MersV1, PubMed, Corpus, bibRecord, 002136

Poly[[diaqua-bis(μ(3)-maleato-κO:O,O:O)dicopper(II)] trihydrate].

Identifieur interne : 002136 ( PubMed/Corpus ); précédent : 002135; suivant : 002137

Poly[[diaqua-bis(μ(3)-maleato-κO:O,O:O)dicopper(II)] trihydrate].

Auteurs : Gregory A. Farnum ; Robert L. Laduca

Source :

Acta crystallographica. Section E, Structure reports online [ 1600-5368 ] ; 2008.

RBID : pubmed:21203054

Abstract

In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo-tri-dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter-lamellar regions contain hydrogen-bonded cyclic water hexa-mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.

DOI: 10.1107/S1600536808023131
PubMed: 21203054

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pubmed:21203054

Le document en format XML

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<author><name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A" last="Farnum">Gregory A. Farnum</name>
<affiliation><nlm:affiliation>Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.</nlm:affiliation>
</affiliation>
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<author><name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L" last="Laduca">Robert L. Laduca</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en">Poly[[diaqua-bis(μ(3)-maleato-κO:O,O:O)dicopper(II)] trihydrate].</title>
<author><name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A" last="Farnum">Gregory A. Farnum</name>
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<author><name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L" last="Laduca">Robert L. Laduca</name>
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<front><div type="abstract" xml:lang="en">In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo-tri-dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter-lamellar regions contain hydrogen-bonded cyclic water hexa-mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.</div>
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<Title>Acta crystallographica. Section E, Structure reports online</Title>
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<ArticleTitle>Poly[[diaqua-bis(μ(3)-maleato-κO:O,O:O)dicopper(II)] trihydrate].</ArticleTitle>
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<Abstract><AbstractText>In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo-tri-dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter-lamellar regions contain hydrogen-bonded cyclic water hexa-mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.</AbstractText>
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<AffiliationInfo><Affiliation>Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.</Affiliation>
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<ReferenceList><Reference><Citation>Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22</Citation>
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Poly[[diaqua-bis(μ(3)-maleato-κO:O,O:O)dicopper(II)] trihydrate].

Poly[[diaqua-bis(μ(3)-maleato-κO:O,O:O)dicopper(II)] trihydrate].

Source :

Abstract

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki