Terpenic olefin epoxidation using metals acetylacetonates as catalysts
Identifieur interne : 000204 ( Maroc/Analysis ); précédent : 000203; suivant : 000205Terpenic olefin epoxidation using metals acetylacetonates as catalysts
Auteurs : Naima Fdil [Maroc] ; Abderrahmane Romane [Maroc] ; Smail Allaoud [Maroc] ; Abdallah Karim [Maroc] ; Yves Castanet [France] ; André Mortreux [France]Source :
- Journal of Molecular Catalysis A: Chemical [ 1381-1169 ] ; 1996.
Abstract
Efficient epoxidation of natural terpenic olefins is performed using nickel acetylacetonate, oxygen and a branched aldehyde at ambient temperature. Total conversions are achieved with selectivities up to 90% into epoxide. Under the same conditions other catalytic systems using transition metal acetylacetonates (Mn(acac)n) have been used, some of which also gave satisfactory results.
Url:
DOI: 10.1016/1381-1169(95)00284-7
Affiliations:
- France, Maroc
- Hauts-de-France, Marrakech-Tensift-Al Haouz, Nord-Pas-de-Calais
- Marrakech, Villeneuve D'Ascq
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000998
- to stream Istex, to step Curation: 000620
- to stream Istex, to step Checkpoint: 000822
- to stream Main, to step Merge: 001020
- to stream Main, to step Curation: 000F81
- to stream Main, to step Exploration: 000F81
- to stream Maroc, to step Extraction: 000204
Links to Exploration step
ISTEX:2CCC00693B144E4B2A3B4295A723045BBB2711C1Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Terpenic olefin epoxidation using metals acetylacetonates as catalysts</title><author><name sortKey="Fdil, Naima" sort="Fdil, Naima" uniqKey="Fdil N" first="Naima" last="Fdil">Naima Fdil</name></author><author><name sortKey="Romane, Abderrahmane" sort="Romane, Abderrahmane" uniqKey="Romane A" first="Abderrahmane" last="Romane">Abderrahmane Romane</name></author><author><name sortKey="Allaoud, Smail" sort="Allaoud, Smail" uniqKey="Allaoud S" first="Smail" last="Allaoud">Smail Allaoud</name></author><author><name sortKey="Karim, Abdallah" sort="Karim, Abdallah" uniqKey="Karim A" first="Abdallah" last="Karim">Abdallah Karim</name></author><author><name sortKey="Castanet, Yves" sort="Castanet, Yves" uniqKey="Castanet Y" first="Yves" last="Castanet">Yves Castanet</name></author><author><name sortKey="Mortreux, Andre" sort="Mortreux, Andre" uniqKey="Mortreux A" first="André" last="Mortreux">André Mortreux</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:2CCC00693B144E4B2A3B4295A723045BBB2711C1</idno><date when="1996" year="1996">1996</date><idno type="doi">10.1016/1381-1169(95)00284-7</idno><idno type="url">https://api.istex.fr/document/2CCC00693B144E4B2A3B4295A723045BBB2711C1/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">000998</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000998</idno><idno type="wicri:Area/Istex/Curation">000620</idno><idno type="wicri:Area/Istex/Checkpoint">000822</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000822</idno><idno type="wicri:doubleKey">1381-1169:1996:Fdil N:terpenic:olefin:epoxidation</idno><idno type="wicri:Area/Main/Merge">001020</idno><idno type="wicri:Area/Main/Curation">000F81</idno><idno type="wicri:Area/Main/Exploration">000F81</idno><idno type="wicri:Area/Maroc/Extraction">000204</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a">Terpenic olefin epoxidation using metals acetylacetonates as catalysts</title><author><name sortKey="Fdil, Naima" sort="Fdil, Naima" uniqKey="Fdil N" first="Naima" last="Fdil">Naima Fdil</name><affiliation wicri:level="3"><country xml:lang="fr">Maroc</country><wicri:regionArea>Laboratoire de Chimie de Coordination, Faculté des Sciences Semlalia, Université Cadi Ayyad, BP S15, Marrakech</wicri:regionArea><placeName><settlement type="city">Marrakech</settlement><region nuts="2">Marrakech-Tensift-Al Haouz</region></placeName></affiliation></author><author><name sortKey="Romane, Abderrahmane" sort="Romane, Abderrahmane" uniqKey="Romane A" first="Abderrahmane" last="Romane">Abderrahmane Romane</name><affiliation wicri:level="3"><country xml:lang="fr">Maroc</country><wicri:regionArea>Laboratoire de Chimie de Coordination, Faculté des Sciences Semlalia, Université Cadi Ayyad, BP S15, Marrakech</wicri:regionArea><placeName><settlement type="city">Marrakech</settlement><region nuts="2">Marrakech-Tensift-Al Haouz</region></placeName></affiliation></author><author><name sortKey="Allaoud, Smail" sort="Allaoud, Smail" uniqKey="Allaoud S" first="Smail" last="Allaoud">Smail Allaoud</name><affiliation wicri:level="3"><country