MersV1, PubMed, Corpus, bibRecord, 001867

(N-Phenyl-thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Identifieur interne : 001867 ( PubMed/Corpus ); précédent : 001866; suivant : 001868

(N-Phenyl-thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Auteurs : Sofia Mekarat ; Chaveng Pakawatchai ; Saowanit Saithong

Source :

Acta crystallographica. Section E, Structure reports online [ 1600-5368 ] ; 2014.

RBID : pubmed:25161537

Abstract

In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops. The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network.

DOI: 10.1107/S1600536814014147
PubMed: 25161537

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pubmed:25161537

Le document en format XML

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<author><name sortKey="Pakawatchai, Chaveng" sort="Pakawatchai, Chaveng" uniqKey="Pakawatchai C" first="Chaveng" last="Pakawatchai">Chaveng Pakawatchai</name>
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<front><div type="abstract" xml:lang="en">In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops. The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network. </div>
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<Abstract><AbstractText>In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops. The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network. </AbstractText>
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(N-Phenyl-thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

(N-Phenyl-thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

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Abstract

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