Spectroscopy and Redox Behaviour of Dicopper(II) and Dinickel(II) Complexes of Bis(cyclen) and Bis(cyclam) Ligands
Identifieur interne : 000E68 ( Istex/Corpus ); précédent : 000E67; suivant : 000E69Spectroscopy and Redox Behaviour of Dicopper(II) and Dinickel(II) Complexes of Bis(cyclen) and Bis(cyclam) Ligands
Auteurs : Sanae El Ghachtouli ; Cyril Cadiou ; Isabelle Déchamps-Olivier ; Françoise Chuburu ; Michel Aplincourt ; Véronique Turcry ; Michel Le Baccon ; Henri HandelSource :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2005-07.
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Abstract
The dinuclear CuII and NiII complexes of meta‐xylyl and pyridyl biscyclen and biscyclam have been prepared and characterised in solution by means of UV/Visible spectra, electrochemical and EPR studies. X‐ray structures of copper biscyclen complexes have been obtained. The comparison of all the data shows that the potentially coordinating N(py) pyridyl atom promotes the interaction between the two metal centers, whether it is spontaneously coordinated (biscyclen complexes) or not (biscyclam ones). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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DOI: 10.1002/ejic.200500120
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ISTEX:FACF2883232D7ED004092CF1D7703E0D3218BE7ELe document en format XML
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X‐ray structures of copper biscyclen complexes have been obtained. The comparison of all the data shows that the potentially coordinating N(py) pyridyl atom promotes the interaction between the two metal centers, whether it is spontaneously coordinated (biscyclen complexes) or not (biscyclam ones). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)</div></front></TEI><istex><corpusName>wiley</corpusName><author><json:item><name>Sanae El Ghachtouli</name><affiliations><json:string>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</json:string></affiliations></json:item><json:item><name>Cyril Cadiou</name><affiliations><json:string>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</json:string></affiliations></json:item><json:item><name>Isabelle Déchamps‐Olivier</name><affiliations><json:string>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</json:string></affiliations></json:item><json:item><name>Françoise Chuburu</name><affiliations><json:string>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</json:string><json:string>E-mail: francoise.chuburu@univ‐reims.fr</json:string></affiliations></json:item><json:item><name>Michel Aplincourt</name><affiliations><json:string>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</json:string></affiliations></json:item><json:item><name>Véronique Turcry</name><affiliations><json:string>UMR CNRS 6521, Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</json:string></affiliations></json:item><json:item><name>Michel Le Baccon</name><affiliations><json:string>UMR CNRS 6521, Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</json:string></affiliations></json:item><json:item><name>Henri Handel</name><affiliations><json:string>UMR CNRS 6521, Université de Bretagne Occidentale, B. 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X‐ray structures of copper biscyclen complexes have been obtained. The comparison of all the data shows that the potentially coordinating N(py) pyridyl atom promotes the interaction between the two metal centers, whether it is spontaneously coordinated (biscyclen complexes) or not (biscyclam ones). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)</abstract><qualityIndicators><score>5.984</score><pdfVersion>1.3</pdfVersion><pdfPageSize>594.92 x 793.94 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractCharCount>569</abstractCharCount><pdfWordCount>6160</pdfWordCount><pdfCharCount>38049</pdfCharCount><pdfPageCount>11</pdfPageCount><abstractWordCount>82</abstractWordCount></qualityIndicators><title>Spectroscopy and Redox Behaviour of Dicopper(II) and Dinickel(II) Complexes of Bis(cyclen) and Bis(cyclam) Ligands</title><refBibs><json:item><host><volume>110</volume><pages><first>17</first></pages><author></author><title>Coord. Chem. 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P. 1039, 51687 Reims Cedex 2, France</affiliation></author><author xml:id="author-4"><persName><forename type="first">Françoise</forename><surname>Chuburu</surname></persName><email>francoise.chuburu@univ‐reims.fr</email><affiliation>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</affiliation></author><author xml:id="author-5"><persName><forename type="first">Michel</forename><surname>Aplincourt</surname></persName><affiliation>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</affiliation></author><author xml:id="author-6"><persName><forename type="first">Véronique</forename><surname>Turcry</surname></persName><affiliation>UMR CNRS 6521, Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation></author><author xml:id="author-7"><persName><forename type="first">Michel</forename><surname>Le Baccon</surname></persName><affiliation>UMR CNRS 6521, Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation></author><author xml:id="author-8"><persName><forename type="first">Henri</forename><surname>Handel</surname></persName><affiliation>UMR CNRS 6521, Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation></author></analytic><monogr><title level="j">European Journal of Inorganic Chemistry</title><title level="j" type="abbrev">Eur. J. Inorg. Chem.