Effect of cations on the diffusivity of the charge carriers in polyaniline membranes
Identifieur interne : 000F18 ( Istex/Corpus ); précédent : 000F17; suivant : 000F19Effect of cations on the diffusivity of the charge carriers in polyaniline membranes
Auteurs : C. Deslouis ; T. El Moustafid ; M. M. Musiani ; M. E. Orazem ; V. Provost ; B. TribolletSource :
- Electrochimica Acta [ 0013-4686 ] ; 1999.
Abstract
The bulk and interfacial transport properties of PANI free-standing membranes have been investigated in acidic media with chloride as common counter-ion and with different co-ions, using the a.c. impedance technique with a four-electrode cell. The experimental data were compared to a recently proposed theoretical expression, based on use of the Nernst–Planck equation for mass transport and on slow discharge for ionic interfacial transfer. Though the only transport properties addressed in this model are the counter-ion and the polaron mobilities, experiments show an influence of the co-ion. In the case of multiple charge cations, especially Zn2+, all mobilities are strongly reduced.
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DOI: 10.1016/S0013-4686(98)00316-8
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Musiani</name><affiliation><mods:affiliation>IPELP del CNR, Corso Stati Uniti 4, 35127 Padova, Italy</mods:affiliation></affiliation></author><author><name sortKey="Orazem, M E" sort="Orazem, M E" uniqKey="Orazem M" first="M. E." last="Orazem">M. E. Orazem</name><affiliation><mods:affiliation>Department of Chemical Engineering, University of Florida, P.O. Box 116005, Gainsville, FL 32611-2021, USA</mods:affiliation></affiliation></author><author><name sortKey="Provost, V" sort="Provost, V" uniqKey="Provost V" first="V." last="Provost">V. Provost</name><affiliation><mods:affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</mods:affiliation></affiliation></author><author><name sortKey="Tribollet, B" sort="Tribollet, B" uniqKey="Tribollet B" first="B." last="Tribollet">B. Tribollet</name><affiliation><mods:affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. 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Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</mods:affiliation></affiliation><affiliation><mods:affiliation>Corresponding author</mods:affiliation></affiliation></author><author><name sortKey="Moustafid, T El" sort="Moustafid, T El" uniqKey="Moustafid T" first="T. El" last="Moustafid">T. El Moustafid</name><affiliation><mods:affiliation>UniversitéCadi Ayyad, Semlalia, rue de Safi, Marrakech, Morocco</mods:affiliation></affiliation></author><author><name sortKey="Musiani, M M" sort="Musiani, M M" uniqKey="Musiani M" first="M. M." last="Musiani">M. M. Musiani</name><affiliation><mods:affiliation>IPELP del CNR, Corso Stati Uniti 4, 35127 Padova, Italy</mods:affiliation></affiliation></author><author><name sortKey="Orazem, M E" sort="Orazem, M E" uniqKey="Orazem M" first="M. E." last="Orazem">M. E. Orazem</name><affiliation><mods:affiliation>Department of Chemical Engineering, University of Florida, P.O. Box 116005, Gainsville, FL 32611-2021, USA</mods:affiliation></affiliation></author><author><name sortKey="Provost, V" sort="Provost, V" uniqKey="Provost V" first="V." last="Provost">V. Provost</name><affiliation><mods:affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</mods:affiliation></affiliation></author><author><name sortKey="Tribollet, B" sort="Tribollet, B" uniqKey="Tribollet B" first="B." last="Tribollet">B. Tribollet</name><affiliation><mods:affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Electrochimica Acta</title><title level="j" type="abbrev">EA</title><idno type="ISSN">0013-4686</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1999">1999</date><biblScope unit="volume">44</biblScope><biblScope unit="issue">12</biblScope><biblScope unit="page" from="2087">2087</biblScope><biblScope unit="page" to="2093">2093</biblScope></imprint><idno type="ISSN">0013-4686</idno></series><idno type="istex">5A3C549948F12B04E317B61E2A455B976D47D549</idno><idno type="DOI">10.1016/S0013-4686(98)00316-8</idno><idno type="PII">S0013-4686(98)00316-8</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0013-4686</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The bulk and interfacial transport properties of PANI free-standing membranes have been investigated in acidic media with chloride as common counter-ion and with different co-ions, using the a.c. impedance technique with a four-electrode cell. The experimental data were compared to a recently proposed theoretical expression, based on use of the Nernst–Planck equation for mass transport and on slow discharge for ionic interfacial transfer. Though the only transport properties addressed in this model are the counter-ion and the polaron mobilities, experiments show an influence of the co-ion. In the case of multiple charge cations, especially Zn2+, all mobilities are strongly reduced.