Exploration
Accueil
Racine
Exploration
Accueil
Racine

Serveur d'exploration MERS

Attention, ce site est en cours de développement !
Attention, site généré par des moyens informatiques à partir de corpus bruts.
Les informations ne sont donc pas validées.

Poly[[diaqua­bis(μ3-maleato-κ4O1:O1′,O4:O4′)dicopper(II)] trihydrate]

Identifieur interne : 002960 ( Main/Exploration ); précédent : 002959; suivant : 002961

Poly[[diaqua­bis(μ3-maleato-κ4O1:O1′,O4:O4′)dicopper(II)] trihydrate]

Auteurs : Gregory A. Farnum [États-Unis] ; Robert L. Laduca [États-Unis]

Source :

RBID : PMC:2961984

Abstract

In the title compound, {[Cu2(C4H2O4)2(H2O)2]·3H2O}n, CuII ions with square-pyramidal coordination are bridged by exo­tri­dentate maleate dianions into [Cu2(maleate)2(H2O)2]n layers coincident with the bc crystal plane. The inter­lamellar regions contain hydrogen-bonded cyclic water hexa­mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.


Url:
DOI: 10.1107/S1600536808023131
PubMed: 21203054
PubMed Central: 2961984


Affiliations:

Links toward previous steps (curation, corpus...)

Le document en format XML

<record>
<TEI>
<teiHeader>
<fileDesc>
<titleStmt>
<title xml:lang="en">Poly[[diaqua­bis(μ
<sub>3</sub>
-maleato-κ
<sup>4</sup>
<italic>O</italic>
<sup>1</sup>
:
<italic>O</italic>
<sup>1′</sup>
,
<italic>O</italic>
<sup>4</sup>
:O
<sup>4′</sup>
)dicopper(II)] trihydrate]</title>
<author>
<name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A." last="Farnum">Gregory A. Farnum</name>
<affiliation wicri:level="1">
<nlm:aff id="a">Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825,
<country>USA</country>
</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author>
<name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L." last="Laduca">Robert L. Laduca</name>
<affiliation wicri:level="1">
<nlm:aff id="a">Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825,
<country>USA</country>
</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt>
<idno type="wicri:source">PMC</idno>
<idno type="pmid">21203054</idno>
<idno type="pmc">2961984</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961984</idno>
<idno type="RBID">PMC:2961984</idno>
<idno type="doi">10.1107/S1600536808023131</idno>
<date when="2008">2008</date>
<idno type="wicri:Area/Pmc/Corpus">000A00</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000A00</idno>
<idno type="wicri:Area/Pmc/Curation">000A00</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000A00</idno>
<idno type="wicri:Area/Pmc/Checkpoint">001394</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">001394</idno>
<idno type="wicri:source">PubMed</idno>
<idno type="RBID">pubmed:21203054</idno>
<idno type="wicri:Area/PubMed/Corpus">002136</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">002136</idno>
<idno type="wicri:Area/PubMed/Curation">002136</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">002136</idno>
<idno type="wicri:Area/PubMed/Checkpoint">001F68</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">001F68</idno>
<idno type="wicri:Area/Ncbi/Merge">000797</idno>
<idno type="wicri:Area/Ncbi/Curation">000797</idno>
<idno type="wicri:Area/Ncbi/Checkpoint">000797</idno>
<idno type="wicri:Area/Main/Merge">002986</idno>
<idno type="wicri:Area/Main/Curation">002960</idno>
<idno type="wicri:Area/Main/Exploration">002960</idno>
</publicationStmt>
<sourceDesc>
<biblStruct>
<analytic>
<title xml:lang="en" level="a" type="main">Poly[[diaqua­bis(μ
<sub>3</sub>
-maleato-κ
<sup>4</sup>
<italic>O</italic>
<sup>1</sup>
:
<italic>O</italic>
<sup>1′</sup>
,
<italic>O</italic>
<sup>4</sup>
:O
<sup>4′</sup>
)dicopper(II)] trihydrate]</title>
<author>
<name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A." last="Farnum">Gregory A. Farnum</name>
<affiliation wicri:level="1">
<nlm:aff id="a">Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825,
<country>USA</country>
</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author>
<name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L." last="Laduca">Robert L. Laduca</name>
<affiliation wicri:level="1">
<nlm:aff id="a">Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825,
<country>USA</country>
</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series>
<title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint>
<date when="2008">2008</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc>
<textClass></textClass>
</profileDesc>
</teiHeader>
<front>
<div type="abstract" xml:lang="en">
<p>In the title compound, {[Cu
<sub>2</sub>
(C
<sub>4</sub>
H
<sub>2</sub>
O
<sub>4</sub>
)
<sub>2</sub>
(H
<sub>2</sub>
O)
<sub>2</sub>
]·3H
<sub>2</sub>
O}
<sub>
<italic>n</italic>
</sub>
, Cu
<sup>II</sup>
ions with square-pyramidal coordination are bridged by exo­tri­dentate maleate dianions into [Cu
<sub>2</sub>
(maleate)
<sub>2</sub>
(H
<sub>2</sub>
O)
<sub>2</sub>
]
<sub>
<italic>n</italic>
</sub>
layers coincident with the
<italic>bc</italic>
crystal plane. The inter­lamellar regions contain hydrogen-bonded cyclic water hexa­mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.</p>
</div>
</front>
<back>
<div1 type="bibliography">
<listBibl>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
<affiliations>
<list>
<country>
<li>États-Unis</li>
</country>
</list>
<tree>
<country name="États-Unis">
<noRegion>
<name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A." last="Farnum">Gregory A. Farnum</name>
</noRegion>
<name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L." last="Laduca">Robert L. Laduca</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002960 | SxmlIndent | more

Ou

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 002960 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Sante
   |area=    MersV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     PMC:2961984
   |texte=   Poly[[diaqua­bis(μ3-maleato-κ4O1:O1′,O4:O4′)dicopper(II)] trihydrate]
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i   -Sk "pubmed:21203054" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd   \
       | NlmPubMed2Wicri -a MersV1
Wicri

This area was generated with Dilib version V0.6.33.
Data generation: Mon Apr 20 23:26:43 2020. Site generation: Sat Mar 27 09:06:09 2021