Bis(dimethyl-malonato-κO,O')bis-[4-(4-pyridylamino-κN)pyridinium]nickel(II) hexa-hydrate.
Identifieur interne : 002133 ( PubMed/Curation ); précédent : 002132; suivant : 002134Bis(dimethyl-malonato-κO,O')bis-[4-(4-pyridylamino-κN)pyridinium]nickel(II) hexa-hydrate.
Auteurs : Gregory A. Farnum [États-Unis] ; Robert L. LaducaSource :
- Acta crystallographica. Section E, Structure reports online [ 1600-5368 ] ; 2008.
Abstract
In the title compound, [Ni(C(5)H(6)O(4))(2)(C(10)H(10)N(3))(2)]·6H(2)O, divalent nickel ions situated on the crystallographic twofold axis are octa-hedrally coordinated by four O atoms from two dimethyl-malonate ligands in a 1,3-chelating mode and two N atoms from two protonated monodentate 4,4'-dipyridylamine mol-ecules. The mol-ecules link into chains via N-H⋯O hydrogen bonding mediated by protonated pyridyl groups. The chains form layer patterns via π-π stacking [centroid-centroid distance = 3.777 (2) Å] . Water mol-ecule hexa-mers are generated from the unligated water mol-ecules (three per asymmetric unit) by inversion centers at Wyckoff position d. These clusters are situated between the pseudolayers, providing hydrogen-bonding pathways that build up the three-dimensional structure.
DOI: 10.1107/S160053680803835X
PubMed: 21581200
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: Pour aller vers cette notice dans l'étape Curation :002133
Links to Exploration step
pubmed:21581200Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis(dimethyl-malonato-κO,O')bis-[4-(4-pyridylamino-κN)pyridinium]nickel(II) hexa-hydrate.</title>
<author><name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A" last="Farnum">Gregory A. Farnum</name>
<affiliation wicri:level="1"><nlm:affiliation>Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.</nlm:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L" last="Laduca">Robert L. Laduca</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2008">2008</date>
<idno type="RBID">pubmed:21581200</idno>
<idno type="pmid">21581200</idno>
<idno type="doi">10.1107/S160053680803835X</idno>
<idno type="wicri:Area/PubMed/Corpus">002133</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">002133</idno>
<idno type="wicri:Area/PubMed/Curation">002133</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">002133</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Bis(dimethyl-malonato-κO,O')bis-[4-(4-pyridylamino-κN)pyridinium]nickel(II) hexa-hydrate.</title>
<author><name sortKey="Farnum, Gregory A" sort="Farnum, Gregory A" uniqKey="Farnum G" first="Gregory A" last="Farnum">Gregory A. Farnum</name>
<affiliation wicri:level="1"><nlm:affiliation>Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.</nlm:affiliation>
<country xml:lang="fr">États-Unis</country>
<wicri:regionArea>Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Laduca, Robert L" sort="Laduca, Robert L" uniqKey="Laduca R" first="Robert L" last="Laduca">Robert L. Laduca</name>
</author>
</analytic>
<series><title level="j">Acta crystallographica. Section E, Structure reports online</title>
<idno type="ISSN">1600-5368</idno>
<imprint><date when="2008" type="published">2008</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">In the title compound, [Ni(C(5)H(6)O(4))(2)(C(10)H(10)N(3))(2)]·6H(2)O, divalent nickel ions situated on the crystallographic twofold axis are octa-hedrally coordinated by four O atoms from two dimethyl-malonate ligands in a 1,3-chelating mode and two N atoms from two protonated monodentate 4,4'-dipyridylamine mol-ecules. The mol-ecules link into chains via N-H⋯O hydrogen bonding mediated by protonated pyridyl groups. The chains form layer patterns via π-π stacking [centroid-centroid distance = 3.777 (2) Å] . Water mol-ecule hexa-mers are generated from the unligated water mol-ecules (three per asymmetric unit) by inversion centers at Wyckoff position d. These clusters are situated between the pseudolayers, providing hydrogen-bonding pathways that build up the three-dimensional structure.</div>
</front>
</TEI>
<pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">21581200</PMID>
<DateCompleted><Year>2011</Year>
<Month>07</Month>
<Day>14</Day>
</DateCompleted>
<DateRevised><Year>2018</Year>