</div></front></TEI><istex><corpusName>elsevier</corpusName><author><json:item><name>C. Deslouis</name><affiliations><json:string>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</json:string><json:string>Corresponding author</json:string></affiliations></json:item><json:item><name>T.El Moustafid</name><affiliations><json:string>UniversitéCadi Ayyad, Semlalia, rue de Safi, Marrakech, Morocco</json:string></affiliations></json:item><json:item><name>M.M. Musiani</name><affiliations><json:string>IPELP del CNR, Corso Stati Uniti 4, 35127 Padova, Italy</json:string></affiliations></json:item><json:item><name>M.E. Orazem</name><affiliations><json:string>Department of Chemical Engineering, University of Florida, P.O. Box 116005, Gainsville, FL 32611-2021, USA</json:string></affiliations></json:item><json:item><name>V. Provost</name><affiliations><json:string>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</json:string></affiliations></json:item><json:item><name>B. Tribollet</name><affiliations><json:string>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Polyaniline</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Membranes</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Impedance</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Mixed conductivity</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Charge transport</value></json:item></subject><language><json:string>eng</json:string></language><originalGenre><json:string>Full-length article</json:string></originalGenre><abstract>The bulk and interfacial transport properties of PANI free-standing membranes have been investigated in acidic media with chloride as common counter-ion and with different co-ions, using the a.c. impedance technique with a four-electrode cell. The experimental data were compared to a recently proposed theoretical expression, based on use of the Nernst–Planck equation for mass transport and on slow discharge for ionic interfacial transfer. Though the only transport properties addressed in this model are the counter-ion and the polaron mobilities, experiments show an influence of the co-ion. In the case of multiple charge cations, especially Zn2+, all mobilities are strongly reduced.</abstract><qualityIndicators><score>4.296</score><pdfVersion>1.2</pdfVersion><pdfPageSize>595 x 842 pts (A4)</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>5</keywordCount><abstractCharCount>690</abstractCharCount><pdfWordCount>3096</pdfWordCount><pdfCharCount>17670</pdfCharCount><pdfPageCount>7</pdfPageCount><abstractWordCount>100</abstractWordCount></qualityIndicators><title>Effect of cations on the diffusivity of the charge carriers in polyaniline membranes</title><pii><json:string>S0013-4686(98)00316-8</json:string></pii><genre><json:string>research-article</json:string></genre><host><volume>44</volume><pii><json:string>S0013-4686(00)X0075-8</json:string></pii><pages><last>2093</last><first>2087</first></pages><issn><json:string>0013-4686</json:string></issn><issue>12</issue><genre><json:string>journal</json:string></genre><language><json:string>unknown</json:string></language><title>Electrochimica Acta</title><publicationDate>1999</publicationDate></host><categories><wos><json:string>ELECTROCHEMISTRY</json:string></wos></categories><publicationDate>1999</publicationDate><copyrightDate>1999</copyrightDate><doi><json:string>10.1016/S0013-4686(98)00316-8</json:string></doi><id>5A3C549948F12B04E317B61E2A455B976D47D549</id><score>0.052074224</score><fulltext><json:item><original>true</original><mimetype>application/pdf</mimetype><extension>pdf</extension><uri>https://api.istex.fr/document/5A3C549948F12B04E317B61E2A455B976D47D549/fulltext/pdf</uri></json:item><json:item><original>false</original><mimetype>application/zip</mimetype><extension>zip</extension><uri>https://api.istex.fr/document/5A3C549948F12B04E317B61E2A455B976D47D549/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/5A3C549948F12B04E317B61E2A455B976D47D549/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a">Effect of cations on the diffusivity of the charge carriers in polyaniline membranes</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>ELSEVIER</publisher><availability><p>©1999 Elsevier Science Ltd</p></availability><date>1999</date></publicationStmt><notesStmt><note type="content">Fig. 1: a.c. Impedance diagram in Nyquist coordinates (imaginary vs real part) for a PANI membrane (thickness 39.8μm) immersed in a solution NaCl (1M)/HCl (pH1).