An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions
Identifieur interne : 003270 ( Istex/Checkpoint ); précédent : 003269; suivant : 003271An Unprecedented Hexapotassium‐Hexamagnesium 24‐Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions
Auteurs : Philip Andrews [Australie] ; Alan Kennedy ; Robert Mulvey [Royaume-Uni] ; Colin Raston [Australie] ; Brett Roberts [Australie] ; René RowlingsSource :
- Angewandte Chemie [ 0044-8249 ] ; 2000-06-02.
Abstract
Sechs Aren‐Anionen in einem kationischen [K6Mg6N12]6+‐Ring (siehe Bild, Aren=Benzol) weist das erste gemischte makrocyclische Metallamid mit 24 (!) Ringatomen auf. Der Makrocyclus wurde in einer sehr effizienten Synthese erhalten, bei der die Anionen durch selektive Monodeprotonierung entstehen.
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DOI: 10.1002/1521-3757(20000602)112:11<2036::AID-ANGE2036>3.0.CO;2-2
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Chem.</title><idno type="ISSN">0044-8249</idno><idno type="eISSN">1521-3757</idno><imprint><publisher>WILEY‐VCH Verlag GmbH</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2000-06-02">2000-06-02</date><biblScope unit="volume">112</biblScope><biblScope unit="issue">11</biblScope><biblScope unit="page" from="2036">2036</biblScope><biblScope unit="page" to="2038">2038</biblScope></imprint><idno type="ISSN">0044-8249</idno></series><idno type="istex">422CF70AD6C619A7537E8EC3BA73B57C480C230F</idno><idno type="DOI">10.1002/1521-3757(20000602)112:11<2036::AID-ANGE2036>3.0.CO;2-2</idno><idno type="ArticleID">ANGE2036</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0044-8249</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="de">Sechs Aren‐Anionen in einem kationischen [K6Mg6N12]6+‐Ring (siehe Bild, Aren=Benzol) weist das erste gemischte makrocyclische Metallamid mit 24 (!) Ringatomen auf. Der Makrocyclus wurde in einer sehr effizienten Synthese erhalten, bei der die Anionen durch selektive Monodeprotonierung entstehen.</div></front></TEI><affiliations><list><country><li>Australie</li><li>Royaume-Uni</li></country></list><tree><noCountry><name sortKey="Kennedy, Alan" sort="Kennedy, Alan" uniqKey="Kennedy A" first="Alan" last="Kennedy">Alan Kennedy</name><name sortKey="Rowlings, Rene" sort="Rowlings, Rene" uniqKey="Rowlings R" first="René" last="Rowlings">René Rowlings</name></noCountry><country name="Australie"><noRegion><name sortKey="Andrews, Philip" sort="Andrews, Philip" uniqKey="Andrews P" first="Philip" last="Andrews">Philip Andrews</name></noRegion><name sortKey="Raston, Colin" sort="Raston, Colin" uniqKey="Raston C" first="Colin" last="Raston">Colin Raston</name><name sortKey="Roberts, Brett" sort="Roberts, Brett" uniqKey="Roberts B" first="Brett" last="Roberts">Brett Roberts</name></country><country name="Royaume-Uni"><noRegion><name sortKey="Mulvey, Robert" sort="Mulvey, Robert" uniqKey="Mulvey R" first="Robert" last="Mulvey">Robert Mulvey</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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