(Bicyclo[3.2.0]hepta‐1,3‐dienyl)cobalt(I) Complexes
Identifieur interne : 009462 ( Main/Exploration ); précédent : 009461; suivant : 009463(Bicyclo[3.2.0]hepta‐1,3‐dienyl)cobalt(I) Complexes
Auteurs : Klaus P. Angermund [Allemagne] ; Peter Betz [Allemagne] ; Holger Butenschön [Allemagne]Source :
- Chemische Berichte [ 0009-2940 ] ; 1993-03.
English descriptors
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Abstract
Three isomeric bicyclo[3.2.0]heptadienes 1 – 3 are compared by semiempirical calculations. Experimental attempts directed to the synthesis of derivatives of 1 are described. The synthesis, properties and some reactions of (η51‐bicyclo[3.2.0]hepta‐1,3‐dienyl)(η41‐cycloocta‐1,5‐diene)cobalt(I) (22), including an X‐ray crystal structure determination of the reaction product with diphenylethyne, the tetraphenylcyclobutadiene complex 30, are presented.
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DOI: 10.1002/cber.19931260323
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Ruhr 1</wicri:noRegion></affiliation><affiliation wicri:level="1"><country xml:lang="fr" wicri:curation="lc">Allemagne</country><wicri:regionArea>Current Address: Bergische Universität – Gesamthochschule Wuppertal, Fachbereich 9 – Organische Chemie –, Gaußstraße 20, W‐5600 Wuppertal 1</wicri:regionArea><wicri:noRegion>W‐5600 Wuppertal 1</wicri:noRegion><wicri:noRegion>W‐5600 Wuppertal 1</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j">Chemische Berichte</title><title level="j" type="abbrev">Chem. 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Experimental attempts directed to the synthesis of derivatives of 1 are described. The synthesis, properties and some reactions of (η51‐bicyclo[3.2.0]hepta‐1,3‐dienyl)(η41‐cycloocta‐1,5‐diene)cobalt(I) (22), including an X‐ray crystal structure determination of the reaction product with diphenylethyne, the tetraphenylcyclobutadiene complex 30, are presented.</div></front></TEI><affiliations><list><country><li>Allemagne</li></country></list><tree><country name="Allemagne"><noRegion><name sortKey="Angermund, Klaus P" sort="Angermund, Klaus P" uniqKey="Angermund K" first="Klaus P." last="Angermund">Klaus P. 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