</note><note type="content">Fig. 2: a.c. Impedance diagram in Nyquist coordinates (imaginary vs real part) for a PANI membrane (thickness 36.6μm) immersed in a solution NaCl (1M)/HCl (pH2).</note><note type="content">Fig. 3: a.c. Impedance diagram in Nyquist coordinates (imaginary vs real part) for a PANI membrane (thickness 42μm) immersed in a solution ZnCl2 (1M)/HCl (pH1).</note><note type="content">Fig. 4: a.c. Impedance diagram in Nyquist coordinates (imaginary vs real part) for a PANI membrane (thickness 34μm) immersed in a solution ZnnCl2 (1M)/HCl (pH2).</note><note type="content">Table 1: Fitted values of the parameters contained in Formulae (2)–(4) for PANI membranes dipped in solutions NaCl (1M)/HCl at different pH values. Area=0.2cm2</note><note type="content">Table 2: Fitted values of the parameters contained in Formulae (2)–(4) for PANI membranes dipped in chloride solutions with an adjusted pH of 1 (HCl) and various cations for a total concentration of 1M. Area=0.2cm2</note><note type="content">Table 3: Fitted values of the parameters contained in Formulae (2)–(4) for PANI membranes dipped in solutions ZnCl2 (1M)/HCl at different pH values. Area=0.2cm2</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a">Effect of cations on the diffusivity of the charge carriers in polyaniline membranes</title><author xml:id="author-1"><persName><forename type="first">C.</forename><surname>Deslouis</surname></persName><affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</affiliation><affiliation>Corresponding author</affiliation></author><author xml:id="author-2"><persName><forename type="first">T.El</forename><surname>Moustafid</surname></persName><affiliation>UniversitéCadi Ayyad, Semlalia, rue de Safi, Marrakech, Morocco</affiliation></author><author xml:id="author-3"><persName><forename type="first">M.M.</forename><surname>Musiani</surname></persName><affiliation>IPELP del CNR, Corso Stati Uniti 4, 35127 Padova, Italy</affiliation></author><author xml:id="author-4"><persName><forename type="first">M.E.</forename><surname>Orazem</surname></persName><affiliation>Department of Chemical Engineering, University of Florida, P.O. Box 116005, Gainsville, FL 32611-2021, USA</affiliation></author><author xml:id="author-5"><persName><forename type="first">V.</forename><surname>Provost</surname></persName><affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</affiliation></author><author xml:id="author-6"><persName><forename type="first">B.</forename><surname>Tribollet</surname></persName><affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</affiliation></author></analytic><monogr><title level="j">Electrochimica Acta</title><title level="j" type="abbrev">EA</title><idno type="pISSN">0013-4686</idno><idno type="PII">S0013-4686(00)X0075-8</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1999"></date><biblScope unit="volume">44</biblScope><biblScope unit="issue">12</biblScope><biblScope unit="page" from="2087">2087</biblScope><biblScope unit="page" to="2093">2093</biblScope></imprint></monogr><idno type="istex">5A3C549948F12B04E317B61E2A455B976D47D549</idno><idno type="DOI">10.1016/S0013-4686(98)00316-8</idno><idno type="PII">S0013-4686(98)00316-8</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>1999</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>The bulk and interfacial transport properties of PANI free-standing membranes have been investigated in acidic media with chloride as common counter-ion and with different co-ions, using the a.c. impedance technique with a four-electrode cell. The experimental data were compared to a recently proposed theoretical expression, based on use of the Nernst–Planck equation for mass transport and on slow discharge for ionic interfacial transfer. Though the only transport properties addressed in this model are the counter-ion and the polaron mobilities, experiments show an influence of the co-ion. In the case of multiple charge cations, especially Zn2+, all mobilities are strongly reduced.