CobaltMaghrebV1, Main, Exploration, bibRecord, 000664

Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)

Identifieur interne : 000664 ( Main/Exploration ); précédent : 000663; suivant : 000665

Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)

Auteurs : Ahmed Selmi [Tunisie] ; Samah Akriche [Tunisie] ; Mohamed Rzaigui [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2009.

RBID : PMC:2971134

Abstract

In the title cobalt(II) complex with 2-methylanilinium and diphosphate, (C₇H₁₀N)₂[Co(H₂P₂O₇)₂(H₂O)₂], a three-dimensional network is built up from anionic layers of [Co(H₂P₂O₇)₂(H₂O)₂]²⁻ units and 2-methylanilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co²⁺ ions lie on inversion centers. An intricate network of O—H⋯O and N—H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other interactions, being of electrostatic and van der Waals nature.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971134

DOI: 10.1107/S1600536809044079
PubMed: 21578209
PubMed Central: 2971134

Affiliations:

Tunisie

Le document en format XML

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P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
]<sup>2−</sup>
 units and 2-methylanilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co<sup>2+</sup>
 ions lie on inversion centers. An intricate network of O—H⋯O and N—H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other interactions, being of electrostatic and van der Waals nature.</p>
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Serveur d'exploration sur le cobalt au Maghreb

Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)

Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)

Source :

Abstract

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)

Bis(2-methyl­anilinium) diaqua­bis[dihydrogendiphosphato(2−)]cobaltate(II)

Source :

Abstract

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Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)

Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)