Solvation phenomena and revision of solid-liquid equilibria in aqueous solutions of two precursors of mixed oxides, the hydrates of cobalt and nickel nitrates : Advanced Thermal Science in France
Identifieur interne : 000022 ( PascalFrancis/Checkpoint ); précédent : 000021; suivant : 000023Solvation phenomena and revision of solid-liquid equilibria in aqueous solutions of two precursors of mixed oxides, the hydrates of cobalt and nickel nitrates : Advanced Thermal Science in France
Auteurs : Richard Tenu [France] ; Christelle Goutaudier [France] ; BAHIJA EL GOUNDALI [Maroc] ; Mohammed Kaddami [Maroc] ; Jean-Jacques Counioux [France]Source :
- Journal of thermal analysis and calorimetry [ 1388-6150 ] ; 2013.
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Abstract
The hydrates of cobalt and nickel nitrates are highly relevant as precursors for the preparation of mixed ceramics. In order to verify the numerous bibliographical data, systematic solubility measurements in aqueous medium under atmospheric pressure and a critical evaluation have been undertaken. By taking solvation phenomena into account, it has proved possible to correlate all the phenomena observed, to obtain equations representative of the liquidus curves, and to refine and extrapolate the experimental curves. The whole stable and metastable coordinates of the invariant transformations in both binary systems have been calculated or more accurately determined.
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: Advanced Thermal Science in France</title><author><name sortKey="Tenu, Richard" sort="Tenu, Richard" uniqKey="Tenu R" first="Richard" last="Tenu">Richard Tenu</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire Multimatériaux et Interfaces, Université de Lyon, Univ Lyon 1 UMR CNRS 5615</s1><s2>69622 Villeurbanne</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Villeurbanne</settlement></placeName></affiliation></author><author><name sortKey="Goutaudier, Christelle" sort="Goutaudier, Christelle" uniqKey="Goutaudier C" first="Christelle" last="Goutaudier">Christelle Goutaudier</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire Multimatériaux et Interfaces, Université de Lyon, Univ Lyon 1 UMR CNRS 5615</s1><s2>69622 Villeurbanne</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region><region type="old region" nuts="2">Rhône-Alpes</region><settlement type="city">Villeurbanne</settlement></placeName></affiliation></author><author><name sortKey="Bahija El Goundali" sort="Bahija El Goundali" uniqKey="Bahija El Goundali" last="Bahija El Goundali">BAHIJA EL GOUNDALI</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire Physico-Chimie des Procédés et Matériaux, Faculté des Sciences et Technologies, Université Hassan Premier</s1><s2>Settat</s2><s3>MAR</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>Settat</wicri:noRegion></affiliation></author><author><name sortKey="Kaddami, Mohammed" sort="Kaddami, Mohammed" uniqKey="Kaddami M" first="Mohammed" last="Kaddami">Mohammed Kaddami</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire Physico-Chimie des 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level="j" type="abbreviated">J. therm. anal. calorim.</title><idno type="ISSN">1388-6150</idno><imprint><date when="2013">2013</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Journal of thermal analysis and calorimetry</title><title level="j" type="abbreviated">J. therm. anal. calorim.</title><idno type="ISSN">1388-6150</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aqueous solution</term><term>Cobalt Nitrates</term><term>Hydrates</term><term>Liquid solid equilibrium</term><term>Nickel Nitrates</term><term>Phase diagram</term><term>Phase equilibrium</term><term>Precursor</term><term>Solvation</term><term>Transition metal Compounds</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Solvatation</term><term>Equilibre liquide solide</term><term>Solution aqueuse</term><term>Précurseur</term><term>Hydrate</term><term>Métal transition Composé</term><term>Nickel 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