Poly[[diaquabis(μ3-maleato-κ4O1:O1′,O4:O4′)dicopper(II)] trihydrate]
Identifieur interne : 002960 ( Main/Exploration ); précédent : 002959; suivant : 002961Poly[[diaquabis(μ3-maleato-κ4O1:O1′,O4:O4′)dicopper(II)] trihydrate]
Auteurs : Gregory A. Farnum [États-Unis] ; Robert L. Laduca [États-Unis]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2008.
Abstract
In the title compound, {[Cu2(C4H2O4)2(H2O)2]·3H2O}
Url:
DOI: 10.1107/S1600536808023131
PubMed: 21203054
PubMed Central: 2961984
Affiliations:
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Le document en format XML
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-maleato-κ<sup>4</sup>
<italic>O</italic>
<sup>1</sup>
:<italic>O</italic>
<sup>1′</sup>
,<italic>O</italic>
<sup>4</sup>
:O<sup>4′</sup>
)dicopper(II)] trihydrate]</title>
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</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
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<author><name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L." last="Laduca">Robert L. Laduca</name>
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<country xml:lang="fr">États-Unis</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Poly[[diaquabis(μ<sub>3</sub>
-maleato-κ<sup>4</sup>
<italic>O</italic>
<sup>1</sup>
:<italic>O</italic>
<sup>1′</sup>
,<italic>O</italic>
<sup>4</sup>
:O<sup>4′</sup>
)dicopper(II)] trihydrate]</title>
<author><name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A." last="Farnum">Gregory A. Farnum</name>
<affiliation wicri:level="1"><nlm:aff id="a">Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825,<country>USA</country>
</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L." last="Laduca">Robert L. Laduca</name>
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<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, {[Cu<sub>2</sub>
(C<sub>4</sub>
H<sub>2</sub>
O<sub>4</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
]·3H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
, Cu<sup>II</sup>
ions with square-pyramidal coordination are bridged by exotridentate maleate dianions into [Cu<sub>2</sub>
(maleate)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
]<sub><italic>n</italic>
</sub>
layers coincident with the <italic>bc</italic>
crystal plane. The interlamellar regions contain hydrogen-bonded cyclic water hexamers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.</p>
</div>
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<affiliations><list><country><li>États-Unis</li>
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