</p></abstract><textClass><keywords scheme="keyword"><list><head>Keywords</head><item><term>Polyaniline</term></item><item><term>Membranes</term></item><item><term>Impedance</term></item><item><term>Mixed conductivity</term></item><item><term>Charge transport</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="1999">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><original>false</original><mimetype>text/plain</mimetype><extension>txt</extension><uri>https://api.istex.fr/document/5A3C549948F12B04E317B61E2A455B976D47D549/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: ce:floats; body; tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"><istex:entity SYSTEM="gr1" NDATA="IMAGE" name="gr1"></istex:entity><istex:entity SYSTEM="gr2" NDATA="IMAGE" name="gr2"></istex:entity><istex:entity SYSTEM="gr3" NDATA="IMAGE" name="gr3"></istex:entity><istex:entity SYSTEM="gr4" NDATA="IMAGE" name="gr4"></istex:entity><istex:entity SYSTEM="fx1" NDATA="IMAGE" name="fx1"></istex:entity></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla"><item-info><jid>EA</jid><aid>2369</aid><ce:pii>S0013-4686(98)00316-8</ce:pii><ce:doi>10.1016/S0013-4686(98)00316-8</ce:doi><ce:copyright year="1999" type="full-transfer">Elsevier Science Ltd</ce:copyright></item-info><head><ce:title>Effect of cations on the diffusivity of the charge carriers in polyaniline membranes</ce:title><ce:author-group><ce:author><ce:given-name>C.</ce:given-name><ce:surname>Deslouis</ce:surname><ce:cross-ref refid="AFF1">a</ce:cross-ref><ce:cross-ref refid="CORR1">*</ce:cross-ref></ce:author><ce:author><ce:given-name>T.El</ce:given-name><ce:surname>Moustafid</ce:surname><ce:cross-ref refid="AFF2">b</ce:cross-ref></ce:author><ce:author><ce:given-name>M.M.</ce:given-name><ce:surname>Musiani</ce:surname><ce:cross-ref refid="AFF3">c</ce:cross-ref></ce:author><ce:author><ce:given-name>M.E.</ce:given-name><ce:surname>Orazem</ce:surname><ce:cross-ref refid="AFF4">d</ce:cross-ref></ce:author><ce:author><ce:given-name>V.</ce:given-name><ce:surname>Provost</ce:surname><ce:cross-ref refid="AFF1">a</ce:cross-ref></ce:author><ce:author><ce:given-name>B.</ce:given-name><ce:surname>Tribollet</ce:surname><ce:cross-ref refid="AFF1">a</ce:cross-ref></ce:author><ce:affiliation id="AFF1"><ce:label>a</ce:label><ce:textfn>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</ce:textfn></ce:affiliation><ce:affiliation id="AFF2"><ce:label>b</ce:label><ce:textfn>UniversitéCadi Ayyad, Semlalia, rue de Safi, Marrakech, Morocco</ce:textfn></ce:affiliation><ce:affiliation id="AFF3"><ce:label>c</ce:label><ce:textfn>IPELP del CNR, Corso Stati Uniti 4, 35127 Padova, Italy</ce:textfn></ce:affiliation><ce:affiliation id="AFF4"><ce:label>d</ce:label><ce:textfn>Department of Chemical Engineering, University of Florida, P.O. Box 116005, Gainsville, FL 32611-2021, USA</ce:textfn></ce:affiliation><ce:correspondence id="CORR1"><ce:label>*</ce:label><ce:text>Corresponding author</ce:text></ce:correspondence></ce:author-group><ce:date-received day="27" month="7" year="1998"></ce:date-received><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>The bulk and interfacial transport properties of PANI free-standing membranes have been investigated in acidic media with chloride as common counter-ion and with different co-ions, using the a.c. impedance technique with a four-electrode cell. The experimental data were compared to a recently proposed theoretical expression, based on use of the Nernst–Planck equation for mass transport and on slow discharge for ionic interfacial transfer. Though the only transport properties addressed in this model are the counter-ion and the polaron mobilities, experiments show an influence of the co-ion. In the case of multiple charge cations, especially Zn<ce:sup>2+</ce:sup>, all mobilities are strongly reduced.</ce:simple-para></ce:abstract-sec></ce:abstract><ce:keywords class="keyword"><ce:section-title>Keywords</ce:section-title><ce:keyword><ce:text>Polyaniline</ce:text></ce:keyword><ce:keyword><ce:text>Membranes</ce:text></ce:keyword><ce:keyword><ce:text>Impedance</ce:text></ce:keyword><ce:keyword><ce:text>Mixed conductivity</ce:text></ce:keyword><ce:keyword><ce:text>Charge transport</ce:text></ce:keyword></ce:keywords></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo><title>Effect of cations on the diffusivity of the charge carriers in polyaniline membranes</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Effect of cations on the diffusivity of the charge carriers in polyaniline membranes</title></titleInfo><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Deslouis</namePart><affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</affiliation><affiliation>Corresponding author</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">T.El</namePart><namePart type="family">Moustafid</namePart><affiliation>UniversitéCadi Ayyad, Semlalia, rue de Safi, Marrakech, Morocco</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.M.