<Month>11</Month>
<Day>13</Day>
</DateRevised>
<Article PubModel="Electronic"><Journal><ISSN IssnType="Print">1600-5368</ISSN>
<JournalIssue CitedMedium="Print"><Volume>64</Volume>
<Issue>Pt 12</Issue>
<PubDate><Year>2008</Year>
<Month>Nov</Month>
<Day>22</Day>
</PubDate>
</JournalIssue>
<Title>Acta crystallographica. Section E, Structure reports online</Title>
<ISOAbbreviation>Acta Crystallogr Sect E Struct Rep Online</ISOAbbreviation>
</Journal>
<ArticleTitle>Bis(dimethyl-malonato-κO,O')bis-[4-(4-pyridylamino-κN)pyridinium]nickel(II) hexa-hydrate.</ArticleTitle>
<Pagination><MedlinePgn>m1603</MedlinePgn>
</Pagination>
<ELocationID EIdType="doi" ValidYN="Y">10.1107/S160053680803835X</ELocationID>
<Abstract><AbstractText>In the title compound, [Ni(C(5)H(6)O(4))(2)(C(10)H(10)N(3))(2)]·6H(2)O, divalent nickel ions situated on the crystallographic twofold axis are octa-hedrally coordinated by four O atoms from two dimethyl-malonate ligands in a 1,3-chelating mode and two N atoms from two protonated monodentate 4,4'-dipyridylamine mol-ecules. The mol-ecules link into chains via N-H⋯O hydrogen bonding mediated by protonated pyridyl groups. The chains form layer patterns via π-π stacking [centroid-centroid distance = 3.777 (2) Å] . Water mol-ecule hexa-mers are generated from the unligated water mol-ecules (three per asymmetric unit) by inversion centers at Wyckoff position d. These clusters are situated between the pseudolayers, providing hydrogen-bonding pathways that build up the three-dimensional structure.</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Farnum</LastName>
<ForeName>Gregory A</ForeName>
<Initials>GA</Initials>
<AffiliationInfo><Affiliation>Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Laduca</LastName>
<ForeName>Robert L</ForeName>
<Initials>RL</Initials>
</Author>
</AuthorList>
<Language>eng</Language>
<PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType>
</PublicationTypeList>
<ArticleDate DateType="Electronic"><Year>2008</Year>
<Month>11</Month>
<Day>22</Day>
</ArticleDate>
</Article>
<MedlineJournalInfo><Country>United States</Country>
<MedlineTA>Acta Crystallogr Sect E Struct Rep Online</MedlineTA>
<NlmUniqueID>101089178</NlmUniqueID>
<ISSNLinking>1600-5368</ISSNLinking>
</MedlineJournalInfo>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="received"><Year>2008</Year>
<Month>10</Month>
<Day>30</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="accepted"><Year>2008</Year>
<Month>11</Month>
<Day>17</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="entrez"><Year>2011</Year>
<Month>5</Month>
<Day>18</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="pubmed"><Year>2008</Year>
<Month>1</Month>
<Day>1</Day>
<Hour>0</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2008</Year>
<Month>1</Month>
<Day>1</Day>
<Hour>0</Hour>
<Minute>1</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>epublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="pubmed">21581200</ArticleId>
<ArticleId IdType="doi">10.1107/S160053680803835X</ArticleId>
<ArticleId IdType="pmc">PMC2960085</ArticleId>
</ArticleIdList>
<ReferenceList><Reference><Citation>Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22</Citation>
<ArticleIdList><ArticleId IdType="pubmed">18156677</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Inorg Chem. 2007 Sep 17;46(19):7917-22</Citation>
<ArticleIdList><ArticleId IdType="pubmed">17696494</ArticleId>
</ArticleIdList>
</Reference>
</ReferenceList>
</PubmedData>
</pubmed>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/PubMed/Curation
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002133 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/PubMed/Curation/biblio.hfd -nk 002133 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Sante |area= MersV1 |flux= PubMed |étape= Curation |type= RBID |clé= pubmed:21581200 |texte= Bis(dimethyl-malonato-κO,O')bis-[4-(4-pyridylamino-κN)pyridinium]nickel(II) hexa-hydrate. }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Curation/RBID.i -Sk "pubmed:21581200" \ | HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Curation/biblio.hfd \ | NlmPubMed2Wicri -a MersV1
This area was generated with Dilib version V0.6.33. |