</title><idno type="pISSN">1434-1948</idno><idno type="eISSN">1099-0682</idno><idno type="DOI">10.1002/(ISSN)1099-0682c</idno><imprint><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2005-07"></date><biblScope unit="volume">2005</biblScope><biblScope unit="issue">13</biblScope><biblScope unit="page" from="2658">2658</biblScope><biblScope unit="page" to="2668">2668</biblScope></imprint></monogr><idno type="istex">FACF2883232D7ED004092CF1D7703E0D3218BE7E</idno><idno type="DOI">10.1002/ejic.200500120</idno><idno type="ArticleID">EJIC200500120</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>2005</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>The dinuclear CuII and NiII complexes of meta‐xylyl and pyridyl biscyclen and biscyclam have been prepared and characterised in solution by means of UV/Visible spectra, electrochemical and EPR studies. X‐ray structures of copper biscyclen complexes have been obtained. The comparison of all the data shows that the potentially coordinating N(py) pyridyl atom promotes the interaction between the two metal centers, whether it is spontaneously coordinated (biscyclen complexes) or not (biscyclam ones). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)</p></abstract><abstract xml:lang="en" style="graphical"><p></p></abstract><textClass xml:lang="en"><keywords scheme="keyword"><list><head>keywords</head><item><term>Copper</term></item><item><term>Nickel</term></item><item><term>Bis(cyclen) ligands</term></item><item><term>Bis(cyclam) ligands</term></item><item><term>Electrochemistry</term></item><item><term>EPR spectroscopy</term></item></list></keywords></textClass><textClass><keywords scheme="Journal Subject"><list><head>article-category</head><item><term>Full Paper</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2005-02-08">Received</change><change when="2005-07">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/FACF2883232D7ED004092CF1D7703E0D3218BE7E/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName><publisherLoc>Weinheim</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1099-0682c</doi><issn type="print">1434-1948</issn><issn type="electronic">1099-0682</issn><idGroup><id type="product" value="EJIC"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="EUROPEAN JOURNAL OF INORGANIC CHEMISTRY">European Journal of Inorganic Chemistry</title><title type="short">Eur. J. Inorg. Chem.</title></titleGroup></publicationMeta><publicationMeta level="part" position="130"><doi origin="wiley" registered="yes">10.1002/ejic.v2005:13</doi><numberingGroup><numbering type="journalVolume" number="2005">2005</numbering><numbering type="journalIssue">13</numbering></numberingGroup><coverDate startDate="2005-07">July 2005</coverDate></publicationMeta><publicationMeta level="unit" type="bookReview" position="15" status="forIssue"><doi origin="wiley" registered="yes">10.1002/ejic.200500120</doi><idGroup><id type="unit" value="EJIC200500120"></id></idGroup><countGroup><count type="pageTotal" number="11"></count></countGroup><titleGroup><title type="articleCategory">Full Paper</title></titleGroup><copyright ownership="publisher">Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2005-02-08"></event><event type="firstOnline" date="2005-06-29"></event><event type="publishedOnlineFinalForm" date="2005-06-29"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.6 mode:FullText source:FullText result:FullText mathml2tex" date="2010-04-19"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-24"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-16"></event></eventGroup><numberingGroup><numbering type="pageFirst">2658</numbering><numbering type="pageLast">2668</numbering></numberingGroup><objectNameGroup><objectName elementName="figure">Scheme</objectName></objectNameGroup><linkGroup><link type="toTypesetVersion" href="file:EJIC.EJIC200500120.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="8"></count><count type="tableTotal" number="5"></count><count type="referenceTotal" number="28"></count></countGroup><titleGroup><title type="main" xml:lang="en">Spectroscopy and Redox Behaviour of Dicopper(<sc>II</sc>) and Dinickel(<sc>II</sc>) Complexes of Bis(cyclen) and Bis(cyclam) Ligands</title><title type="short" xml:lang="en">Spectroscopy and Redox Behaviour of Dicopper(<sc>II</sc>) and Dinickel(<sc>II</sc>) Complexes</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Sanae</givenNames><familyName>El Ghachtouli</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Cyril</givenNames><familyName>Cadiou</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Isabelle</givenNames><familyName>Déchamps‐Olivier</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Françoise</givenNames><familyName>Chuburu</familyName></personName><contactDetails><email normalForm="francoise.chuburu@univ-reims.fr">francoise.chuburu@univ‐reims.fr</email></contactDetails></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Michel</givenNames><familyName>Aplincourt</familyName></personName></creator><creator xml:id="au6" creatorRole="author" affiliationRef="#af2"><personName><givenNames>Véronique</givenNames><familyName>Turcry</familyName></personName></creator><creator xml:id="au7" creatorRole="author" affiliationRef="#af2"><personName><givenNames>Michel</givenNames><familyName>Le Baccon</familyName></personName></creator><creator xml:id="au8" creatorRole="author" affiliationRef="#af2"><personName><givenNames>Henri</givenNames><familyName>Handel</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="FR" type="organization"><unparsedAffiliation>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</unparsedAffiliation></affiliation><affiliation xml:id="af2" countryCode="FR" type="organization"><unparsedAffiliation>UMR CNRS 6521, Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Copper</keyword><keyword xml:id="kwd2">Nickel</keyword><keyword xml:id="kwd3">Bis(cyclen) ligands</keyword><keyword xml:id="kwd4">Bis(cyclam) ligands</keyword><keyword xml:id="kwd5">Electrochemistry</keyword><keyword xml:id="kwd6">EPR spectroscopy</keyword></keywordGroup><supportingInformation><p>Supporting information for this article is available on the WWW under <url href="http://www.wiley-vch.de/contents/jc_2005/2005/i200500120_s.pdf">http://www.wiley‐vch.de/contents/jc_2005/2005/i200500120_s.pdf</url> or from the author.