</namePart><namePart type="family">Musiani</namePart><affiliation>IPELP del CNR, Corso Stati Uniti 4, 35127 Padova, Italy</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.E.</namePart><namePart type="family">Orazem</namePart><affiliation>Department of Chemical Engineering, University of Florida, P.O. Box 116005, Gainsville, FL 32611-2021, USA</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">V.</namePart><namePart type="family">Provost</namePart><affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">B.</namePart><namePart type="family">Tribollet</namePart><affiliation>UPR 15 du CNRS-LPLE, UniversitéP. et M. Curie, T22 5ème étage 4 place Jussieu, 75252 Paris Cédex 05, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1999</dateIssued><copyrightDate encoding="w3cdtf">1999</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">The bulk and interfacial transport properties of PANI free-standing membranes have been investigated in acidic media with chloride as common counter-ion and with different co-ions, using the a.c. impedance technique with a four-electrode cell. The experimental data were compared to a recently proposed theoretical expression, based on use of the Nernst–Planck equation for mass transport and on slow discharge for ionic interfacial transfer. Though the only transport properties addressed in this model are the counter-ion and the polaron mobilities, experiments show an influence of the co-ion. In the case of multiple charge cations, especially Zn2+, all mobilities are strongly reduced.</abstract><note type="content">Fig. 1: a.c. Impedance diagram in Nyquist coordinates (imaginary vs real part) for a PANI membrane (thickness 39.8μm) immersed in a solution NaCl (1M)/HCl (pH1).</note><note type="content">Fig. 2: a.c. Impedance diagram in Nyquist coordinates (imaginary vs real part) for a PANI membrane (thickness 36.6μm) immersed in a solution NaCl (1M)/HCl (pH2).</note><note type="content">Fig. 3: a.c. Impedance diagram in Nyquist coordinates (imaginary vs real part) for a PANI membrane (thickness 42μm) immersed in a solution ZnCl2 (1M)/HCl (pH1).</note><note type="content">Fig. 4: a.c. Impedance diagram in Nyquist coordinates (imaginary vs real part) for a PANI membrane (thickness 34μm) immersed in a solution ZnnCl2 (1M)/HCl (pH2).</note><note type="content">Table 1: Fitted values of the parameters contained in Formulae (2)–(4) for PANI membranes dipped in solutions NaCl (1M)/HCl at different pH values. Area=0.2cm2</note><note type="content">Table 2: Fitted values of the parameters contained in Formulae (2)–(4) for PANI membranes dipped in chloride solutions with an adjusted pH of 1 (HCl) and various cations for a total concentration of 1M. Area=0.2cm2</note><note type="content">Table 3: Fitted values of the parameters contained in Formulae (2)–(4) for PANI membranes dipped in solutions ZnCl2 (1M)/HCl at different pH values. Area=0.2cm2</note><subject><genre>Keywords</genre><topic>Polyaniline</topic><topic>Membranes</topic><topic>Impedance</topic><topic>Mixed conductivity</topic><topic>Charge transport</topic></subject><relatedItem type="host"><titleInfo><title>Electrochimica Acta</title></titleInfo><titleInfo type="abbreviated"><title>EA</title></titleInfo><genre type="journal">journal</genre><originInfo><dateIssued encoding="w3cdtf">19990101</dateIssued></originInfo><identifier type="ISSN">0013-4686</identifier><identifier type="PII">S0013-4686(00)X0075-8</identifier><part><date>19990101</date><detail type="volume"><number>44</number><caption>vol.</caption></detail><detail type="issue"><number>12</number><caption>no.</caption></detail><extent unit="issue pages"><start>1845</start><end>2172</end></extent><extent unit="pages"><start>2087</start><end>2093</end></extent></part></relatedItem><identifier type="istex">5A3C549948F12B04E317B61E2A455B976D47D549</identifier><identifier type="DOI">10.1016/S0013-4686(98)00316-8</identifier><identifier type="PII">S0013-4686(98)00316-8</identifier><accessCondition type="use and reproduction" contentType="copyright">©1999 Elsevier Science Ltd</accessCondition><recordInfo><recordContentSource>ELSEVIER</recordContentSource><recordOrigin>Elsevier Science Ltd, ©1999</recordOrigin></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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