Poly[[diaqua-bis(μ(3)-maleato-κO:O,O:O)dicopper(II)] trihydrate].
Identifieur interne : 002136 ( PubMed/Corpus ); précédent : 002135; suivant : 002137Poly[[diaqua-bis(μ(3)-maleato-κO:O,O:O)dicopper(II)] trihydrate].
Auteurs : Gregory A. Farnum ; Robert L. LaducaSource :
- Acta crystallographica. Section E, Structure reports online [ 1600-5368 ] ; 2008.
Abstract
In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo-tri-dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter-lamellar regions contain hydrogen-bonded cyclic water hexa-mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.
DOI: 10.1107/S1600536808023131
PubMed: 21203054
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pubmed:21203054Le document en format XML
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<author><name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L" last="Laduca">Robert L. Laduca</name>
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<front><div type="abstract" xml:lang="en">In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo-tri-dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter-lamellar regions contain hydrogen-bonded cyclic water hexa-mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.</div>
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<Abstract><AbstractText>In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo-tri-dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter-lamellar regions contain hydrogen-bonded cyclic water hexa-mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.</AbstractText>
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