Spectroscopy and Redox Behaviour of Dicopper(II) and Dinickel(II) Complexes of Bis(cyclen) and Bis(cyclam) Ligands
Identifieur interne : 002C18 ( Main/Exploration ); précédent : 002C17; suivant : 002C19Spectroscopy and Redox Behaviour of Dicopper(II) and Dinickel(II) Complexes of Bis(cyclen) and Bis(cyclam) Ligands
Auteurs : Sanae El Ghachtouli [France] ; Cyril Cadiou [France] ; Isabelle Déchamps-Olivier [France] ; Françoise Chuburu [France] ; Michel Aplincourt [France] ; Véronique Turcry [France] ; Michel Le Baccon [France] ; Henri Handel [France]Source :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2005-07.
Descripteurs français
- Wicri :
- topic : Cuivre, électrochimie, Nickel.
English descriptors
- KwdEn :
Abstract
The dinuclear CuII and NiII complexes of meta‐xylyl and pyridyl biscyclen and biscyclam have been prepared and characterised in solution by means of UV/Visible spectra, electrochemical and EPR studies. X‐ray structures of copper biscyclen complexes have been obtained. The comparison of all the data shows that the potentially coordinating N(py) pyridyl atom promotes the interaction between the two metal centers, whether it is spontaneously coordinated (biscyclen complexes) or not (biscyclam ones). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Url:
DOI: 10.1002/ejic.200500120
Affiliations:
- France
- Champagne-Ardenne, Grand Est, Région Bretagne
- Brest, Reims
- Université de Bretagne Occidentale
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Le document en format XML
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X‐ray structures of copper biscyclen complexes have been obtained. The comparison of all the data shows that the potentially coordinating N(py) pyridyl atom promotes the interaction between the two metal centers, whether it is spontaneously coordinated (biscyclen complexes) or not (biscyclam ones). (© Wiley‐VCH Verlag GmbH & Co. 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