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Solvation phenomena and revision of solid-liquid equilibria in aqueous solutions of two precursors of mixed oxides, the hydrates of cobalt and nickel nitrates : Advanced Thermal Science in France

Identifieur interne : 000272 ( PascalFrancis/Curation ); précédent : 000271; suivant : 000273

Solvation phenomena and revision of solid-liquid equilibria in aqueous solutions of two precursors of mixed oxides, the hydrates of cobalt and nickel nitrates : Advanced Thermal Science in France

Auteurs : Richard Tenu [France] ; Christelle Goutaudier [France] ; BAHIJA EL GOUNDALI [Maroc] ; Mohammed Kaddami [Maroc] ; Jean-Jacques Counioux [France]

Source :

RBID : Pascal:13-0286688

Descripteurs français

English descriptors

Abstract

The hydrates of cobalt and nickel nitrates are highly relevant as precursors for the preparation of mixed ceramics. In order to verify the numerous bibliographical data, systematic solubility measurements in aqueous medium under atmospheric pressure and a critical evaluation have been undertaken. By taking solvation phenomena into account, it has proved possible to correlate all the phenomena observed, to obtain equations representative of the liquidus curves, and to refine and extrapolate the experimental curves. The whole stable and metastable coordinates of the invariant transformations in both binary systems have been calculated or more accurately determined.
pA  
A01 01  1    @0 1388-6150
A03   1    @0 J. therm. anal. calorim.
A05       @2 112
A06       @2 1
A08 01  1  ENG  @1 Solvation phenomena and revision of solid-liquid equilibria in aqueous solutions of two precursors of mixed oxides, the hydrates of cobalt and nickel nitrates : Advanced Thermal Science in France
A11 01  1    @1 TENU (Richard)
A11 02  1    @1 GOUTAUDIER (Christelle)
A11 03  1    @1 BAHIJA EL GOUNDALI
A11 04  1    @1 KADDAMI (Mohammed)
A11 05  1    @1 COUNIOUX (Jean-Jacques)
A14 01      @1 Laboratoire Multimatériaux et Interfaces, Université de Lyon, Univ Lyon 1 UMR CNRS 5615 @2 69622 Villeurbanne @3 FRA @Z 1 aut. @Z 2 aut. @Z 5 aut.
A14 02      @1 Laboratoire Physico-Chimie des Procédés et Matériaux, Faculté des Sciences et Technologies, Université Hassan Premier @2 Settat @3 MAR @Z 3 aut. @Z 4 aut.
A20       @1 263-270
A21       @1 2013
A23 01      @0 ENG
A43 01      @1 INIST @2 6367 @5 354000505172840340
A44       @0 0000 @1 © 2013 INIST-CNRS. All rights reserved.
A45       @0 16 ref.
A47 01  1    @0 13-0286688
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Journal of thermal analysis and calorimetry
A66 01      @0 NLD
C01 01    ENG  @0 The hydrates of cobalt and nickel nitrates are highly relevant as precursors for the preparation of mixed ceramics. In order to verify the numerous bibliographical data, systematic solubility measurements in aqueous medium under atmospheric pressure and a critical evaluation have been undertaken. By taking solvation phenomena into account, it has proved possible to correlate all the phenomena observed, to obtain equations representative of the liquidus curves, and to refine and extrapolate the experimental curves. The whole stable and metastable coordinates of the invariant transformations in both binary systems have been calculated or more accurately determined.
C02 01  X    @0 001C01C04
C03 01  X  FRE  @0 Solvatation @5 01
C03 01  X  ENG  @0 Solvation @5 01
C03 01  X  SPA  @0 Solvatación @5 01
C03 02  X  FRE  @0 Equilibre liquide solide @5 02
C03 02  X  ENG  @0 Liquid solid equilibrium @5 02
C03 02  X  SPA  @0 Equilibrio líquido sólido @5 02
C03 03  X  FRE  @0 Solution aqueuse @5 03
C03 03  X  ENG  @0 Aqueous solution @5 03
C03 03  X  SPA  @0 Solución acuosa @5 03
C03 04  X  FRE  @0 Précurseur @5 04
C03 04  X  ENG  @0 Precursor @5 04
C03 04  X  SPA  @0 Precursor @5 04
C03 05  X  FRE  @0 Hydrate @2 NA @5 05
C03 05  X  ENG  @0 Hydrates @2 NA @5 05
C03 05  X  SPA  @0 Hidrato @2 NA @5 05
C03 06  X  FRE  @0 Métal transition Composé @2 NC @2 NA @5 06
C03 06  X  ENG  @0 Transition metal Compounds @2 NC @2 NA @5 06
C03 06  X  SPA  @0 Metal transición Compuesto @2 NC @2 NA @5 06
C03 07  X  FRE  @0 Nickel Nitrate @2 NC @2 FX @2 NA @5 07
C03 07  X  ENG  @0 Nickel Nitrates @2 NC @2 FX @2 NA @5 07
C03 07  X  SPA  @0 Niquel Nitrato @2 NC @2 FX @2 NA @5 07
C03 08  X  FRE  @0 Cobalt Nitrate @2 NC @2 NA @2 FX @5 08
C03 08  X  ENG  @0 Cobalt Nitrates @2 NC @2 NA @2 FX @5 08
C03 08  X  SPA  @0 Cobalto Nitrato @2 NC @2 NA @2 FX @5 08
C03 09  X  FRE  @0 Diagramme phase @5 09
C03 09  X  ENG  @0 Phase diagram @5 09
C03 09  X  SPA  @0 Diagrama fase @5 09
C03 10  X  FRE  @0 Equilibre phase @5 32
C03 10  X  ENG  @0 Phase equilibrium @5 32
C03 10  X  SPA  @0 Equilibrio fase @5 32
C03 11  X  FRE  @0 Oxyde mixte @4 INC @5 76
N21       @1 273
pR  
A30 01  1  FRE  @1 Edition of the Journées d'Etude des Equilibres entre phases @3 Rouen FRA @4 2012-03-28

