Inorganic perchlorato complexes
Identifieur interne : 000D22 ( Istex/Curation ); précédent : 000D21; suivant : 000D23Inorganic perchlorato complexes
Auteurs : Jean-Louis Pascal [France] ; Frédéric Favier [France]Source :
- Coordination Chemistry Reviews [ 0010-8545 ] ; 1998.
Abstract
A summary is given of the synthesis of non-solvated inorganic perchlorato complexes and their structural characterization. The synthesis of perchlorato complexes has been extended to many elements of the periodic table by the use of efficient perchlorating reagents such as perchloric acid, HClO4–Cl2O7 oleums and chlorine trioxide, Cl2O6. X-ray diffraction, EXAFS and vibrational spectroscopy show that the perchlorato ligand, [ClO4], can be strongly bonded to metals in various bonding arrangements: monodentate, bridging or chelating bidentate, simply bridging or simultaneously bridging and chelating tridentate. It is mostly an assembling ligand.
Url:
DOI: 10.1016/S0010-8545(98)00102-7
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<front><div type="abstract" xml:lang="en">A summary is given of the synthesis of non-solvated inorganic perchlorato complexes and their structural characterization. The synthesis of perchlorato complexes has been extended to many elements of the periodic table by the use of efficient perchlorating reagents such as perchloric acid, HClO4–Cl2O7 oleums and chlorine trioxide, Cl2O6. X-ray diffraction, EXAFS and vibrational spectroscopy show that the perchlorato ligand, [ClO4], can be strongly bonded to metals in various bonding arrangements: monodentate, bridging or chelating bidentate, simply bridging or simultaneously bridging and chelating tridentate. It is mostly an assembling ligand.</div>
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