An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions
Identifieur interne : 001D25 ( Istex/Corpus ); précédent : 001D24; suivant : 001D26An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions
Auteurs : Philip Andrews ; Alan Kennedy ; Robert Mulvey ; Colin Raston ; Brett Roberts ; René RowlingsSource :
- Angewandte Chemie [ 0044-8249 ] ; 2000-06-02.
Abstract
Sechs Aren‐Anionen in einem kationischen [K6Mg6N12]6+‐Ring (siehe Bild, Aren=Benzol) weist das erste gemischte makrocyclische Metallamid mit 24 (!) Ringatomen auf. Der Makrocyclus wurde in einer sehr effizienten Synthese erhalten, bei der die Anionen durch selektive Monodeprotonierung entstehen.
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DOI: 10.1002/1521-3757(20000602)112:11<2036::AID-ANGE2036>3.0.CO;2-2
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<front><div type="abstract" xml:lang="de">Sechs Aren‐Anionen in einem kationischen [K6Mg6N12]6+‐Ring (siehe Bild, Aren=Benzol) weist das erste gemischte makrocyclische Metallamid mit 24 (!) Ringatomen auf. Der Makrocyclus wurde in einer sehr effizienten Synthese erhalten, bei der die Anionen durch selektive Monodeprotonierung entstehen.</div>
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Mg<sub>6</sub>
N<sub>12</sub>
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<noteGroup><note xml:id="fnxx" numbered="no"><p>This work was supported by the UK Engineering and Physical Science Research Council (Grant award No. GR/M78113). Thanks are also extended to Dr. P. J. Nichols for help with the crystallographic work.</p>
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<mods version="3.6"><titleInfo lang="en"><title>An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
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<titleInfo type="alternative" contentType="CDATA" lang="en"><title>An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions</title>
</titleInfo>
<name type="personal"><namePart type="given">Philip C.</namePart>
<namePart type="family">Andrews</namePart>
<namePart type="termsOfAddress">Dr.</namePart>
<affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Alan R.</namePart>
<namePart type="family">Kennedy</namePart>
<namePart type="termsOfAddress">Dr.</namePart>
<affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Robert E.</namePart>
<namePart type="family">Mulvey</namePart>
<namePart type="termsOfAddress">Prof.</namePart>
<affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</affiliation>
<affiliation>E-mail: r.e.mulvey@strath.ac.uk</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Colin L.</namePart>
<namePart type="family">Raston</namePart>
<namePart type="termsOfAddress">Prof.</namePart>
<affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Brett A.</namePart>
<namePart type="family">Roberts</namePart>
<affiliation>Department of Chemistry Monash University Clayton, Victoria, 3168, Australia</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">René B.</namePart>
<namePart type="family">Rowlings</namePart>
<namePart type="termsOfAddress">Dr.</namePart>
<affiliation>Department of Pure and Applied Chemistry University of Strathclyde Glasgow, G1 1XL, UK, Fax: (+44) 141‐552‐0876</affiliation>
<role><roleTerm type="text">author</roleTerm>
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<typeOfResource>text</typeOfResource>
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<originInfo><publisher>WILEY‐VCH Verlag GmbH</publisher>
<place><placeTerm type="text">Weinheim</placeTerm>
</place>
<dateIssued encoding="w3cdtf">2000-06-02</dateIssued>
<dateCaptured encoding="w3cdtf">2000-02-07</dateCaptured>
<copyrightDate encoding="w3cdtf">2000</copyrightDate>
</originInfo>
<language><languageTerm type="code" authority="rfc3066">en</languageTerm>
<languageTerm type="code" authority="iso639-2b">eng</languageTerm>
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<extent unit="figures">12</extent>
<extent unit="references">14</extent>
</physicalDescription>
<abstract type="short" lang="de">Sechs Aren‐Anionen in einem kationischen [K6Mg6N12]6+‐Ring (siehe Bild, Aren=Benzol) weist das erste gemischte makrocyclische Metallamid mit 24 (!) Ringatomen auf. Der Makrocyclus wurde in einer sehr effizienten Synthese erhalten, bei der die Anionen durch selektive Monodeprotonierung entstehen.</abstract>
<subject lang="de"><genre>keywords</genre>
<topic>Alkalimetalle</topic>
<topic>Amide</topic>
<topic>Erdalkalimetalle</topic>
<topic>Makrocyclen</topic>
<topic>Templatsynthesen</topic>
</subject>
<relatedItem type="host"><titleInfo><title>Angewandte Chemie</title>
</titleInfo>
<titleInfo type="abbreviated"><title>Angew. Chem.</title>
</titleInfo>
<genre type="journal">journal</genre>
<subject><genre>article-category</genre>
<topic>Zuschrift</topic>
</subject>
<identifier type="ISSN">0044-8249</identifier>
<identifier type="eISSN">1521-3757</identifier>
<identifier type="DOI">10.1002/(ISSN)1521-3757</identifier>
<identifier type="PublisherID">ANGE</identifier>
<part><date>2000</date>
<detail type="volume"><caption>vol.</caption>
<number>112</number>
</detail>
<detail type="issue"><caption>no.</caption>
<number>11</number>
</detail>
<extent unit="pages"><start>2036</start>
<end>2038</end>
<total>3</total>
</extent>
</part>
</relatedItem>
<identifier type="istex">422CF70AD6C619A7537E8EC3BA73B57C480C230F</identifier>
<identifier type="DOI">10.1002/1521-3757(20000602)112:11<2036::AID-ANGE2036>3.0.CO;2-2</identifier>
<identifier type="ArticleID">ANGE2036</identifier>
<accessCondition type="use and reproduction" contentType="copyright">Copyright © 2000 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany</accessCondition>
<recordInfo><recordContentSource>WILEY</recordContentSource>
<recordOrigin>WILEY‐VCH Verlag GmbH</recordOrigin>
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