Terpenic olefin epoxidation using metals acetylacetonates as catalysts
Identifieur interne : 000998 ( Istex/Corpus ); précédent : 000997; suivant : 000999Terpenic olefin epoxidation using metals acetylacetonates as catalysts
Auteurs : Naima Fdil ; Abderrahmane Romane ; Smail Allaoud ; Abdallah Karim ; Yves Castanet ; André MortreuxSource :
- Journal of Molecular Catalysis A: Chemical [ 1381-1169 ] ; 1996.
Abstract
Efficient epoxidation of natural terpenic olefins is performed using nickel acetylacetonate, oxygen and a branched aldehyde at ambient temperature. Total conversions are achieved with selectivities up to 90% into epoxide. Under the same conditions other catalytic systems using transition metal acetylacetonates (Mn(acac)n) have been used, some of which also gave satisfactory results.
Url:
DOI: 10.1016/1381-1169(95)00284-7
Links to Exploration step
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<ce:abstract-sec><ce:simple-para>Efficient epoxidation of natural terpenic olefins is performed using nickel acetylacetonate, oxygen and a branched aldehyde at ambient temperature. Total conversions are achieved with selectivities up to 90% into epoxide. Under the same conditions other catalytic systems using transition metal acetylacetonates (M<ce:sup><ce:italic>n</ce:italic>
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<ce:keyword><ce:text>Nickel</ce:text>
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<ce:keyword><ce:text>Transition metals</ce:text>
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<ce:keyword><ce:text>Terpenic olefins</ce:text>
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<namePart type="family">Castanet</namePart>
<affiliation>Laboratoire de Catalyse Hétérogène et Homogène, URA CNRS 402, ENSC LILLE, BP 108, 59652 Villeneuve D'Ascq cedex, France</affiliation>
<role><roleTerm type="text">author</roleTerm>
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</name>
<name type="personal"><namePart type="given">André</namePart>
<namePart type="family">Mortreux</namePart>
<affiliation>Laboratoire de Catalyse Hétérogène et Homogène, URA CNRS 402, ENSC LILLE, BP 108, 59652 Villeneuve D'Ascq cedex, France</affiliation>
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<originInfo><publisher>ELSEVIER</publisher>
<dateIssued encoding="w3cdtf">1996</dateIssued>
<copyrightDate encoding="w3cdtf">1996</copyrightDate>
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<language><languageTerm type="code" authority="iso639-2b">eng</languageTerm>
<languageTerm type="code" authority="rfc3066">en</languageTerm>
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<abstract lang="en">Efficient epoxidation of natural terpenic olefins is performed using nickel acetylacetonate, oxygen and a branched aldehyde at ambient temperature. Total conversions are achieved with selectivities up to 90% into epoxide. Under the same conditions other catalytic systems using transition metal acetylacetonates (Mn(acac)n) have been used, some of which also gave satisfactory results.</abstract>
<note type="content">Section title: Article</note>
<subject><genre>article-category</genre>
<topic>Chemical and metal catalysis</topic>
</subject>
<subject><genre>Keywords</genre>
<topic>Epoxidation</topic>
<topic>Nickel</topic>
<topic>Acetylacetonate</topic>
<topic>Transition metals</topic>
<topic>Terpenic olefins</topic>
<topic>Oxygen</topic>
</subject>
<relatedItem type="host"><titleInfo><title>Journal of Molecular Catalysis A: Chemical</title>
</titleInfo>
<titleInfo type="abbreviated"><title>MOLCAA</title>
</titleInfo>
<genre type="journal">journal</genre>
<originInfo><dateIssued encoding="w3cdtf">19960425</dateIssued>
</originInfo>
<identifier type="ISSN">1381-1169</identifier>
<identifier type="PII">S1381-1169(00)X0008-8</identifier>
<part><date>19960425</date>
<detail type="volume"><number>108</number>
<caption>vol.</caption>
</detail>
<detail type="issue"><number>1</number>
<caption>no.</caption>
</detail>
<extent unit="issue pages"><start>L1</start>
<end>L3</end>
</extent>
<extent unit="issue pages"><start>5</start>
<end>50</end>
</extent>
<extent unit="pages"><start>15</start>
<end>21</end>
</extent>
</part>
</relatedItem>
<identifier type="istex">2CCC00693B144E4B2A3B4295A723045BBB2711C1</identifier>
<identifier type="DOI">10.1016/1381-1169(95)00284-7</identifier>
<identifier type="PII">1381-1169(95)00284-7</identifier>
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