Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)
Identifieur interne : 000334 ( Pmc/Checkpoint ); précédent : 000333; suivant : 000335Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)
Auteurs : Ahmed Selmi [Tunisie] ; Samah Akriche [Tunisie] ; Mohamed Rzaigui [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2009.
Abstract
In the title cobalt(II) complex with 2-methylanilinium and diphosphate, (C7H10N)2[Co(H2P2O7)2(H2O)2], a three-dimensional network is built up from anionic layers of [Co(H2P2O7)2(H2O)2]2− units and 2-methylanilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co2+ ions lie on inversion centers. An intricate network of O—H⋯O and N—H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other interactions, being of electrostatic and van der Waals nature.
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DOI: 10.1107/S1600536809044079
PubMed: 21578209
PubMed Central: 2971134
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<author><name sortKey="Selmi, Ahmed" sort="Selmi, Ahmed" uniqKey="Selmi A" first="Ahmed" last="Selmi">Ahmed Selmi</name>
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<author><name sortKey="Akriche, Samah" sort="Akriche, Samah" uniqKey="Akriche S" first="Samah" last="Akriche">Samah Akriche</name>
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<author><name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)</title>
<author><name sortKey="Selmi, Ahmed" sort="Selmi, Ahmed" uniqKey="Selmi A" first="Ahmed" last="Selmi">Ahmed Selmi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Akriche, Samah" sort="Akriche, Samah" uniqKey="Akriche S" first="Samah" last="Akriche">Samah Akriche</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2009">2009</date>
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<front><div type="abstract" xml:lang="en"><p>In the title cobalt(II) complex with 2-methylanilinium and diphosphate, (C<sub>7</sub>
H<sub>10</sub>
N)<sub>2</sub>
[Co(H<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
], a three-dimensional network is built up from anionic layers of [Co(H<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
]<sup>2−</sup>
units and 2-methylanilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co<sup>2+</sup>
ions lie on inversion centers. An intricate network of O—H⋯O and N—H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other interactions, being of electrostatic and van der Waals nature.</p>
</div>
</front>
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<biblStruct></biblStruct>
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<biblStruct></biblStruct>
<biblStruct></biblStruct>
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<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title>
</journal-title-group>
<issn pub-type="epub">1600-5368</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
</journal-meta>
<article-meta><article-id pub-id-type="pmid">21578209</article-id>
<article-id pub-id-type="pmc">2971134</article-id>
<article-id pub-id-type="publisher-id">fl2278</article-id>
<article-id pub-id-type="doi">10.1107/S1600536809044079</article-id>
<article-id pub-id-type="coden">ACSEBH</article-id>
<article-id pub-id-type="pii">S1600536809044079</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Metal-Organic Papers</subject>
</subj-group>
</article-categories>
<title-group><article-title>Bis(2-methylanilinium) diaquabis[dihydrogendiphosphato(2−)]cobaltate(II)</article-title>
<alt-title><italic>(C<sub>7</sub>
H<sub>10</sub>
N)<sub>2</sub>
[Co(H<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
]</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Selmi</surname>
<given-names>Ahmed</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Akriche</surname>
<given-names>Samah</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Rzaigui</surname>
<given-names>Mohamed</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<aff id="a"><label>a</label>
Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>ahmedselmi09@yahoo.fr</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>11</month>
<year>2009</year>
</pub-date>
<pub-date pub-type="epub"><day>31</day>
<month>10</month>
<year>2009</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>31</day>
<month>10</month>
<year>2009</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
. </pmc-comment>
<volume>65</volume>
<issue>Pt 11</issue>
<issue-id pub-id-type="publisher-id">e091100</issue-id>
<fpage>m1487</fpage>
<lpage>m1487</lpage>
<history><date date-type="received"><day>07</day>
<month>10</month>
<year>2009</year>
</date>
<date date-type="accepted"><day>23</day>
<month>10</month>
<year>2009</year>
</date>
</history>
<permissions><copyright-statement>© Selmi et al. 2009</copyright-statement>
<copyright-year>2009</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536809044079">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract><p>In the title cobalt(II) complex with 2-methylanilinium and diphosphate, (C<sub>7</sub>
H<sub>10</sub>
N)<sub>2</sub>
[Co(H<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
], a three-dimensional network is built up from anionic layers of [Co(H<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
]<sup>2−</sup>
units and 2-methylanilinium cations located between these layers. The dihydrogendiphosphate groups present a bent eclipsed conformation, while the Co<sup>2+</sup>
ions lie on inversion centers. An intricate network of O—H⋯O and N—H⋯O hydrogen bonds is established between the different components, assuring the cohesion of the network with other interactions, being of electrostatic and van der Waals nature.</p>
</abstract>
</article-meta>
</front>
<floats-group><table-wrap id="table1" position="float"><label>Table 1</label>
<caption><title>Hydrogen-bond geometry (Å, °)</title>
</caption>
<table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
</tr>
</thead>
<tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O6—H6⋯O3<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.82</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.75</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.5712 (17)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">177</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O2—H2⋯O7<sup>ii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.82</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.71</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.522 (2)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">169</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O8—H2<italic>W</italic>
⋯O2<sup>iii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.842 (9)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.978 (10)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.8199 (18)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">179 (3)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O8—H1<italic>W</italic>
⋯O4<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.842 (9)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.202 (13)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.020 (2)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">164 (3)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">N1—H1<italic>A</italic>
⋯O7<sup>iii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.89</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.89</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.7788 (18)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">177</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">N1—H1<italic>B</italic>
⋯O5</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.89</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.31</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.0083 (19)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">135</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">N1—H1<italic>B</italic>
⋯O1<sup>iv</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.89</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.48</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.105 (2)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">127</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">N1—H1<italic>C</italic>
⋯O3<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.89</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.94</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.821 (2)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">168</td>
</tr>
</tbody>
</table>
<table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-65-m1487-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (ii) <inline-formula><inline-graphic xlink:href="e-65-m1487-efi3.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iii) <inline-formula><inline-graphic xlink:href="e-65-m1487-efi4.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iv) <inline-formula><inline-graphic xlink:href="e-65-m1487-efi5.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
.</p>
</table-wrap-foot>
</table-wrap>
</floats-group>
</pmc>
<affiliations><list><country><li>Tunisie</li>
</country>
</list>
<tree><country name="Tunisie"><noRegion><name sortKey="Selmi, Ahmed" sort="Selmi, Ahmed" uniqKey="Selmi A" first="Ahmed" last="Selmi">Ahmed Selmi</name>
</noRegion>
<name sortKey="Akriche, Samah" sort="Akriche, Samah" uniqKey="Akriche S" first="Samah" last="Akriche">Samah Akriche</name>
<name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name>
</country>
</tree>
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