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Le document en format XML

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<term>Nickel Nitrates</term>
<term>Phase diagram</term>
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<term>Solvation</term>
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<term>Hydrate</term>
<term>Métal transition Composé</term>
<term>Nickel Nitrate</term>
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<div type="abstract" xml:lang="en">The hydrates of cobalt and nickel nitrates are highly relevant as precursors for the preparation of mixed ceramics. In order to verify the numerous bibliographical data, systematic solubility measurements in aqueous medium under atmospheric pressure and a critical evaluation have been undertaken. By taking solvation phenomena into account, it has proved possible to correlate all the phenomena observed, to obtain equations representative of the liquidus curves, and to refine and extrapolate the experimental curves. The whole stable and metastable coordinates of the invariant transformations in both binary systems have been calculated or more accurately determined.</div>
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<s0>The hydrates of cobalt and nickel nitrates are highly relevant as precursors for the preparation of mixed ceramics. In order to verify the numerous bibliographical data, systematic solubility measurements in aqueous medium under atmospheric pressure and a critical evaluation have been undertaken. By taking solvation phenomena into account, it has proved possible to correlate all the phenomena observed, to obtain equations representative of the liquidus curves, and to refine and extrapolate the experimental curves. The whole stable and metastable coordinates of the invariant transformations in both binary systems have been calculated or more accurately determined.</s0>
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<fC02 i1="01" i2="X">
<s0>001C01C04</s0>
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<s0>Solvatation</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG">
<s0>Solvation</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA">
<s0>Solvatación</s0>
<s5>01</s5>
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<fC03 i1="02" i2="X" l="FRE">
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<s5>02</s5>
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<fC03 i1="02" i2="X" l="ENG">
<s0>Liquid solid equilibrium</s0>
<s5>02</s5>
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<s0>Equilibrio líquido sólido</s0>
<s5>02</s5>
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<fC03 i1="03" i2="X" l="FRE">
<s0>Solution aqueuse</s0>
<s5>03</s5>
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<fC03 i1="03" i2="X" l="ENG">
<s0>Aqueous solution</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Solución acuosa</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Précurseur</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Precursor</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Precursor</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Hydrate</s0>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Hydrates</s0>
<s2>NA</s2>
<s5>05</s5>
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<fC03 i1="05" i2="X" l="SPA">
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<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Métal transition Composé</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Transition metal Compounds</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
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<fC03 i1="06" i2="X" l="SPA">
<s0>Metal transición Compuesto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
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<fC03 i1="07" i2="X" l="FRE">
<s0>Nickel Nitrate</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Nickel Nitrates</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Niquel Nitrato</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Cobalt Nitrate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s2>FX</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Cobalt Nitrates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s2>FX</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Cobalto Nitrato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s2>FX</s2>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Diagramme phase</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Phase diagram</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Diagrama fase</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Equilibre phase</s0>
<s5>32</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Phase equilibrium</s0>
<s5>32</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Equilibrio fase</s0>
<s5>32</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Oxyde mixte</s0>
<s4>INC</s4>
<s5>76</s5>
</fC03>
<fN21>
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<s1>Edition of the Journées d'Etude des Equilibres entre phases</s1>
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