Na2Co(H2PO4)4·4H2O
Identifieur interne : 000429 ( Istex/Corpus ); précédent : 000428; suivant : 000430Na2Co(H2PO4)4·4H2O
Auteurs : Abderrahmen Guesmi ; Mohamed Faouzi Zid ; Ahmed DrissSource :
- Acta Crystallographica Section C [ 0108-2701 ] ; 2000-05.
Abstract
In the title compound, disodium cobalt tetrakis(dihydrogenphosphate) tetrahydrate, the CoII ion lies on an inversion centre and is octahedrally surrounded by two water molecules and four H2PO4 groups to give a cobalt complex anion of the form [Co(H2PO4)4(OH2)]2−. The three‐dimensional framework results from hydrogen bonding between the anions. The relationship with the structures of Co(H2PO4)2·2H2O and K2CoP4O12·5H2O is discussed.
Url:
DOI: 10.1107/S0108270199015279
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<front><div type="abstract" xml:lang="en">In the title compound, disodium cobalt tetrakis(dihydrogenphosphate) tetrahydrate, the CoII ion lies on an inversion centre and is octahedrally surrounded by two water molecules and four H2PO4 groups to give a cobalt complex anion of the form [Co(H2PO4)4(OH2)]2−. The three‐dimensional framework results from hydrogen bonding between the anions. The relationship with the structures of Co(H2PO4)2·2H2O and K2CoP4O12·5H2O is discussed.</div>
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<titleGroup><title type="main">Na<sub>2</sub>
Co(H<sub>2</sub>
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Co(H<sub>2</sub>
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<abstractGroup><abstract type="main" xml:lang="en"><p>In the title compound, disodium cobalt tetrakis(dihydrogenphosphate) tetrahydrate, the Co<sup>II</sup>
ion lies on an inversion centre and is octahedrally surrounded by two water molecules and four H<sub>2</sub>
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<abstract lang="en">In the title compound, disodium cobalt tetrakis(dihydrogenphosphate) tetrahydrate, the CoII ion lies on an inversion centre and is octahedrally surrounded by two water molecules and four H2PO4 groups to give a cobalt complex anion of the form [Co(H2PO4)4(OH2)]2−. The three‐dimensional framework results from hydrogen bonding between the anions. The relationship with the structures of Co(H2PO4)2·2H2O and K2CoP4O12·5H2O is discussed.</abstract>
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