Na2Co(H2PO4)4·4H2O
Identifieur interne : 000D01 ( Main/Exploration ); précédent : 000D00; suivant : 000D02Na2Co(H2PO4)4·4H2O
Auteurs : Abderrahmen Guesmi [Tunisie] ; Mohamed Faouzi Zid [Tunisie] ; Ahmed Driss [Tunisie]Source :
- Acta Crystallographica Section C [ 0108-2701 ] ; 2000-05.
Abstract
In the title compound, disodium cobalt tetrakis(dihydrogenphosphate) tetrahydrate, the CoII ion lies on an inversion centre and is octahedrally surrounded by two water molecules and four H2PO4 groups to give a cobalt complex anion of the form [Co(H2PO4)4(OH2)]2−. The three‐dimensional framework results from hydrogen bonding between the anions. The relationship with the structures of Co(H2PO4)2·2H2O and K2CoP4O12·5H2O is discussed.
Url:
DOI: 10.1107/S0108270199015279
Affiliations:
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- to stream Istex, to step Checkpoint: 000609
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- to stream Main, to step Curation: 000D01
Le document en format XML
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<front><div type="abstract" xml:lang="en">In the title compound, disodium cobalt tetrakis(dihydrogenphosphate) tetrahydrate, the CoII ion lies on an inversion centre and is octahedrally surrounded by two water molecules and four H2PO4 groups to give a cobalt complex anion of the form [Co(H2PO4)4(OH2)]2−. The three‐dimensional framework results from hydrogen bonding between the anions. The relationship with the structures of Co(H2PO4)2·2H2O and K2CoP4O12·5H2O is discussed.</div>
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