(N-Phenylthiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate
Identifieur interne : 001D70 ( Main/Exploration ); précédent : 001D69; suivant : 001D71(N-Phenylthiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate
Auteurs : Sofia Mekarat [Thaïlande] ; Chaveng Pakawatchai [Thaïlande] ; Saowanit Saithong [Thaïlande]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.
Abstract
In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the AgI atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H⋯O hydrogen bonds, generating tetramers (two cations and two anions), which feature
Url:
DOI: 10.1107/S1600536814014147
PubMed: 25161537
PubMed Central: 4120613
Affiliations:
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-Phenylthiourea-κ<italic>S</italic>
)bis(triphenylphosphane-κ<italic>P</italic>
)silver(I) nitrate</title>
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<front><div type="abstract" xml:lang="en"><p>In the title salt, [Ag(C<sub>7</sub>
H<sub>8</sub>
N<sub>2</sub>
S)(C<sub>18</sub>
H<sub>15</sub>
P)<sub>2</sub>
]NO<sub>3</sub>
, the coordination geometry about the Ag<sup>I</sup>
atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H⋯O hydrogen bonds, generating tetramers (two cations and two anions), which feature <italic>R</italic>
<sub>2</sub>
<sup>2</sup>
(8) and <italic>R</italic>
<sub>4</sub>
<sup>4</sup>
(8) loops. The cations are linked by weak C—H⋯π interactions, generating a three-dimensional network.</p>
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