</p></supportingInformation><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>The dinuclear Cu<sup>II</sup> and Ni<sup>II</sup> complexes of <i>meta</i>‐xylyl and pyridyl biscyclen and biscyclam have been prepared and characterised in solution by means of UV/Visible spectra, electrochemical and EPR studies. X‐ray structures of copper biscyclen complexes have been obtained. The comparison of all the data shows that the potentially coordinating N(<i>py</i>) pyridyl atom promotes the interaction between the two metal centers, whether it is spontaneously coordinated (biscyclen complexes) or not (biscyclam ones). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)</p></abstract><abstract type="graphical" xml:lang="en"><p><blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:14341948:media:EJIC200500120:fig000"></mediaResource><mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" href=""></mediaResource><mediaResource alt="original image" rendition="webOriginal" mimeType="image/jpeg" href=""></mediaResource><mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/jpeg" href=""></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Spectroscopy and Redox Behaviour of Dicopper(II) and Dinickel(II) Complexes of Bis(cyclen) and Bis(cyclam) Ligands</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>Spectroscopy and Redox Behaviour of Dicopper(II) and Dinickel(II) Complexes</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Spectroscopy and Redox Behaviour of Dicopper(II) and Dinickel(II) Complexes of Bis(cyclen) and Bis(cyclam) Ligands</title></titleInfo><name type="personal"><namePart type="given">Sanae</namePart><namePart type="family">El Ghachtouli</namePart><affiliation>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Cyril</namePart><namePart type="family">Cadiou</namePart><affiliation>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Isabelle</namePart><namePart type="family">Déchamps‐Olivier</namePart><affiliation>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Françoise</namePart><namePart type="family">Chuburu</namePart><affiliation>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</affiliation><affiliation>E-mail: francoise.chuburu@univ‐reims.fr</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Michel</namePart><namePart type="family">Aplincourt</namePart><affiliation>GRECI, Université de Reims Champagne–Ardenne, B. P. 1039, 51687 Reims Cedex 2, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Véronique</namePart><namePart type="family">Turcry</namePart><affiliation>UMR CNRS 6521, Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Michel</namePart><namePart type="family">Le Baccon</namePart><affiliation>UMR CNRS 6521, Université de Bretagne Occidentale, B. P. 809, 29285 Brest Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Henri</namePart><namePart type="family">Handel</namePart><affiliation>UMR CNRS 6521, Université de Bretagne Occidentale, B. 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X‐ray structures of copper biscyclen complexes have been obtained. The comparison of all the data shows that the potentially coordinating N(py) pyridyl atom promotes the interaction between the two metal centers, whether it is spontaneously coordinated (biscyclen complexes) or not (biscyclam ones). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)</abstract><abstract type="graphical" lang="en"></abstract><subject lang="en"><genre>keywords</genre><topic>Copper</topic><topic>Nickel</topic><topic>Bis(cyclen) ligands</topic><topic>Bis(cyclam) ligands</topic><topic>Electrochemistry</topic><topic>EPR spectroscopy</topic></subject><relatedItem type="host"><titleInfo><title>European Journal of Inorganic Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Eur. J. Inorg. Chem.</title></titleInfo><genre type="journal">journal</genre><note type="content"> Supporting information for this article is available on the WWW under http://www.wiley‐vch.de/contents/jc_2005/2005/i200500120_s.pdf or from the author.</note><subject><genre>article-category</genre><topic>Full Paper</topic></subject><identifier type="ISSN">1434-1948</identifier><identifier type="eISSN">1099-0682</identifier><identifier type="DOI">10.1002/(ISSN)1099-0682c</identifier><identifier type="PublisherID">EJIC</identifier><part><date>2005</date><detail type="volume"><caption>vol.</caption><number>2005</number></detail><detail type="issue"><caption>no.</caption><number>13</number></detail><extent unit="pages"><start>2658</start><end>2668</end><total>11</total></extent></part></relatedItem><identifier type="istex">FACF2883232D7ED004092CF1D7703E0D3218BE7E</identifier><identifier type="DOI">10.1002/ejic.200500120</identifier><identifier type="ArticleID">EJIC200500120</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. 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