpoint/biblio.hfd -nk 000161 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    CobaltMaghrebV1
   |flux=    PascalFrancis
   |étape=   Checkpoint
   |type=    RBID
   |clé=     Pascal:06-0526554
   |texte=   New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy
}}

This area was generated with Dilib version V0.6.32.
Data generation: Tue Nov 14 12:56:51 2017. Site generation: Mon Feb 12 07:59:49 2024

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri