MersV1, Main, Exploration, bibRecord, 002A03

Bis(dimethylmalonato-κ2O,O′)bis[4-(4-pyridylamino-κN4)pyridinium]nickel(II) hexahydrate

Identifieur interne : 002A03 ( Main/Exploration ); précédent : 002A02; suivant : 002A04

Bis(dimethylmalonato-κ2O,O′)bis[4-(4-pyridylamino-κN4)pyridinium]nickel(II) hexahydrate

Auteurs : Gregory A. Farnum [États-Unis] ; Robert L. Laduca [États-Unis]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2008.

RBID : PMC:2960085

Abstract

In the title compound, [Ni(C₅H₆O₄)₂(C₁₀H₁₀N₃)₂]·6H₂O, divalent nickel ions situated on the crystallographic twofold axis are octahedrally coordinated by four O atoms from two dimethylmalonate ligands in a 1,3-chelating mode and two N atoms from two protonated monodentate 4,4′-dipyridylamine molecules. The molecules link into chains via N—H⋯O hydrogen bonding mediated by protonated pyridyl groups. The chains form layer patterns via π–π stacking [centroid–centroid distance = 3.777 (2) Å] . Water molecule hexamers are generated from the unligated water molecules (three per asymmetric unit) by inversion centers at Wyckoff position d. These clusters are situated between the pseudolayers, providing hydrogen-bonding pathways that build up the three-dimensional structure.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960085

DOI: 10.1107/S160053680803835X
PubMed: 21581200
PubMed Central: 2960085

Affiliations:

États-Unis

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis(dimethylmalonato-κ<sup>2</sup>
<italic>O</italic>
,<italic>O</italic>
′)bis[4-(4-pyridylamino-κ<italic>N</italic>
<sup>4</sup>
)pyridinium]nickel(II) hexahydrate</title>
<author><name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A." last="Farnum">Gregory A. Farnum</name>
<affiliation wicri:level="1"><nlm:aff id="a">Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825,<country>USA</country>
</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L." last="Laduca">Robert L. Laduca</name>
<affiliation wicri:level="1"><nlm:aff id="a">Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825,<country>USA</country>
</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PMC</idno>
<idno type="pmid">21581200</idno>
<idno type="pmc">2960085</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960085</idno>
<idno type="RBID">PMC:2960085</idno>
<idno type="doi">10.1107/S160053680803835X</idno>
<date when="2008">2008</date>
<idno type="wicri:Area/Pmc/Corpus">000A08</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000A08</idno>
<idno type="wicri:Area/Pmc/Curation">000A08</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000A08</idno>
<idno type="wicri:Area/Pmc/Checkpoint">001403</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">001403</idno>
<idno type="wicri:source">PubMed</idno>
<idno type="RBID">pubmed:21581200</idno>
<idno type="wicri:Area/PubMed/Corpus">002133</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">002133</idno>
<idno type="wicri:Area/PubMed/Curation">002133</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">002133</idno>
<idno type="wicri:Area/PubMed/Checkpoint">002011</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">002011</idno>
<idno type="wicri:Area/Ncbi/Merge">000840</idno>
<idno type="wicri:Area/Ncbi/Curation">000840</idno>
<idno type="wicri:Area/Ncbi/Checkpoint">000840</idno>
<idno type="wicri:Area/Main/Merge">002A29</idno>
<idno type="wicri:Area/Main/Curation">002A03</idno>
<idno type="wicri:Area/Main/Exploration">002A03</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis(dimethylmalonato-κ<sup>2</sup>
<italic>O</italic>
,<italic>O</italic>
′)bis[4-(4-pyridylamino-κ<italic>N</italic>
<sup>4</sup>
)pyridinium]nickel(II) hexahydrate</title>
<author><name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A." last="Farnum">Gregory A. Farnum</name>
<affiliation wicri:level="1"><nlm:aff id="a">Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825,<country>USA</country>
</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L." last="Laduca">Robert L. Laduca</name>
<affiliation wicri:level="1"><nlm:aff id="a">Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825,<country>USA</country>
</nlm:aff>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2008">2008</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en"><p>In the title compound, [Ni(C<sub>5</sub>
H<sub>6</sub>
O<sub>4</sub>
)<sub>2</sub>
(C<sub>10</sub>
H<sub>10</sub>
N<sub>3</sub>
)<sub>2</sub>
]·6H<sub>2</sub>
O, divalent nickel ions situated on the crystallographic twofold axis are octahedrally coordinated by four O atoms from two dimethylmalonate ligands in a 1,3-chelating mode and two N atoms from two protonated monodentate 4,4′-dipyridylamine molecules. The molecules link into chains <italic>via</italic>
 N—H⋯O hydrogen bonding mediated by protonated pyridyl groups. The chains form layer patterns <italic>via</italic>
 π–π stacking [centroid–centroid distance = 3.777 (2) Å] . Water molecule hexamers are generated from the unligated water molecules (three per asymmetric unit) by inversion centers at Wyckoff position <italic>d</italic>
. These clusters are situated between the pseudolayers, providing hydrogen-bonding pathways that build up the three-dimensional structure.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
<affiliations><list><country><li>États-Unis</li>
</country>
</list>
<tree><country name="États-Unis"><noRegion><name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A." last="Farnum">Gregory A. Farnum</name>
</noRegion>
<name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L." last="Laduca">Robert L. Laduca</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002A03 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 002A03 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Sante
   |area=    MersV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     PMC:2960085
   |texte=   Bis(dimethylmalonato-κ2O,O′)bis[4-(4-pyridylamino-κN4)pyridinium]nickel(II) hexahydrate
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i   -Sk "pubmed:21581200" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd   \
       | NlmPubMed2Wicri -a MersV1

This area was generated with Dilib version V0.6.33.
Data generation: Mon Apr 20 23:26:43 2020. Site generation: Sat Mar 27 09:06:09 2021

Serveur d'exploration MERS

Bis(dimethylmalonato-κ2O,O′)bis[4-(4-pyridylamino-κN4)pyridinium]nickel(II) hexahydrate

Bis(dimethylmalonato-κ2O,O′)bis[4-(4-pyridylamino-κN4)pyridinium]nickel(II) hexahydrate

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration MERS
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration MERS

Bis(dimethyl­malonato-κ2O,O′)bis­[4-(4-pyridylamino-κN4)pyridinium]nickel(II) hexa­hydrate

Bis(dimethyl­malonato-κ2O,O′)bis­[4-(4-pyridylamino-κN4)pyridinium]nickel(II) hexa­hydrate

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

Bis(dimethylmalonato-κ2O,O′)bis[4-(4-pyridylamino-κN4)pyridinium]nickel(II) hexahydrate

Bis(dimethylmalonato-κ2O,O′)bis[4-(4-pyridylamino-κN4)pyridinium]nickel(II) hexahydrate