xml:lang="fr">Maroc</country><wicri:regionArea>Laboratoire de Chimie de Coordination, Faculté des Sciences Semlalia, Université Cadi Ayyad, BP S15, Marrakech</wicri:regionArea><placeName><settlement type="city">Marrakech</settlement><region nuts="2">Marrakech-Tensift-Al Haouz</region></placeName></affiliation></author><author><name sortKey="Karim, Abdallah" sort="Karim, Abdallah" uniqKey="Karim A" first="Abdallah" last="Karim">Abdallah Karim</name><affiliation></affiliation><affiliation wicri:level="3"><country xml:lang="fr">Maroc</country><wicri:regionArea>Laboratoire de Chimie de Coordination, Faculté des Sciences Semlalia, Université Cadi Ayyad, BP S15, Marrakech</wicri:regionArea><placeName><settlement type="city">Marrakech</settlement><region nuts="2">Marrakech-Tensift-Al Haouz</region></placeName></affiliation></author><author><name sortKey="Castanet, Yves" sort="Castanet, Yves" uniqKey="Castanet Y" first="Yves" last="Castanet">Yves Castanet</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Catalyse Hétérogène et Homogène, URA CNRS 402, ENSC LILLE, BP 108, 59652 Villeneuve D'Ascq cedex</wicri:regionArea><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve D'Ascq</settlement></placeName></affiliation></author><author><name sortKey="Mortreux, Andre" sort="Mortreux, Andre" uniqKey="Mortreux A" first="André" last="Mortreux">André Mortreux</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Catalyse Hétérogène et Homogène, URA CNRS 402, ENSC LILLE, BP 108, 59652 Villeneuve D'Ascq cedex</wicri:regionArea><placeName><region type="region" nuts="2">Hauts-de-France</region><region type="old region" nuts="2">Nord-Pas-de-Calais</region><settlement type="city">Villeneuve D'Ascq</settlement></placeName></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Molecular Catalysis A: Chemical</title><title level="j" type="abbrev">MOLCAA</title><idno type="ISSN">1381-1169</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1996">1996</date><biblScope unit="volume">108</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="15">15</biblScope><biblScope unit="page" to="21">21</biblScope></imprint><idno type="ISSN">1381-1169</idno></series><idno type="istex">2CCC00693B144E4B2A3B4295A723045BBB2711C1</idno><idno type="DOI">10.1016/1381-1169(95)00284-7</idno><idno type="PII">1381-1169(95)00284-7</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1381-1169</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Efficient epoxidation of natural terpenic olefins is performed using nickel acetylacetonate, oxygen and a branched aldehyde at ambient temperature. Total conversions are achieved with selectivities up to 90% into epoxide. Under the same conditions other catalytic systems using transition metal acetylacetonates (Mn(acac)n) have been used, some of which also gave satisfactory results.</div></front></TEI><affiliations><list><country><li>France</li><li>Maroc</li></country><region><li>Hauts-de-France</li><li>Marrakech-Tensift-Al Haouz</li><li>Nord-Pas-de-Calais</li></region><settlement><li>Marrakech</li><li>Villeneuve D'Ascq</li></settlement></list><tree><country name="Maroc"><region name="Marrakech-Tensift-Al Haouz"><name sortKey="Fdil, Naima" sort="Fdil, Naima" uniqKey="Fdil N" first="Naima" last="Fdil">Naima Fdil</name></region><name sortKey="Allaoud, Smail" sort="Allaoud, Smail" uniqKey="Allaoud S" first="Smail" last="Allaoud">Smail Allaoud</name><name sortKey="Karim, Abdallah" sort="Karim, Abdallah" uniqKey="Karim A" first="Abdallah" last="Karim">Abdallah Karim</name><name sortKey="Romane, Abderrahmane" sort="Romane, Abderrahmane" uniqKey="Romane A" first="Abderrahmane" last="Romane">Abderrahmane Romane</name></country><country name="France"><region name="Hauts-de-France"><name sortKey="Castanet, Yves" sort="Castanet, Yves" uniqKey="Castanet Y" first="Yves" last="Castanet">Yves Castanet</name></region><name sortKey="Mortreux, Andre" sort="Mortreux, Andre" uniqKey="Mortreux A" first="André" last="Mortreux">André Mortreux</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Maroc/Analysis
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000204 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Maroc/Analysis/biblio.hfd -nk 000204 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= CobaltMaghrebV1
|flux= Maroc
|étape= Analysis
|type= RBID
|clé= ISTEX:2CCC00693B144E4B2A3B4295A723045BBB2711C1
|texte= Terpenic olefin epoxidation using metals acetylacetonates as catalysts
}}
| This area was generated with Dilib version V0.6.32. |  |