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Chapter 4 - X β-Diketiminato complexes of groups 3 to 5

Identifieur interne : 001760 ( Istex/Corpus ); précédent : 001759; suivant : 001761

Chapter 4 - X β-Diketiminato complexes of groups 3 to 5

Source :

SPR - Organometallic Chemistry [ 0301-0074 ]

RBID : ISTEX:9FE6704F8CAB4086DAE1AFE23FF1A7CD76F3109D

Abstract

This article covers the progress of β-diketiminates as supporting ligands in transition metal complexes from the seminal review published by Lappert et al. in 2002 to the middle of 2013.1 Due to the tremendous number of reports since 2002 involving this class of ligand, this review focuses on the early transition metals, with elements from groups 3 to 5. β-diketiminate ligands are sterically demanding and thus stabilise highly reactive metal environments engendering both low-coordinate and multiply-bonded motifs. Recent publications also demonstrate the utility of this ligand class to build early transition catalysts with unique and interesting reactivity.

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https://api.istex.fr/document/9FE6704F8CAB4086DAE1AFE23FF1A7CD76F3109D/fulltext/pdf

DOI: 10.1039/9781849737692-00072

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ISTEX:9FE6704F8CAB4086DAE1AFE23FF1A7CD76F3109D

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<ack><p>ADP wishes to thank Dr. Christian Grave for highly valuable discussions regarding the material in this review. This review is dedicated to the memory of Professor Gregory L. Hillhouse, a true pioneer of organometallic chemistry.</p>
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<titleInfo type="alternative" contentType="CDATA"><title>Chapter 4 - X β-Diketiminato complexes of groups 3 to 5</title>
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<name type="personal"><namePart type="given">Andrew D.</namePart>
<namePart type="family">Phillips</namePart>
<affiliation>Office S3.14, Centre for Molecular Innovation and Drug Discovery, University College Dublin, Belfield Campus, Dublin Co, D4, Ireland</affiliation>
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<abstract>This article covers the progress of β-diketiminates as supporting ligands in transition metal complexes from the seminal review published by Lappert et al. in 2002 to the middle of 2013.1 Due to the tremendous number of reports since 2002 involving this class of ligand, this review focuses on the early transition metals, with elements from groups 3 to 5. β-diketiminate ligands are sterically demanding and thus stabilise highly reactive metal environments engendering both low-coordinate and multiply-bonded motifs. Recent publications also demonstrate the utility of this ligand class to build early transition catalysts with unique and interesting reactivity.</abstract>
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Chapter 4 - X β-Diketiminato complexes of groups 3 to 5

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