CobaltMaghrebV1, France, Analysis, bibRecord, 000177

Is 3-methyl-2-oxazolidinone a suitable solvent for lithium-ion batteries?

Identifieur interne : 000177 ( France/Analysis ); précédent : 000176; suivant : 000178

Is 3-methyl-2-oxazolidinone a suitable solvent for lithium-ion batteries?

Auteurs : L. Gzara [Tunisie] ; A. Chagnes [France] ; B. Carre [France] ; M. Dhahbi [Tunisie] ; D. Lemordant [France]

Source :

Journal of power sources [ 0378-7753 ] ; 2006.

RBID : Pascal:06-0331068

Descripteurs français

Pascal (Inist)
- Batterie lithium, Accumulateur électrochimique, Oxazolidinedione, Solvant, Electrolyte, Cycle charge décharge, Stabilité.
Wicri :
- topic : Solvant.

English descriptors

KwdEn :
- Discharge charge cycle, Electrolyte, Lithium battery, Oxazolidinedione, Secondary cell, Solvent, Stability.

Abstract

3-Methyl-2-oxazolidinone (MeOx) has been mixed to ethylene carbonate (EC) or dimethyl carbonate (DMC) in presence of lithium tetrafluoroborate (LiBF₄) or lithium hexafluorophosphate (LiPF₆) for use as electrolyte in lithium batteries. The optimized electrolytes in term of conductivity and viscosity are MeOx:EC, x(MeOx)=0.5 and MeOx:DMC, x(MeOx)=0.4 in presence of LiBF₄ (1 M) or LiPF₆ (1 M). MeOx:EC electrolytes have a better thermal stability than MeOx:DMC electrolytes but the low wettability of the Celgard separator by MeOx:EC prevents its use in lithium batteries. No lithium insertion-deinsertion occurs when LiPF₆ is used as salt in MeOx-based electrolytes. MeOx:DMC, x(MeOx) = 0.4 + LiBF4 (1 M) exhibits a good cycling ability at a graphite electrode but all the investigated electrolytes containing MeOx have a low stability in oxidation at a lithium cobalt oxide electrode (Li_xCoO₂).

Affiliations:

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Pascal:06-0331068

Le document en format XML

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<front><div type="abstract" xml:lang="en">3-Methyl-2-oxazolidinone (MeOx) has been mixed to ethylene carbonate (EC) or dimethyl carbonate (DMC) in presence of lithium tetrafluoroborate (LiBF<sub>4</sub>
) or lithium hexafluorophosphate (LiPF<sub>6</sub>
) for use as electrolyte in lithium batteries. The optimized electrolytes in term of conductivity and viscosity are MeOx:EC, x(MeOx)=0.5 and MeOx:DMC, x(MeOx)=0.4 in presence of LiBF<sub>4</sub>
 (1 M) or LiPF<sub>6</sub>
 (1 M). MeOx:EC electrolytes have a better thermal stability than MeOx:DMC electrolytes but the low wettability of the Celgard separator by MeOx:EC prevents its use in lithium batteries. No lithium insertion-deinsertion occurs when LiPF<sub>6</sub>
 is used as salt in MeOx-based electrolytes. MeOx:DMC, x(MeOx) = 0.4 + LiBF4 (1 M) exhibits a good cycling ability at a graphite electrode but all the investigated electrolytes containing MeOx have a low stability in oxidation at a lithium cobalt oxide electrode (Li<sub>x</sub>
CoO<sub>2</sub>
).</div>
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Is 3-methyl-2-oxazolidinone a suitable solvent for lithium-ion batteries?

Is 3-methyl-2-oxazolidinone a suitable solvent for lithium-ion batteries?

Source :

Descripteurs français

English descriptors

Abstract

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